Strain-Induced Enhancement of Eu3+ Emission in Red Phosphor NaMgPO4:Eu3+, Al3+ View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-02

AUTHORS

Yong Gao, Qiwei Long, Rong Nong, Tianman Wang, Yingheng Huang, Sen Liao, Huaxin Zhang

ABSTRACT

A series of (NaMgPO4)0.98−x: Eu0.023+, Alx3+ phosphors were prepared by the solid-state method. X-ray powder diffraction results confirm that the samples contain mixture phases of crystals. The doped effect of Al3+ on the photoluminescence properties of (NaMgPO4)0.98−x: Eu0.023+, Alx3+ phosphors is discussed. The results indicate that two dependent curves of emission relative intensity and strain on Al3+ doping concentration are all Gaussian curves, and a high correlation is observed between emission relative intensity of Eu3+ and strain caused by Al3+. In other words, emission relative intensity of Eu3+ is enhanced with the increase of the strain. The enhanced mechanism of the strain is discussed. In addition, (NaMgPO4)0.98−x: Eu0.023+, Alx3+ phosphors are electric dipole-dominated transition red phosphors. The optimal molar concentration of Al3+ for the samples is 9%, which (NaMgPO4)0.89: Eu0.023+, Al0.093+ is a potential candidate as the red-emitting phosphor for ultraviolet-based white light-emitting diodes. More... »

PAGES

911-916

Journal

TITLE

Journal of Electronic Materials

ISSUE

2

VOLUME

46

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11664-016-4950-2

DOI

http://dx.doi.org/10.1007/s11664-016-4950-2

DIMENSIONS

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