Thermoelectric Properties of the Homologous Compounds Pb5Bi6Se14−xIx (x = 0.0, 0.025, and 0.05) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-06

AUTHORS

S. Sassi, C. Candolfi, A. Dauscher, B. Lenoir

ABSTRACT

Homologous compounds represent an interesting platform for design of new thermoelectric materials. We report herein on synthesis, structural and chemical characterizations, and high-temperature (300 K to 700 K) transport properties measurements of Pb5Bi6Se14−xIx (x = 0.0, 0.025, and 0.05) homologous compounds. Successful insertion of iodine into the crystal structure of Pb5Bi6Se14 was confirmed by its influence on the transport properties. The doping effectiveness of iodine was demonstrated by the increase in the electron concentration, resulting in more pronounced metallic character of transport with respect to undoped Pb5Bi6Se14. The peak ZT value of 0.5, which was achieved at 700 K in the x = 0.025 sample, remains similar to that obtained in Pb5Bi6Se14. More... »

PAGES

3198-3202

References to SciGraph publications

Journal

TITLE

Journal of Electronic Materials

ISSUE

6

VOLUME

47

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11664-018-6061-8

DOI

http://dx.doi.org/10.1007/s11664-018-6061-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1100424842


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Materials Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institut Jean Lamour", 
          "id": "https://www.grid.ac/institutes/grid.461892.0", 
          "name": [
            "Institut Jean Lamour, UMR 7198, CNRS-Universit\u00e9 de Lorraine, 2 all\u00e9e Andr\u00e9 Guinier-Campus ARTEM, 54011, Nancy, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sassi", 
        "givenName": "S.", 
        "id": "sg:person.011001166047.14", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011001166047.14"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institut Jean Lamour", 
          "id": "https://www.grid.ac/institutes/grid.461892.0", 
          "name": [
            "Institut Jean Lamour, UMR 7198, CNRS-Universit\u00e9 de Lorraine, 2 all\u00e9e Andr\u00e9 Guinier-Campus ARTEM, 54011, Nancy, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Candolfi", 
        "givenName": "C.", 
        "id": "sg:person.01230313266.53", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01230313266.53"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institut Jean Lamour", 
          "id": "https://www.grid.ac/institutes/grid.461892.0", 
          "name": [
            "Institut Jean Lamour, UMR 7198, CNRS-Universit\u00e9 de Lorraine, 2 all\u00e9e Andr\u00e9 Guinier-Campus ARTEM, 54011, Nancy, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dauscher", 
        "givenName": "A.", 
        "id": "sg:person.0716277067.05", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0716277067.05"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institut Jean Lamour", 
          "id": "https://www.grid.ac/institutes/grid.461892.0", 
          "name": [
            "Institut Jean Lamour, UMR 7198, CNRS-Universit\u00e9 de Lorraine, 2 all\u00e9e Andr\u00e9 Guinier-Campus ARTEM, 54011, Nancy, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lenoir", 
        "givenName": "B.", 
        "id": "sg:person.01276426466.94", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01276426466.94"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1107/s0021889805005686", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002083386"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0020168508090057", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008677502", 
          "https://doi.org/10.1134/s0020168508090057"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.90.220504", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012437243"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.90.220504", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012437243"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.90.020504", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016537534"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.90.020504", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016537534"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s2075113311050224", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017192904", 
          "https://doi.org/10.1134/s2075113311050224"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/978-1-4899-5723-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019622167", 
          "https://doi.org/10.1007/978-1-4899-5723-8"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/978-1-4899-5723-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019622167", 
          "https://doi.org/10.1007/978-1-4899-5723-8"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.109.236804", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025534765"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.109.236804", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025534765"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c4ta05135a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030711628"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11664-016-4976-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039025081", 
          "https://doi.org/10.1007/s11664-016-4976-5"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11664-016-4976-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039025081", 
          "https://doi.org/10.1007/s11664-016-4976-5"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c1ee01314a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041241572"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jssc.2014.09.034", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044481646"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/acs.inorgchem.6b02118", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055094502"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic501327u", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055574301"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.92.100508", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060647009"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.92.100508", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060647009"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/acs.inorgchem.7b02656", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1099709789"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2018-06", 
    "datePublishedReg": "2018-06-01", 
    "description": "Homologous compounds represent an interesting platform for design of new thermoelectric materials. We report herein on synthesis, structural and chemical characterizations, and high-temperature (300 K to 700 K) transport properties measurements of Pb5Bi6Se14\u2212xIx (x = 0.0, 0.025, and 0.05) homologous compounds. Successful insertion of iodine into the crystal structure of Pb5Bi6Se14 was confirmed by its influence on the transport properties. The doping effectiveness of iodine was demonstrated by the increase in the electron concentration, resulting in more pronounced metallic character of transport with respect to undoped Pb5Bi6Se14. The peak ZT value of 0.5, which was achieved at 700 K in the x = 0.025 sample, remains similar to that obtained in Pb5Bi6Se14.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s11664-018-6061-8", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136213", 
        "issn": [
          "0361-5235", 
          "1543-186X"
        ], 
        "name": "Journal of Electronic Materials", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "47"
      }
    ], 
    "name": "Thermoelectric Properties of the Homologous Compounds Pb5Bi6Se14\u2212xIx (x = 0.0, 0.025, and 0.05)", 
    "pagination": "3198-3202", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "1238756f5dfd2e95eba65666cacf7babf32d307e285c4376a7a110f5ebe877a8"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11664-018-6061-8"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1100424842"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11664-018-6061-8", 
      "https://app.dimensions.ai/details/publication/pub.1100424842"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T18:16", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8675_00000493.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007/s11664-018-6061-8"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11664-018-6061-8'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11664-018-6061-8'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11664-018-6061-8'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11664-018-6061-8'


