Highly Efficient Near-IR Photoluminescence of Er3+ Immobilized in Mesoporous SBA-15 View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2010-08-24

AUTHORS

YL Xue, P Wu, Y Liu, X Zhang, L Lin, Q Jiang

ABSTRACT

SiO2 mesoporous molecular sieve SBA-15 with the incorporation of erbium ions is studied as a novel type of nanoscopic composite photoluminescent material in this paper. To enhance the photoluminescence efficiency, two schemes have been used for the incorporation of Er3+ where (1) Er3+ is ligated with bis-(perfluoromethylsulfonyl)-aminate (PMS) forming Er(PMS)x-SBA-15 and (2) Yb3+ is codoped with Er3+ forming Yb-Er-SBA-15. As high as 11.17 × 10−21cm2 of fluorescent cross section at 1534 nm and 88 nm of “effective bandwidth” have been gained. It is a 29.3% boost in fluorescent cross section compared to what has been obtained in conventional silica. The upconversion coefficient in Yb-Er-SBA-15 is relatively small compared to that in other ordinary glass hosts. The increased fluorescent cross section and lowered upconversion coefficient could benefit for the high-gain optical amplifier. Finally, the Judd–Ofelt theory has also been used for the analyses of the optical spectra of Er(PMS)x-SBA-15. More... »

PAGES

1952

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11671-010-9732-9

DOI

http://dx.doi.org/10.1007/s11671-010-9732-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1006149833

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/21170408


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/02", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0205", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Optical Physics", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Department of Electronic Engineering, East China Normal University, 500 Dongchuan Road, 200241, Shanghai, China", 
          "id": "http://www.grid.ac/institutes/grid.22069.3f", 
          "name": [
            "Department of Electronic Engineering, East China Normal University, 500 Dongchuan Road, 200241, Shanghai, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Xue", 
        "givenName": "YL", 
        "id": "sg:person.011335511425.50", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011335511425.50"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, 500 Dongchuan Road, 200241, Shanghai, China", 
          "id": "http://www.grid.ac/institutes/grid.22069.3f", 
          "name": [
            "Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, 500 Dongchuan Road, 200241, Shanghai, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wu", 
        "givenName": "P", 
        "id": "sg:person.07456107721.08", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07456107721.08"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, 500 Dongchuan Road, 200241, Shanghai, China", 
          "id": "http://www.grid.ac/institutes/grid.22069.3f", 
          "name": [
            "Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, 500 Dongchuan Road, 200241, Shanghai, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Liu", 
        "givenName": "Y", 
        "id": "sg:person.015252661671.73", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015252661671.73"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, 500 Dongchuan Road, 200241, Shanghai, China", 
          "id": "http://www.grid.ac/institutes/grid.22069.3f", 
          "name": [
            "Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, 500 Dongchuan Road, 200241, Shanghai, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zhang", 
        "givenName": "X", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Electronic Engineering, East China Normal University, 500 Dongchuan Road, 200241, Shanghai, China", 
          "id": "http://www.grid.ac/institutes/grid.22069.3f", 
          "name": [
            "Department of Electronic Engineering, East China Normal University, 500 Dongchuan Road, 200241, Shanghai, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lin", 
        "givenName": "L", 
        "id": "sg:person.011044314465.07", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011044314465.07"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Electronic Engineering, East China Normal University, 500 Dongchuan Road, 200241, Shanghai, China", 
          "id": "http://www.grid.ac/institutes/grid.22069.3f", 
          "name": [
            "Department of Electronic Engineering, East China Normal University, 500 Dongchuan Road, 200241, Shanghai, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Jiang", 
        "givenName": "Q", 
        "type": "Person"
      }
    ], 
    "datePublished": "2010-08-24", 
    "datePublishedReg": "2010-08-24", 
    "description": "SiO2 mesoporous molecular sieve SBA-15 with the incorporation of erbium ions is studied as a novel type of nanoscopic composite photoluminescent material in this paper. To enhance the photoluminescence efficiency, two schemes have been used for the incorporation of Er3+ where (1) Er3+ is ligated with bis-(perfluoromethylsulfonyl)-aminate (PMS) forming Er(PMS)x-SBA-15 and (2) Yb3+ is codoped with Er3+ forming Yb-Er-SBA-15. As high as 11.17 \u00d7 10\u221221cm2 of fluorescent cross section at 1534 nm and 88 nm of \u201ceffective bandwidth\u201d have been gained. It is a 29.3% boost in fluorescent cross section compared to what has been obtained in conventional silica. The upconversion coefficient in Yb-Er-SBA-15 is relatively small compared to that in other ordinary glass hosts. The increased fluorescent cross section and lowered upconversion coefficient could benefit for the high-gain optical amplifier. Finally, the Judd\u2013Ofelt theory has also been used for the analyses of the optical spectra of Er(PMS)x-SBA-15.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s11671-010-9732-9", 
    "isAccessibleForFree": true, 
    "isFundedItemOf": [
      {
        "id": "sg:grant.5001306", 
        "type": "MonetaryGrant"
      }
    ], 
    "isPartOf": [
      {
        "id": "sg:journal.1037280", 
        "issn": [
          "1931-7573", 
          "1556-276X"
        ], 
        "name": "Nanoscale Research Letters", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "12", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "5"
      }
    ], 
    "keywords": [
      "SBA-15", 
      "Yb\u2013Er", 
      "high gain optical amplifier", 
      "mesoporous molecular sieve SBA-15", 
      "molecular sieve SBA-15", 
      "mesoporous SBA-15", 
      "optical amplifier", 
      "conventional silica", 
      "effective bandwidth", 
      "photoluminescence efficiency", 
      "erbium ions", 
      "photoluminescent materials", 
      "near-IR photoluminescence", 
      "upconversion coefficient", 
      "optical spectra", 
      "glass host", 
      "novel type", 
      "Er3", 
      "bandwidth", 
      "photoluminescence", 
      "amplifier", 
      "silica", 
      "Yb3", 
      "incorporation", 
      "efficiency", 
      "scheme", 
      "materials", 
      "spectra", 
      "ions", 
      "Judd\u2013Ofelt theory", 
      "Bi", 
      "paper", 
      "cross sections", 
      "coefficient", 
      "host", 
      "boost", 
      "sections", 
      "types", 
      "analysis", 
      "theory"
    ], 
    "name": "Highly Efficient Near-IR Photoluminescence of Er3+ Immobilized in Mesoporous SBA-15", 
    "pagination": "1952", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1006149833"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11671-010-9732-9"
        ]
      }, 
      {
        "name": "pubmed_id", 
        "type": "PropertyValue", 
        "value": [
          "21170408"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11671-010-9732-9", 
      "https://app.dimensions.ai/details/publication/pub.1006149833"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-12-01T06:28", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221201/entities/gbq_results/article/article_506.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s11671-010-9732-9"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11671-010-9732-9'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11671-010-9732-9'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11671-010-9732-9'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11671-010-9732-9'


