Modeling of α-tocopherol loss and oxidation products formed during thermoxidation in triolein and tripalmitin mixtures View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2001-07

AUTHORS

T. Verleyen, A. Kamal-Eldin, C. Dobarganes, R. Verhe, K. Dewettinck, A. Huyghebaert

ABSTRACT

The degradation of alpha-tocopherol and the formation of alpha-tocopherol and triacylglycerol oxidation products at high temperatures (150-250 degrees C) over a heating period (0-4 h) for a model system ranging between triolein and tripalmitin were modeled by use of an experimental design. The oxidation products of alpha-tocopherol formed under these conditions were alpha-tocopherolquinone (1 .4-7.7%) and epoxy-alpha-tocopherolquinones (4.3-34.8%). The results indicate a very high susceptibility of alpha-tocopherol to capture peroxyl radicals upon oxidation, leading to the formation of polar tocopherol oxidation products. Both alpha-tocopherolquinone and epoxy-alpha-tocopherolquinones were not stable upon prolonged heating and were further degraded to other unknown oxidation products. The kinetics of alpha-tocopherol oxidation were significantly influenced by the triolein/tripalmitin ratio. By increasing the level of triacylglycerol unsaturation the rate of alpha-tocopherol recovery after heating increased significantly from 2.2 to 44.2% whereas in the meantime triacylglycerol polymerization increased from 0 to 3.7%. More... »

PAGES

719-726

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11745-001-0777-6

DOI

http://dx.doi.org/10.1007/s11745-001-0777-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1048226483

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/11521970


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