Simultaneous removal of H2S and COS using Zn-based solid sorbents in the bench-scale continuous hot gas desulfurization system integrated with ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-12

AUTHORS

Young Cheol Park, Sung-Ho Jo, Ho-Jung Ryu, Jong-Ho Moon, Chang-Keun Yi, Yongseung Yoon, Jeom-In Baek

ABSTRACT

A bench-scale continuous hot gas desulfurization system using Zn-based solid sorbents was developed to remove H2S and COS simultaneously in a 110 Nm3/h of real coal-gasified syngas. The bench-scale unit, which consisted of a fast fluidized-bed type desulfurizer and a bubbling fluidized-bed type regenerator, was integrated with a 3 ton/day-scale coal gasifier installed at the Institute for Advanced Engineering. The solid sorbents, which consisted of 50 wt% of ZnO for sulfides sorption and 50 wt% of supporters for mechanical strength, were manufactured by a spray drying method and supplied by Korea Electric Power Corporation Research Institute. The bench-scale unit was designed to operate at the high temperature of above 500 °C and the high pressure of 19 kgf/cm2 gauge. Integration of the bench-scale unit with a coal gasifier was first performed to investigate the operation stability of the integrated system. And the long-term continuous operation above 30 h was performed to analyze the desulfurization performance of the bench-scale unit. The concentration of both H2S and COS in the syngas was measured by a continuous UV gas analyzer and an online gas chromatograph and that of both H2S and COS after desulfurization was measured by an online gas chromatograph. Through the above 30-h continuous operation, the sulfur removal reached up to 99.9%. More... »

PAGES

1812-1816

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11814-012-0059-3

DOI

http://dx.doi.org/10.1007/s11814-012-0059-3

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1015174906


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0904", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Korea Institute of Energy Research", 
          "id": "https://www.grid.ac/institutes/grid.418979.a", 
          "name": [
            "Greenhouse Gas Research Center, Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, 305-343, Daejeon, Korea"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Park", 
        "givenName": "Young Cheol", 
        "id": "sg:person.015137306513.04", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015137306513.04"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Korea Institute of Energy Research", 
          "id": "https://www.grid.ac/institutes/grid.418979.a", 
          "name": [
            "Greenhouse Gas Research Center, Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, 305-343, Daejeon, Korea"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Jo", 
        "givenName": "Sung-Ho", 
        "id": "sg:person.013724616531.80", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013724616531.80"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Korea Institute of Energy Research", 
          "id": "https://www.grid.ac/institutes/grid.418979.a", 
          "name": [
            "Greenhouse Gas Research Center, Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, 305-343, Daejeon, Korea"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ryu", 
        "givenName": "Ho-Jung", 
        "id": "sg:person.016153074417.00", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016153074417.00"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Korea Institute of Energy Research", 
          "id": "https://www.grid.ac/institutes/grid.418979.a", 
          "name": [
            "Greenhouse Gas Research Center, Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, 305-343, Daejeon, Korea"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Moon", 
        "givenName": "Jong-Ho", 
        "id": "sg:person.011010234257.77", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011010234257.77"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Korea Institute of Energy Research", 
          "id": "https://www.grid.ac/institutes/grid.418979.a", 
          "name": [
            "Greenhouse Gas Research Center, Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, 305-343, Daejeon, Korea"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Yi", 
        "givenName": "Chang-Keun", 
        "id": "sg:person.01052724037.29", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01052724037.29"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute for Advanced Engineering", 
          "id": "https://www.grid.ac/institutes/grid.486772.8", 
          "name": [
            "Center for Plant Engineering, Institute for Advanced Engineering, 5, Weoncheon-dong, Yeongtong-gu, 443-749, Suwon, Korea"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Yoon", 
        "givenName": "Yongseung", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Green Growth Laboratory, Korea Electric Power Corporation Research Institute, 65, Munji-ro, Yuseong-gu, 305-380, Daejeon, Korea"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Baek", 
        "givenName": "Jeom-In", 
        "id": "sg:person.016174557240.09", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016174557240.09"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf02705633", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000642752", 
          "https://doi.org/10.1007/bf02705633"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02705633", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000642752", 
          "https://doi.org/10.1007/bf02705633"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02698296", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035720227", 
          "https://doi.org/10.1007/bf02698296"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02698296", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035720227", 
          "https://doi.org/10.1007/bf02698296"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.apt.2009.12.004", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039097539"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2012-12", 
    "datePublishedReg": "2012-12-01", 
    "description": "A bench-scale continuous hot gas desulfurization system using Zn-based solid sorbents was developed to remove H2S and COS simultaneously in a 110 Nm3/h of real coal-gasified syngas. The bench-scale unit, which consisted of a fast fluidized-bed type desulfurizer and a bubbling fluidized-bed type regenerator, was integrated with a 3 ton/day-scale coal gasifier installed at the Institute for Advanced Engineering. The solid sorbents, which consisted of 50 wt% of ZnO for sulfides sorption and 50 wt% of supporters for mechanical strength, were manufactured by a spray drying method and supplied by Korea Electric Power Corporation Research Institute. The bench-scale unit was designed to operate at the high temperature of above 500 \u00b0C and the high pressure of 19 kgf/cm2 gauge. Integration of the bench-scale unit with a coal gasifier was first performed to investigate the operation stability of the integrated system. And the long-term continuous operation above 30 h was performed to analyze the desulfurization performance of the bench-scale unit. The concentration of both H2S and COS in the syngas was measured by a continuous UV gas analyzer and an online gas chromatograph and that of both H2S and COS after desulfurization was measured by an online gas chromatograph. Through the above 30-h continuous operation, the sulfur removal reached up to 99.9%.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s11814-012-0059-3", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1046991", 
        "issn": [
          "0256-1115", 
          "1975-7220"
        ], 
        "name": "Korean Journal of Chemical Engineering", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "12", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "29"
      }
    ], 
    "name": "Simultaneous removal of H2S and COS using Zn-based solid sorbents in the bench-scale continuous hot gas desulfurization system integrated with a coal gasifier", 
    "pagination": "1812-1816", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "484c8f01c7e2aab59e7fcf377062ac6cb3c92661bc390ad9d176f46cc1b089c2"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11814-012-0059-3"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1015174906"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11814-012-0059-3", 
      "https://app.dimensions.ai/details/publication/pub.1015174906"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T15:03", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8663_00000521.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs11814-012-0059-3"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11814-012-0059-3'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11814-012-0059-3'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11814-012-0059-3'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11814-012-0059-3'