 

This table displays all metadata directly associated to this object as RDF triples.

131 TRIPLES      21 PREDICATES      42 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11664-018-6061-8 schema:about anzsrc-for:09
2 anzsrc-for:0912
3 schema:author N64f0dbfb12414342a9b528fda0c6e912
4 schema:citation sg:pub.10.1007/978-1-4899-5723-8
5 sg:pub.10.1007/s11664-016-4976-5
6 sg:pub.10.1134/s0020168508090057
7 sg:pub.10.1134/s2075113311050224
8 https://doi.org/10.1016/j.jssc.2014.09.034
9 https://doi.org/10.1021/acs.inorgchem.6b02118
10 https://doi.org/10.1021/acs.inorgchem.7b02656
11 https://doi.org/10.1021/ic501327u
12 https://doi.org/10.1039/c1ee01314a
13 https://doi.org/10.1039/c4ta05135a
14 https://doi.org/10.1103/physrevb.90.020504
15 https://doi.org/10.1103/physrevb.90.220504
16 https://doi.org/10.1103/physrevb.92.100508
17 https://doi.org/10.1103/physrevlett.109.236804
18 https://doi.org/10.1107/s0021889805005686
19 schema:datePublished 2018-06
20 schema:datePublishedReg 2018-06-01
21 schema:description Homologous compounds represent an interesting platform for design of new thermoelectric materials. We report herein on synthesis, structural and chemical characterizations, and high-temperature (300 K to 700 K) transport properties measurements of Pb5Bi6Se14−xIx (x = 0.0, 0.025, and 0.05) homologous compounds. Successful insertion of iodine into the crystal structure of Pb5Bi6Se14 was confirmed by its influence on the transport properties. The doping effectiveness of iodine was demonstrated by the increase in the electron concentration, resulting in more pronounced metallic character of transport with respect to undoped Pb5Bi6Se14. The peak ZT value of 0.5, which was achieved at 700 K in the x = 0.025 sample, remains similar to that obtained in Pb5Bi6Se14.
22 schema:genre research_article
23 schema:inLanguage en
24 schema:isAccessibleForFree false
25 schema:isPartOf N0410b992e22146c69894b743629b801d
26 N370808e342d84d80922f0a6791f9f4ae
27 sg:journal.1136213
28 schema:name Thermoelectric Properties of the Homologous Compounds Pb5Bi6Se14−xIx (x = 0.0, 0.025, and 0.05)
29 schema:pagination 3198-3202
30 schema:productId N9505f93221d44c9da7dec6660f4914fa
31 Nd24558ba5c204f4a826212aa701d9709
32 Nf055deb6a09e4e7baf626541787d870f
33 schema:sameAs https://app.dimensions.ai/details/publication/pub.1100424842
34 https://doi.org/10.1007/s11664-018-6061-8
35 schema:sdDatePublished 2019-04-10T18:16
36 schema:sdLicense https://scigraph.springernature.com/explorer/license/
37 schema:sdPublisher Nec5f9b22c283456fb1bb3b586a7af085
38 schema:url http://link.springer.com/10.1007/s11664-018-6061-8
39 sgo:license sg:explorer/license/
40 sgo:sdDataset articles
41 rdf:type schema:ScholarlyArticle
42 N0410b992e22146c69894b743629b801d schema:volumeNumber 47
43 rdf:type schema:PublicationVolume
44 N370808e342d84d80922f0a6791f9f4ae schema:issueNumber 6
45 rdf:type schema:PublicationIssue
46 N59844731eba14c43a9b67d2a5430f4a2 rdf:first sg:person.01230313266.53
47 rdf:rest N86575921ff2e474b869e0afce0c45ef4
48 N64f0dbfb12414342a9b528fda0c6e912 rdf:first sg:person.011001166047.14
49 rdf:rest N59844731eba14c43a9b67d2a5430f4a2
50 N86575921ff2e474b869e0afce0c45ef4 rdf:first sg:person.0716277067.05
51 rdf:rest Nfd070ff9bd0b455aa3830265f35b7402
52 N9505f93221d44c9da7dec6660f4914fa schema:name dimensions_id
53 schema:value pub.1100424842
54 rdf:type schema:PropertyValue
55 Nd24558ba5c204f4a826212aa701d9709 schema:name doi
56 schema:value 10.1007/s11664-018-6061-8
57 rdf:type schema:PropertyValue
58 Nec5f9b22c283456fb1bb3b586a7af085 schema:name Springer Nature - SN SciGraph project
59 rdf:type schema:Organization
60 Nf055deb6a09e4e7baf626541787d870f schema:name readcube_id
61 schema:value 1238756f5dfd2e95eba65666cacf7babf32d307e285c4376a7a110f5ebe877a8
62 rdf:type schema:PropertyValue
63 Nfd070ff9bd0b455aa3830265f35b7402 rdf:first sg:person.01276426466.94
64 rdf:rest rdf:nil
