Structure and magnetic behavior of a trinuclear Mn(II) coordination complex with EDTA-ligand View Full Text


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Article Info

DATE

2007-12

AUTHORS

Zu-li Liu, Ai-qing Zhao, Kai-lun Yao, Li-hui Jia

ABSTRACT

A trinuclear Mn(II) coordination complex Mn3(HEDTA)2·10H2O (EDTA=ethylene diamine tetraacetic acid) 1 has been synthesized and characterized by X-ray crystal structure determination. In addition, IR spectrum, thermogravimetric analysis, electron paramagnetic resonance (EPR) spectra and magnetic susceptibility of this complex are discussed. X-ray determination indicates that six- and seven-coordinate modes between Mn(II) and H4EDTA exist alternately in 1. Furthermore, detailed discussion of magnetic ordering in the temperature range of 2∼300 K reveals the antiferromagnetic interactions in the complex. More... »

PAGES

556-561

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11741-007-0606-2

DOI

http://dx.doi.org/10.1007/s11741-007-0606-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1039501843


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