Understanding the role of silane pretreatments in an organic coating system. Part 2: a study of molecular dynamics simulation View Full Text


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Article Info

DATE

2019-04-02

AUTHORS

Xiao-Xin Wang, Hong-Li Fu, Mei-Yan Jiang, Ying-Chun Liu, Ji-Ming Hu

ABSTRACT

In the second part of this work, silane-pretreated epoxy coatings on aluminum substrate are theoretically studied by molecular dynamics simulation. The results show that (3-glycidoxypropyl)-trimethoxysilane (GPTMS) provides improved interaction energy for aluminum and epoxy interface and thus ensures satisfactory adhesion. Water diffuses fastest and slowest across the interface of bis-1,2-(triethoxysilyl)ethane (BTSE)- and GPTMS-pretreated painting systems, respectively, suggesting that BTSE has the worst and GPTMS provides the best capability for constructing a reliable interface among the selected painting systems. The existence of both silane pretreatments improves the resistance of structure relaxation of the epoxy polymer chain to water penetration. More... »

PAGES

1-11

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11998-019-00183-9

DOI

http://dx.doi.org/10.1007/s11998-019-00183-9

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https://app.dimensions.ai/details/publication/pub.1113199871


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