Experimental Study of the Cu2O-FeOx-CaO System in Equilibrium With Metallic Copper at 1200 °C to 1300 °C and at P(O2)s ... View Full Text


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Article Info

DATE

2022-04-28

AUTHORS

Svetlana Sineva, Denis Shishin, Roman Starykh, Maksym Shevchenko, Evgueni Jak

ABSTRACT

The experimental study of the phase equilibria between calcium ferrite slag, metallic copper, spinel and/or dicalcium ferrite in the Cu2O-FeOx-CaO system has been carried out. Effects of temperature, oxygen partial pressure and Fe/CaO ratio on phase assemblages and compositions have been estimated. The advanced experimental technique including high-temperature equilibration on primary phase substrates, rapid quenching of the samples and quantitative measurements of equilibrated phase compositions using electron probe X-ray microanalysis has been applied. Spinel and dicalcium ferrite substrates have been specially designed to study phase equilibria at certain primary phase fields. Obtained experimental results have been compared with thermodynamic assessment of the Cu2O-FeOx-CaO system and available literature data. More... »

PAGES

1-10

References to SciGraph publications

  • 2019-01-02. Experimental Liquidus Studies of the Pb-Fe-Ca-O System in Air in JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION
  • 2019-03-01. Integrated Experimental and Thermodynamic Modeling Study of the Effects of Al2O3, CaO, and MgO on Slag–Matte Equilibria in the Cu-Fe-O-S-Si-(Al, Ca, Mg) System in JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION
  • 1993-04. The solubility of copper in lime-saturated and calcium ferrite-saturated liquid iron oxide in METALLURGICAL AND MATERIALS TRANSACTIONS B
  • 2008-03-08. Phase Equilibria in Ferrous Calcium Silicate Slags: Part III. Copper-Saturated Slag at 1250 °C and 1300 °C at an Oxygen Partial Pressure of 10−6 atm in METALLURGICAL AND MATERIALS TRANSACTIONS B
  • 2004-04. Liquidus temperatures in calcium ferrite slags in equilibrium with molten copper in METALLURGICAL AND MATERIALS TRANSACTIONS B
  • 2018-08-19. Multicomponent Thermodynamic Databases for Complex Non-ferrous Pyrometallurgical Processes in EXTRACTION 2018
  • 2009-07-14. Liquidus Temperatures in the “Cu2O”-FeO-Fe2O3-CaO System at Molten Metallic Copper Saturation in METALLURGICAL AND MATERIALS TRANSACTIONS B
  • 2009-07-14. Experimental Techniques for Investigating Calcium Ferrite Slags at Metallic Copper Saturation and Application to the Systems “Cu2O”-“Fe2O3” and “Cu2O”-CaO at Metallic Copper Saturation in METALLURGICAL AND MATERIALS TRANSACTIONS B
  • 2009-09-24. Liquidus Temperatures in the “Cu2O”-FeO-Fe2O3-CaO-SiO2 System at Metallic Copper Saturation, at Fixed Oxygen Partial Pressures, and in Equilibrium with Spinel or Dicalcium Ferrite at 1200 °C and 1250 °C in METALLURGICAL AND MATERIALS TRANSACTIONS B
  • 2014-08-13. Copper Solubility and Redox Equilibria in Magnesia Saturated CaO-CuOx-FeOx Slags in METALLURGICAL AND MATERIALS TRANSACTIONS B
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    URI

    http://scigraph.springernature.com/pub.10.1007/s11663-022-02529-y

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    http://dx.doi.org/10.1007/s11663-022-02529-y

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