Contribution to the Zr-rich part of the Zn-Zr phase diagram View Full Text


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Article Info

DATE

2004-10

AUTHORS

Maureen E. Williams, William J. Boettinger, Ursula R. Kattner

ABSTRACT

The reaction of zinc vapor with Zircaloy-4 and nuclear grade zirconium was investigated with various analytical techniques: optical metallography, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Based on the results, the Zr-rich part of the Zn-Zr phase diagram was revised. A eutectoid decomposition of (βZr) occurs at 718±6 °C with a composition of xZr=0.865; this temperature is lower than the previously accepted 750 °C eutectoid. The solubility of Zn in (αZr) was determined to be at xZn=0.0236, a maximum at 725 °C. The intermetallic phase ZnZr2 was observed to occur in samples heat treated at 712 °C and 725 °C, but not in those heat treated at 700 °C and 775 °C. More... »

PAGES

355-363

References to SciGraph publications

  • 1993-08-01. Thermodynamic reevaluation of the Cu-Zn system in JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION
  • 1992-08-01. The Zn-Zr (zinc-zirconium) system in JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s11669-004-0153-2

    DOI

    http://dx.doi.org/10.1007/s11669-004-0153-2

    DIMENSIONS

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