Large-scale synthesis of methyl cis-9, trans-11-octadecadienoate from methyl ricinoleate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1997-08

AUTHORS

O. Berdeaux, W. W. Christie, F. D. Gunstone, J. -L. Sebedio

ABSTRACT

The conjugated linoleic acid methyl cis-9,trans-11-octadecadienoate has been prepared on a large scale from methyl ricinoleate. Methyl ricinoleate was purified from castor esters by a partition method. It was converted to the mesylate, which was reacted with a base (1,8-diazabicyclo[5,4,0]-undec-7-ene) to give a product that contained 66% of the desired ester. Two urea crystallizations produced a product containing 83% methyl cis-9,trans-11-octadecadienoate, the identity of which was confirmed by gas chromatography linked to mass spectrometry and by Fourier transform infrared spectroscopy. The remaining impurities were methyl cis-9,cis-11- and cis-9-,trans-12-octadecadienoate. More... »

PAGES

1011-1015

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11746-997-0018-z

DOI

http://dx.doi.org/10.1007/s11746-997-0018-z

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1009182792


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