Oxygen Deficiency and Hydrogen Turn ZnO Red View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-05

AUTHORS

M. H. Weber, N. S. Parmar, K. A. Jones, K. G. Lynn

ABSTRACT

The effect of hydrogen on ZnO while annealing at 1370 K under oxygen-poor conditions with excess Zn vapor or Ti metal is studied. ZnO turns red only when hydrogen is present in a complex with oxygen vacancies. A practical method is described to remove hydrogen from ZnO in a sealed ampoule and to bind it to Ti metal. Hydrogen coupled to an oxygen vacancy is the simplest defect to explain the observations. The coloration is reversible at 1370 K by adding or removing hydrogen, consistent with an activation energy >1.5 eV. In red ZnO Hall data show a shallow donor level around 45 meV. More... »

PAGES

573-576

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11664-010-1115-6

DOI

http://dx.doi.org/10.1007/s11664-010-1115-6

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https://app.dimensions.ai/details/publication/pub.1026128810


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