 

This table displays all metadata directly associated to this object as RDF triples.

138 TRIPLES      20 PREDICATES      65 URIs      57 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11671-010-9732-9 schema:about anzsrc-for:02
2 anzsrc-for:0205
3 schema:author Nc0db5b6c1f954ffd9205a3fc84ed77f8
4 schema:datePublished 2010-08-24
5 schema:datePublishedReg 2010-08-24
6 schema:description SiO2 mesoporous molecular sieve SBA-15 with the incorporation of erbium ions is studied as a novel type of nanoscopic composite photoluminescent material in this paper. To enhance the photoluminescence efficiency, two schemes have been used for the incorporation of Er3+ where (1) Er3+ is ligated with bis-(perfluoromethylsulfonyl)-aminate (PMS) forming Er(PMS)x-SBA-15 and (2) Yb3+ is codoped with Er3+ forming Yb-Er-SBA-15. As high as 11.17 × 10−21cm2 of fluorescent cross section at 1534 nm and 88 nm of “effective bandwidth” have been gained. It is a 29.3% boost in fluorescent cross section compared to what has been obtained in conventional silica. The upconversion coefficient in Yb-Er-SBA-15 is relatively small compared to that in other ordinary glass hosts. The increased fluorescent cross section and lowered upconversion coefficient could benefit for the high-gain optical amplifier. Finally, the Judd–Ofelt theory has also been used for the analyses of the optical spectra of Er(PMS)x-SBA-15.
7 schema:genre article
8 schema:isAccessibleForFree true
9 schema:isPartOf N0ff9c7ccb9a44e9fb44cec4e6517cc51
10 N95364464fd3947d382e8438744118471
11 sg:journal.1037280
12 schema:keywords Bi
13 Er3
14 Judd–Ofelt theory
15 SBA-15
16 Yb3
17 Yb–Er
18 amplifier
19 analysis
20 bandwidth
21 boost
22 coefficient
23 conventional silica
24 cross sections
25 effective bandwidth
26 efficiency
27 erbium ions
28 glass host
29 high gain optical amplifier
30 host
31 incorporation
32 ions
33 materials
34 mesoporous SBA-15
35 mesoporous molecular sieve SBA-15
36 molecular sieve SBA-15
37 near-IR photoluminescence
38 novel type
39 optical amplifier
40 optical spectra
41 paper
42 photoluminescence
43 photoluminescence efficiency
44 photoluminescent materials
45 scheme
46 sections
47 silica
48 spectra
49 theory
50 types
51 upconversion coefficient
52 schema:name Highly Efficient Near-IR Photoluminescence of Er3+ Immobilized in Mesoporous SBA-15
53 schema:pagination 1952
54 schema:productId N76a050b9b18243f1b1551cd7164f663e
55 N9c59b9d990784ee6a408de935f7f2be7
56 Ned6c19e9f7d64fdb80082d5d859fe988
57 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006149833
58 https://doi.org/10.1007/s11671-010-9732-9
59 schema:sdDatePublished 2022-12-01T06:28
60 schema:sdLicense https://scigraph.springernature.com/explorer/license/
61 schema:sdPublisher N55a51a43eb1a4db283f643b71c36249a
62 schema:url https://doi.org/10.1007/s11671-010-9732-9
63 sgo:license sg:explorer/license/
64 sgo:sdDataset articles
65 rdf:type schema:ScholarlyArticle
66 N04f83180353641ef997549df0b370632 rdf:first sg:person.015252661671.73
67 rdf:rest N1b98fecdc3d741d89974e6ddcf5dd253
68 N0ff9c7ccb9a44e9fb44cec4e6517cc51 schema:issueNumber 12
69 rdf:type schema:PublicationIssue
70 N1b98fecdc3d741d89974e6ddcf5dd253 rdf:first Ncf02349cad5049cd880f7c4f4018c592
71 rdf:rest Nf0a06d37f31549c0a588150778605613
72 N55a51a43eb1a4db283f643b71c36249a schema:name Springer Nature - SN SciGraph project
