Composition Control of Low-Volatility Solids Through Chemical Vapor Transport Reactions. I. Theory of Selective Chemical Vapor Transport View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2007-11-28

AUTHORS

A.Yu. Zavrazhnov, I.D. Zartsyn, A.V. Naumov, V.P. Zlomanov, A.V. Davydov

ABSTRACT

A new method is proposed for controlling the composition (nonstoichiometry) of low-volatility inorganic compounds. It is based on the introduction/elimination of one of the components into/from the low-volatility compound using reversible selective chemical vapor transport. The conditions for composition control through selective chemical vapor transport are deduced from the principles of nonequilibrium thermodynamics, in which the direction of the mass-transfer of a component is unambiguously defined by the temperature and composition of the source (T1, x1) and of the sample (T2, x2). This approach can be employed to control the sample composition in a closed vapor-transport system, in which composition x2 of the sample is defined by the fixed values of x1, T1, and T2, provided the steady-state (no mass-transfer) condition is achieved. The effect of steady-state conditions on sample composition is visualized using T2-T1-x2 diagram for the following system: sample (Ga-S phases)-vapor-charge (pure Ga). More... »

PAGES

510-516

References to SciGraph publications

  • 2003-07. Chemical transport reactions as a new variant of the phase composition control in JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION
  • 2001-08-01. Manometric method for the study of P-T-X diagrams in JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION
  • 1963. Thermodynamik der Irreversiblen Prozesse in NONE
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s11669-007-9200-0

    DOI

    http://dx.doi.org/10.1007/s11669-007-9200-0

    DIMENSIONS

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