Influence of ZnO Inclusions on the Low-Temperature Thermoelectric Properties of CoSb3 View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-06

AUTHORS

C. Chubilleau, B. Lenoir, P. Masschelein, A. Dauscher, C. Godart

ABSTRACT

CoSb3 composites with different amounts of ZnO nanoparticles (2 wt.% to 12 wt.%) were prepared from nanosized ZnO (commercial) and micron-sized CoSb3 (obtained via solid-state reaction) particles mixed in solution and freeze dried. The resulting powders were densified by spark plasma sintering. The samples were characterized by x-ray diffraction and scanning electron microscopy. It was found that ZnO forms micron-sized clusters at the grain boundaries of the matrix material. The thermoelectric properties (electrical resistivity, thermopower, and thermal conductivity) were measured in the 2 K to 300 K temperature range. Both the electrical and thermal conductivities were observed to decrease with increasing ZnO content. The dimensionless figure of merit ZT was improved by up to 30% at 300 K for the sample containing 2 wt.% ZnO. More... »

PAGES

1181-1185

References to SciGraph publications

  • 2010-09. Thermal Conductivity Reduction in CoSb3–CeO2 Nanocomposites in JOURNAL OF ELECTRONIC MATERIALS
  • Journal

    TITLE

    Journal of Electronic Materials

    ISSUE

    6

    VOLUME

    41

    Author Affiliations

    Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s11664-011-1866-8

    DOI

    http://dx.doi.org/10.1007/s11664-011-1866-8

    DIMENSIONS

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