Effect of Composition on Thermoelectric Properties of As-Cast Materials: The Cu12−xCoxSb4S13−ySey Case View Full Text


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Article Info

DATE

2019-04

AUTHORS

Tiago Kalil Cortinhas Alves, Gonçalo Domingues, Elsa Branco Lopes, António Pereira Gonçalves

ABSTRACT

Samples with Cu12−xCoxSb4S13−ySey (0 ≤ x ≤ 2, 0 ≤ y ≤ 1) nominal compositions were prepared by melting the elements under vacuum, followed by slow cooling. The phases formed in this process were identified and characterized by powder x-ray diffraction and scanning electron microscopy observations, complemented with energy-dispersive spectroscopy. All samples have tetrahedrite as the major phase (> 78 vol.%). However, minority phases like skinnerite and chalcostibite are usually also observed, the number and volume of them increasing with the increase of cobalt content. Measurements of electrical resistivity and Seebeck coefficient showed that these materials can present large power factors, with the Cu11.5Co0.5Sb4S12Se sample having a room temperature value higher than 200 μW K−2 m−1. More... »

PAGES

2028-2035

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11664-019-06956-7

DOI

http://dx.doi.org/10.1007/s11664-019-06956-7

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https://app.dimensions.ai/details/publication/pub.1111629722


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