Spectroscopic observation of H2 migration in structure-I clathrate hydrate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-11

AUTHORS

Sukjeong Choi, Kyuchul Shin, Jong-Ho Cha, Huen Lee

ABSTRACT

We demonstrate the spectroscopic observation of H2 migration in the binary structure-I (sI) clathrate hydrate. The H2 molecules captured into sI small cage (sI-S) at lower temperature migrate to sI large cage (sI-L) through shared pentagonal face of 51262 cage. The hexagonal faces of 51262 cage provide the windows essential for creating continuous diffusion paths for H2 molecules. It is essential to realize that the vacant channels formed by the linkage of specific cages can play an important role in guest diffusion pathways and occupancy occurring in a complex clathrate hydrate matrix. More... »

PAGES

1397-1400

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11814-008-0229-5

DOI

http://dx.doi.org/10.1007/s11814-008-0229-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1017313812


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