Construction of yolk–shell Fe3O4@C nanocubes for highly stable and efficient lithium-ion storage View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-12

AUTHORS

Ruiping Liu, Chao Zhang, Xiaofan Zhang, Fei Guo, Yue Dong, Qi Wang, Hanqing Zhao

ABSTRACT

The yolk-shell Fe3O4@C nanocubes were successfully synthesized through carbothermic reduction process from carbon-coated α-Fe2O3 precursor. The results show that the yolk-shell Fe3O4@C nanocubes are uniformly coated with a thin carbon layer, and a clear cavity about 150 nm in width between Fe3O4 core and carbon shell are formed due to the volume shrinkage during the reduction treatment. The obtained yolk-shell Fe3O4@C nanocubes exhibit excellent cycling stability (the discharge capacity is 709.7 mA$h/g after 100 cycles at the current density of 0.1C) and rate performance (1023.4 mA$h/g at 0.1C, 932.5 mA$h/g at 0.2C, 756.1 mA$h/g at 0.5C, 405.6 mA$h/g at 1C, and 332.3 mA$h/g at 2C, and more importantly, when the current density finally backs to 0.1C, a capacity of 776.8 mA$h/g can be restored). The outstanding lithium storage properties may be attributed to the unique yolk-shell structures. More... »

PAGES

1-7

References to SciGraph publications

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URI

http://scigraph.springernature.com/pub.10.1007/s11706-018-0443-y

DOI

http://dx.doi.org/10.1007/s11706-018-0443-y

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