73 rdf:type schema:Organization
74 N76a050b9b18243f1b1551cd7164f663e schema:name doi
75 schema:value 10.1007/s11671-010-9732-9
76 rdf:type schema:PropertyValue
77 N8f660cd0745146deb6e924656de41cb7 rdf:first Ne9605e9bf4b649aeba1952bbb3f7dc27
78 rdf:rest rdf:nil
79 N95364464fd3947d382e8438744118471 schema:volumeNumber 5
80 rdf:type schema:PublicationVolume
81 N9c59b9d990784ee6a408de935f7f2be7 schema:name dimensions_id
82 schema:value pub.1006149833
83 rdf:type schema:PropertyValue
84 Nb3766c0d1c6c46d6bab7f088f463c7c9 rdf:first sg:person.07456107721.08
85 rdf:rest N04f83180353641ef997549df0b370632
86 Nc0db5b6c1f954ffd9205a3fc84ed77f8 rdf:first sg:person.011335511425.50
87 rdf:rest Nb3766c0d1c6c46d6bab7f088f463c7c9
88 Ncf02349cad5049cd880f7c4f4018c592 schema:affiliation grid-institutes:grid.22069.3f
89 schema:familyName Zhang
90 schema:givenName X
91 rdf:type schema:Person
92 Ne9605e9bf4b649aeba1952bbb3f7dc27 schema:affiliation grid-institutes:grid.22069.3f
93 schema:familyName Jiang
94 schema:givenName Q
95 rdf:type schema:Person
96 Ned6c19e9f7d64fdb80082d5d859fe988 schema:name pubmed_id
97 schema:value 21170408
98 rdf:type schema:PropertyValue
99 Nf0a06d37f31549c0a588150778605613 rdf:first sg:person.011044314465.07
100 rdf:rest N8f660cd0745146deb6e924656de41cb7
101 anzsrc-for:02 schema:inDefinedTermSet anzsrc-for:
102 schema:name Physical Sciences
103 rdf:type schema:DefinedTerm
104 anzsrc-for:0205 schema:inDefinedTermSet anzsrc-for:
105 schema:name Optical Physics
106 rdf:type schema:DefinedTerm
107 sg:grant.5001306 http://pending.schema.org/fundedItem sg:pub.10.1007/s11671-010-9732-9
108 rdf:type schema:MonetaryGrant
109 sg:journal.1037280 schema:issn 1556-276X
110 1931-7573
111 schema:name Nanoscale Research Letters
112 schema:publisher Springer Nature
113 rdf:type schema:Periodical
114 sg:person.011044314465.07 schema:affiliation grid-institutes:grid.22069.3f
115 schema:familyName Lin
116 schema:givenName L
117 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011044314465.07
118 rdf:type schema:Person
119 sg:person.011335511425.50 schema:affiliation grid-institutes:grid.22069.3f
120 schema:familyName Xue
121 schema:givenName YL
122 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011335511425.50
123 rdf:type schema:Person
124 sg:person.015252661671.73 schema:affiliation grid-institutes:grid.22069.3f
125 schema:familyName Liu
126 schema:givenName Y
127 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015252661671.73
128 rdf:type schema:Person
129 sg:person.07456107721.08 schema:affiliation grid-institutes:grid.22069.3f
130 schema:familyName Wu
131 schema:givenName P
132 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07456107721.08
133 rdf:type schema:Person
134 grid-institutes:grid.22069.3f schema:alternateName Department of Electronic Engineering, East China Normal University, 500 Dongchuan Road, 200241, Shanghai, China
135 Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, 500 Dongchuan Road, 200241, Shanghai, China
136 schema:name Department of Electronic Engineering, East China Normal University, 500 Dongchuan Road, 200241, Shanghai, China
137 Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, 500 Dongchuan Road, 200241, Shanghai, China
138 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...