Low-Temperature Transport Properties of InxFeyCo4−ySb12 View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-09

AUTHORS

J. Leszczynski, A. Dauscher, P. Masschelein, B. Lenoir

ABSTRACT

Interesting results for cobalt triantimonide partially filled with indium have encouraged us to explore skutterudites filled with higher indium fractions. For pure InxCo4Sb12, the fraction of voids filled is limited to about x = 0.25. To enable the insertion of more indium atoms, charge compensation is necessary. In this work, we studied the skutterudite compound InxFeyCo4−ySb12 partially filled with indium, where iron substitution for cobalt was employed for charge compensation. Polycrystalline samples were prepared by direct reaction of constituents. Structural and chemical characterization were accomplished by x-ray diffraction and energy-dispersive x-ray spectroscopy. Electrical resistivity, thermoelectric power, and thermal conductivity were measured between 2 K and 350 K. The influence of indium and iron on the charge-carrier transport properties and thermal conductivity in InxFeyCo4−ySb12 compounds is presented and discussed. More... »

PAGES

1764-1768

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11664-010-1117-4

DOI

http://dx.doi.org/10.1007/s11664-010-1117-4

DIMENSIONS

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