Phase Equilibria and Thermodynamics of Selected Compounds in the Ag–Fe–Sn–S System View Full Text


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Article Info

DATE

2018-09

AUTHORS

Mykola Moroz, Fiseha Tesfaye, Pavlo Demchenko, Myroslava Prokhorenko, Daniel Lindberg, Oleksandr Reshetnyak, Leena Hupa

ABSTRACT

Polythermal sections in the vicinity of the quaternary compounds Ag2FeSnS4 and Ag2FeSn3S8 have been modeled. The mechanism of formation of these quaternary compounds and their thermal stability have been investigated. Measurements of electromotive force allowed calculations of the standard thermodynamic functions ΔG°, ΔH°, and S° of the Ag2FeSnS4 and Ag2FeSn3S8 compounds. Based on calorimetric measurements, the enthalpies of phase transitions of the selected compounds were determined. Furthermore, the heat capacities of both quaternary compounds were estimated by applying different calculation methods. Thermodynamic properties of the quaternary compounds, which are regarded as functional magnetic materials, were analyzed and are discussed in detail. More... »

PAGES

5433-5442

References to SciGraph publications

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  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s11664-018-6430-3

    DOI

    http://dx.doi.org/10.1007/s11664-018-6430-3

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    https://app.dimensions.ai/details/publication/pub.1104898728


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    260 https://www.grid.ac/institutes/grid.77054.31 schema:alternateName Lviv University
    261 schema:name Department of Inorganic Chemistry, Ivan Franko National University of Lviv, Kyryla and Mefodiya 6, 79005, Lviv, Ukraine
    262 Department of Physical and Colloid Chemistry, Ivan Franko National University of Lviv, Kyryla and Mefodiya 6, 79005, Lviv, Ukraine
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