Ontology type: schema:ScholarlyArticle
2016-05
AUTHORSKyuchul Shin, Minjun Cha, Wonhee Lee, Huen Lee
ABSTRACTAcid clathrate hydrates which do not contain hydrogen fluoride impurities are believed to include several vacancy sites in the host lattice for protonation of the framework. In this work, the crystal structures of a DClO4· 5.5D2O solid at various temperatures were identified by the direct space method and Rietveld refinement of the neutron powder diffraction patterns. A position change of vacancy sites accompanying the shift of ClO4− guest ions in the 51262 cavity toward the center of the cavity from the edge of the hexagonal face was observed at about 180 K, and this phenomenon is expected to result in weakened host proton-guest anion interactions and to induce a phase transition related to the proton conduction behavior of the DClO4 clathrate. The present findings explain the proton dynamics of the hydrogen fluoride-free acid clathrate hydrates and provide a better understanding of the nature of guest-host interactions occurring on ion-doped hydrate materials. More... »
PAGES1728-1735
http://scigraph.springernature.com/pub.10.1007/s11814-016-0010-0
DOIhttp://dx.doi.org/10.1007/s11814-016-0010-0
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1010897815
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Kyungpook National University",
"id": "https://www.grid.ac/institutes/grid.258803.4",
"name": [
"School of Applied Chemical Engineering, Major in Applied Chemistry, Kyungpook National University, 80 Daehak-ro, Buk-gu, 41566, Daegu, Korea"
],
"type": "Organization"
},
"familyName": "Shin",
"givenName": "Kyuchul",
"id": "sg:person.01252214461.39",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01252214461.39"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Kangwon National University",
"id": "https://www.grid.ac/institutes/grid.412010.6",
"name": [
"Department of Energy and Resources Engineering, Kangwon National University, 1 Kangwondaehak-gil, Chuncheon-si, 24341, Gangwon-do, Korea"
],
"type": "Organization"
},
"familyName": "Cha",
"givenName": "Minjun",
"id": "sg:person.01163245326.41",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01163245326.41"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Korea Institute of Energy Research",
"id": "https://www.grid.ac/institutes/grid.418979.a",
"name": [
"Climate Change Research Division, Korea Institute of Energy Research (KIER), 34128, Daejeon, Korea"
],
"type": "Organization"
},
"familyName": "Lee",
"givenName": "Wonhee",
"id": "sg:person.01045443305.51",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01045443305.51"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Korea Advanced Institute of Science and Technology",
"id": "https://www.grid.ac/institutes/grid.37172.30",
"name": [
"Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), 291 Daehak-ro, Yuseong-gu, 34143, Daejeon, Korea"
],
"type": "Organization"
},
"familyName": "Lee",
"givenName": "Huen",
"id": "sg:person.01042725253.39",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01042725253.39"
],
"type": "Person"
}
],
"citation": [
{
"id": "https://doi.org/10.1073/pnas.1302812110",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1002264257"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.electacta.2013.07.185",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1009564362"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0921-4526(93)90108-i",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1011196855"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0921-4526(93)90108-i",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1011196855"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/asia.201300089",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1011408810"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/asia.200900219",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1012926986"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/asia.200900219",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1012926986"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/anie.200903501",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1024250588"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/anie.200903501",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1024250588"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1107/s0021889802015236",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1026434426"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1524/zkri.2007.222.3-4.105",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1027212880"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1073/pnas.1205820109",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1027261344"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/b907797a",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1039533130"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/b907797a",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1039533130"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1139/v72-565",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1040304314"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1107/s0021889811038970",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1048136594"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.ssi.2013.06.004",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1050880744"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ic50221a016",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055580573"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/j100335a008",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055665331"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja00238a032",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055716721"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja905426e",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055861971"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja905426e",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055861971"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jp073910c",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056072714"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jp073910c",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056072714"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jp110737q",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056080588"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jp110737q",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056080588"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jp504656x",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056101360"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jp805510g",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056109616"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jp805510g",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056109616"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1063/1.1819863",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1057824644"
],
"type": "CreativeWork"
}
],
"datePublished": "2016-05",
"datePublishedReg": "2016-05-01",
"description": "Acid clathrate hydrates which do not contain hydrogen fluoride impurities are believed to include several vacancy sites in the host lattice for protonation of the framework. In this work, the crystal structures of a DClO4\u00b7 5.5D2O solid at various temperatures were identified by the direct space method and Rietveld refinement of the neutron powder diffraction patterns. A position change of vacancy sites accompanying the shift of ClO4\u2212 guest ions in the 51262 cavity toward the center of the cavity from the edge of the hexagonal face was observed at about 180 K, and this phenomenon is expected to result in weakened host proton-guest anion interactions and to induce a phase transition related to the proton conduction behavior of the DClO4 clathrate. The present findings explain the proton dynamics of the hydrogen fluoride-free acid clathrate hydrates and provide a better understanding of the nature of guest-host interactions occurring on ion-doped hydrate materials.",
"genre": "research_article",
"id": "sg:pub.10.1007/s11814-016-0010-0",
"inLanguage": [
"en"
],
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1046991",
"issn": [
"0256-1115",
"1975-7220"
],
"name": "Korean Journal of Chemical Engineering",
"type": "Periodical"
},
{
"issueNumber": "5",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "33"
}
],
"name": "Structural identification of DClO4 clathrate hydrates: Neutron powder diffraction analysis",
"pagination": "1728-1735",
"productId": [
{
"name": "readcube_id",
"type": "PropertyValue",
"value": [
"33eb9a9c20fee3f45efea02e535009e51e12976d068a95c9a441893ba590047f"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/s11814-016-0010-0"
]
},
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1010897815"
]
}
],
"sameAs": [
"https://doi.org/10.1007/s11814-016-0010-0",
"https://app.dimensions.ai/details/publication/pub.1010897815"
],
"sdDataset": "articles",
"sdDatePublished": "2019-04-10T18:22",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8675_00000520.jsonl",
"type": "ScholarlyArticle",
"url": "http://link.springer.com/10.1007%2Fs11814-016-0010-0"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11814-016-0010-0'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11814-016-0010-0'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11814-016-0010-0'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11814-016-0010-0'
This table displays all metadata directly associated to this object as RDF triples.
157 TRIPLES
21 PREDICATES
49 URIs
19 LITERALS
7 BLANK NODES