 

This table displays all metadata directly associated to this object as RDF triples.

118 TRIPLES      21 PREDICATES      30 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11814-012-0059-3 schema:about anzsrc-for:09
2 anzsrc-for:0904
3 schema:author N46627682ed7140048434772017775936
4 schema:citation sg:pub.10.1007/bf02698296
5 sg:pub.10.1007/bf02705633
6 https://doi.org/10.1016/j.apt.2009.12.004
7 schema:datePublished 2012-12
8 schema:datePublishedReg 2012-12-01
9 schema:description A bench-scale continuous hot gas desulfurization system using Zn-based solid sorbents was developed to remove H2S and COS simultaneously in a 110 Nm3/h of real coal-gasified syngas. The bench-scale unit, which consisted of a fast fluidized-bed type desulfurizer and a bubbling fluidized-bed type regenerator, was integrated with a 3 ton/day-scale coal gasifier installed at the Institute for Advanced Engineering. The solid sorbents, which consisted of 50 wt% of ZnO for sulfides sorption and 50 wt% of supporters for mechanical strength, were manufactured by a spray drying method and supplied by Korea Electric Power Corporation Research Institute. The bench-scale unit was designed to operate at the high temperature of above 500 °C and the high pressure of 19 kgf/cm2 gauge. Integration of the bench-scale unit with a coal gasifier was first performed to investigate the operation stability of the integrated system. And the long-term continuous operation above 30 h was performed to analyze the desulfurization performance of the bench-scale unit. The concentration of both H2S and COS in the syngas was measured by a continuous UV gas analyzer and an online gas chromatograph and that of both H2S and COS after desulfurization was measured by an online gas chromatograph. Through the above 30-h continuous operation, the sulfur removal reached up to 99.9%.
10 schema:genre research_article
11 schema:inLanguage en
12 schema:isAccessibleForFree false
13 schema:isPartOf Na8480bf639de4a518528790a20bd2ec3
14 Nc571928ca8fb441f81e5835437ff9d3c
15 sg:journal.1046991
16 schema:name Simultaneous removal of H2S and COS using Zn-based solid sorbents in the bench-scale continuous hot gas desulfurization system integrated with a coal gasifier
17 schema:pagination 1812-1816
18 schema:productId N160b663bf79445d29fbaf593a912175c
19 N3460211a90794bd098e6db5b55cfb21c
20 N4ec20f83c63a44aaa6b4e495af493ebe
21 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015174906
22 https://doi.org/10.1007/s11814-012-0059-3
23 schema:sdDatePublished 2019-04-10T15:03
24 schema:sdLicense https://scigraph.springernature.com/explorer/license/
25 schema:sdPublisher N84fd95061cfb4772ba47d749b92e7333
26 schema:url http://link.springer.com/10.1007%2Fs11814-012-0059-3
27 sgo:license sg:explorer/license/
28 sgo:sdDataset articles
29 rdf:type schema:ScholarlyArticle
30 N160b663bf79445d29fbaf593a912175c schema:name readcube_id
31 schema:value 484c8f01c7e2aab59e7fcf377062ac6cb3c92661bc390ad9d176f46cc1b089c2
32 rdf:type schema:PropertyValue
33 N2a50f42f4d04451b9a656888461b5ee1 schema:affiliation https://www.grid.ac/institutes/grid.486772.8
34 schema:familyName Yoon
35 schema:givenName Yongseung
36 rdf:type schema:Person
37 N3460211a90794bd098e6db5b55cfb21c schema:name dimensions_id
38 schema:value pub.1015174906
39 rdf:type schema:PropertyValue
40 N46627682ed7140048434772017775936 rdf:first sg:person.015137306513.04
41 rdf:rest Ndca1b282dcd04c93bdcee1cc0e090f6e
42 N4ec20f83c63a44aaa6b4e495af493ebe schema:name doi
43 schema:value 10.1007/s11814-012-0059-3
44 rdf:type schema:PropertyValue
45 N4eea3ad11c1b4c2fa1394edc33476d56 rdf:first sg:person.011010234257.77
46 rdf:rest Nfe5819f2c1254dc2812045cbb66ca5ee
47 N84fd95061cfb4772ba47d749b92e7333 schema:name Springer Nature - SN SciGraph project
48 rdf:type schema:Organization