65 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
66 schema:name Engineering
67 rdf:type schema:DefinedTerm
68 anzsrc-for:0912 schema:inDefinedTermSet anzsrc-for:
69 schema:name Materials Engineering
70 rdf:type schema:DefinedTerm
71 sg:journal.1136213 schema:issn 0361-5235
72 1543-186X
73 schema:name Journal of Electronic Materials
74 rdf:type schema:Periodical
75 sg:person.011001166047.14 schema:affiliation https://www.grid.ac/institutes/grid.461892.0
76 schema:familyName Sassi
77 schema:givenName S.
78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011001166047.14
79 rdf:type schema:Person
80 sg:person.01230313266.53 schema:affiliation https://www.grid.ac/institutes/grid.461892.0
81 schema:familyName Candolfi
82 schema:givenName C.
83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01230313266.53
84 rdf:type schema:Person
85 sg:person.01276426466.94 schema:affiliation https://www.grid.ac/institutes/grid.461892.0
86 schema:familyName Lenoir
87 schema:givenName B.
88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01276426466.94
89 rdf:type schema:Person
90 sg:person.0716277067.05 schema:affiliation https://www.grid.ac/institutes/grid.461892.0
91 schema:familyName Dauscher
92 schema:givenName A.
93 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0716277067.05
94 rdf:type schema:Person
95 sg:pub.10.1007/978-1-4899-5723-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019622167
96 https://doi.org/10.1007/978-1-4899-5723-8
97 rdf:type schema:CreativeWork
98 sg:pub.10.1007/s11664-016-4976-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039025081
99 https://doi.org/10.1007/s11664-016-4976-5
100 rdf:type schema:CreativeWork
101 sg:pub.10.1134/s0020168508090057 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008677502
102 https://doi.org/10.1134/s0020168508090057
103 rdf:type schema:CreativeWork
104 sg:pub.10.1134/s2075113311050224 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017192904
105 https://doi.org/10.1134/s2075113311050224
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1016/j.jssc.2014.09.034 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044481646
108 rdf:type schema:CreativeWork
109 https://doi.org/10.1021/acs.inorgchem.6b02118 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055094502
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1021/acs.inorgchem.7b02656 schema:sameAs https://app.dimensions.ai/details/publication/pub.1099709789
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1021/ic501327u schema:sameAs https://app.dimensions.ai/details/publication/pub.1055574301
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1039/c1ee01314a schema:sameAs https://app.dimensions.ai/details/publication/pub.1041241572
116 rdf:type schema:CreativeWork
117 https://doi.org/10.1039/c4ta05135a schema:sameAs https://app.dimensions.ai/details/publication/pub.1030711628
118 rdf:type schema:CreativeWork
119 https://doi.org/10.1103/physrevb.90.020504 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016537534
120 rdf:type schema:CreativeWork
121 https://doi.org/10.1103/physrevb.90.220504 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012437243
122 rdf:type schema:CreativeWork
123 https://doi.org/10.1103/physrevb.92.100508 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060647009
124 rdf:type schema:CreativeWork
125 https://doi.org/10.1103/physrevlett.109.236804 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025534765
126 rdf:type schema:CreativeWork
127 https://doi.org/10.1107/s0021889805005686 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002083386
128 rdf:type schema:CreativeWork
129 https://www.grid.ac/institutes/grid.461892.0 schema:alternateName Institut Jean Lamour
130 schema:name Institut Jean Lamour, UMR 7198, CNRS-Université de Lorraine, 2 allée André Guinier-Campus ARTEM, 54011, Nancy, France
131 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...