Ontology type: schema:ScholarlyArticle
2016-11
AUTHORSC. Leigh Broadhurst, Walter F. Schmidt, Moon S. Kim, Julie. K. Nguyen, Jianwei Qin, Kuanglin Chao, Gary L. Bauchan, Daniel. R. Shelton
ABSTRACTWe analyzed the unsaturated fatty acids oleic (OA, 18:1n-9) and linoleic (LA, 18:2n-3), and a 3:1 LA:OA mixture from -100 to 50 °C with continuous gradient temperature Raman spectroscopy (GTRS). The 20 Mb three-dimensional data arrays with 0.2 °C increments and first/second derivatives allowed rapid, complete assignment of solid, liquid, and transition state vibrational modes. For OA, large spectral and line width changes occurred in the solid state γ to α transition near -4 °C, and the melt (13 °C) over a range of only 1 °C. For LA, major intensity reductions from 200 to 1750 cm-1 and some peak shifts marked one solid state phase transition at -50 °C. A second solid state transition (-33 °C) had minor spectral changes. Large spectral and line width changes occurred at the melt transition (-7 °C) over a narrow temperature range. For both molecules, melting initiates at the diene structure, then progresses towards the ends. In the 3:1 LA:OA mixture, some less intense and lower frequencies present in the individual lipids are weaker or absent. For example, modes assignable to C8 rocking, C9H-C10H wagging, C10H-C11H wagging, and CH3 rocking are present in OA but absent in LA:OA. Our data quantify the concept of lipid premelting and identify the flexible structures within OA and LA, which have characteristic vibrational modes beginning at cryogenic temperatures. More... »
PAGES1289-1302
http://scigraph.springernature.com/pub.10.1007/s11745-016-4194-1
DOIhttp://dx.doi.org/10.1007/s11745-016-4194-1
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PUBMEDhttps://www.ncbi.nlm.nih.gov/pubmed/27663253
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