49 N86894d3e24d64236ba617c456501299c schema:name Green Growth Laboratory, Korea Electric Power Corporation Research Institute, 65, Munji-ro, Yuseong-gu, 305-380, Daejeon, Korea
50 rdf:type schema:Organization
51 N9b4a35c870744c0d8ffa10ba3ed12a77 rdf:first sg:person.016153074417.00
52 rdf:rest N4eea3ad11c1b4c2fa1394edc33476d56
53 N9cade8a05ce4496c9bde514776878dc9 rdf:first N2a50f42f4d04451b9a656888461b5ee1
54 rdf:rest Nc25add16efac4765a6444847418dbfb8
55 Na8480bf639de4a518528790a20bd2ec3 schema:volumeNumber 29
56 rdf:type schema:PublicationVolume
57 Nc25add16efac4765a6444847418dbfb8 rdf:first sg:person.016174557240.09
58 rdf:rest rdf:nil
59 Nc571928ca8fb441f81e5835437ff9d3c schema:issueNumber 12
60 rdf:type schema:PublicationIssue
61 Ndca1b282dcd04c93bdcee1cc0e090f6e rdf:first sg:person.013724616531.80
62 rdf:rest N9b4a35c870744c0d8ffa10ba3ed12a77
63 Nfe5819f2c1254dc2812045cbb66ca5ee rdf:first sg:person.01052724037.29
64 rdf:rest N9cade8a05ce4496c9bde514776878dc9
65 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
66 schema:name Engineering
67 rdf:type schema:DefinedTerm
68 anzsrc-for:0904 schema:inDefinedTermSet anzsrc-for:
69 schema:name Chemical Engineering
70 rdf:type schema:DefinedTerm
71 sg:journal.1046991 schema:issn 0256-1115
72 1975-7220
73 schema:name Korean Journal of Chemical Engineering
74 rdf:type schema:Periodical
75 sg:person.01052724037.29 schema:affiliation https://www.grid.ac/institutes/grid.418979.a
76 schema:familyName Yi
77 schema:givenName Chang-Keun
78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01052724037.29
79 rdf:type schema:Person
80 sg:person.011010234257.77 schema:affiliation https://www.grid.ac/institutes/grid.418979.a
81 schema:familyName Moon
82 schema:givenName Jong-Ho
83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011010234257.77
84 rdf:type schema:Person
85 sg:person.013724616531.80 schema:affiliation https://www.grid.ac/institutes/grid.418979.a
86 schema:familyName Jo
87 schema:givenName Sung-Ho
88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013724616531.80
89 rdf:type schema:Person
90 sg:person.015137306513.04 schema:affiliation https://www.grid.ac/institutes/grid.418979.a
91 schema:familyName Park
92 schema:givenName Young Cheol
93 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015137306513.04
94 rdf:type schema:Person
95 sg:person.016153074417.00 schema:affiliation https://www.grid.ac/institutes/grid.418979.a
96 schema:familyName Ryu
97 schema:givenName Ho-Jung
98 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016153074417.00
99 rdf:type schema:Person
100 sg:person.016174557240.09 schema:affiliation N86894d3e24d64236ba617c456501299c
101 schema:familyName Baek
102 schema:givenName Jeom-In
103 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016174557240.09
104 rdf:type schema:Person
105 sg:pub.10.1007/bf02698296 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035720227
106 https://doi.org/10.1007/bf02698296
107 rdf:type schema:CreativeWork
108 sg:pub.10.1007/bf02705633 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000642752
109 https://doi.org/10.1007/bf02705633
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1016/j.apt.2009.12.004 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039097539
112 rdf:type schema:CreativeWork
113 https://www.grid.ac/institutes/grid.418979.a schema:alternateName Korea Institute of Energy Research
114 schema:name Greenhouse Gas Research Center, Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, 305-343, Daejeon, Korea
115 rdf:type schema:Organization
116 https://www.grid.ac/institutes/grid.486772.8 schema:alternateName Institute for Advanced Engineering
117 schema:name Center for Plant Engineering, Institute for Advanced Engineering, 5, Weoncheon-dong, Yeongtong-gu, 443-749, Suwon, Korea
118 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...