Crystal Structure and High-Temperature Thermoelectric Properties of the Mo3−xRuxSb7 Compounds View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-09

AUTHORS

C. Candolfi, J. Leszczynski, P. Masschelein, C. Chubilleau, B. Lenoir, A. Dauscher, E. Guilmeau, J. Hejtmanek, S. J. Clarke, R. I. Smith

ABSTRACT

Zintl phases are currently receiving great attention for their thermoelectric potential typified by the discovery of a high ZT value in Yb14MnSb11-based compounds. Herein, we report on the crystallographic characterization via neutron and x-ray diffraction experiments, and on the thermoelectric properties measured in the 300 K to 1000 K temperature range, of Mo3Sb7 and its isostructural compounds Mo3−xRuxSb7. Even though Mo3Sb7 displays rather high ZT values given its metallic character, the partial substitution of Mo by Ru substantially improves its thermoelectric properties, resulting in a ZT value of ∼0.45 at 1000 K for x = 0.8. More... »

PAGES

2132-2135

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11664-009-0981-2

DOI

http://dx.doi.org/10.1007/s11664-009-0981-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1010777805


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