Effect of support for alcohol-hydrocarbon synthesis from syngas in Cu-based catalyst View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-04

AUTHORS

Sun-Hwa Yeon, Dae-Hyun Shin, Nam-Sun Nho, Kyoung-Hee Shin, Chang-Soo Jin, Sung-Chan Nam

ABSTRACT

Effects of a Cu-based catalyst on the catalytic performance in alcohol-hydrocarbon synthesis from syngas have been investigated, using various supports. Under the different porosities of three supports (zinc oxide, activation carbon, and titanium dioxide), whereas Cu/ZnO produces one liquid phase of major mixed alcohols, Cu/AC and Cu/TiO2 create two phases, alcohol (∼75%) and hydrocarbon (∼25%). X-ray diffraction shows that CuO impregnated on supports undergoes a complete reduction of metallic copper Cu0, which is the real active phase in the catalytic process. The Cu/TiO2 catalyst showed the highest ethanol composition in a mixed alcohol phase under GHSV 18,000 h−1, 30 bar, and 300 °C. More... »

PAGES

864-870

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11814-012-0205-y

DOI

http://dx.doi.org/10.1007/s11814-012-0205-y

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https://app.dimensions.ai/details/publication/pub.1035024711


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