Solidification of Nb-bearing superalloys: Part I. Reaction sequences View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1998-11

AUTHORS

J. N. DuPont, M. R. Notis, A. R. Marder, C. V. Robino, J. R. Michael

ABSTRACT

The solidification reaction sequences of experimental superalloys containing systematic variations in Fe, Nb, Si, and C were studied using differential thermal analysis (DTA) and microstructural characterization techniques. The reaction sequences responsible for microstructural development were found to be similar to those expected in the Ni-Nb-C ternary system and commercial superalloys of comparable composition. The solute-rich interdendritic liquid generally exhibited two eutectic-type reactions at the terminal stages of solidification: L → (γ+NbC) and L → (γ+Laves). The Ni-base alloys with a high C/Nb ratio represented the only exception to this general solidification sequence. This group of alloys terminated solidification with the L → (γ + NbC) reaction and did not exhibit the γ/Laves constituent. At similar levels of solute elements (Nb, Si, and C), the Fe-base alloys always formed more of the γ/Laves eutectic-type constituent than the corresponding Ni-base alloys. Silicon additions also increased the amount of the γ/Laves constituent that formed in the assolidified microstructure, while C additions promoted formation of γ/NbC. The influence of Nb was dependent on the C content of the alloy. When the C content was low, Nb additions generally promoted formation of γ/Laves, while Nb additions to alloys with high C led to formation of the γ/NbC constituent. The results of this work are combined with quantitative analyses for developing γ-Nb-C pseudoternary solidification diagrams in a companion article. More... »

PAGES

2785-2796

References to SciGraph publications

  • 1993-05. Microstructural characterization of INCOLOY 903 weldments in METALLURGICAL AND MATERIALS TRANSACTIONS A
  • 1981-06. Solute redistribution during solidification with rapid solid state diffusion in METALLURGICAL TRANSACTIONS A
  • 1998-11. Solidification of Nb-bearing superalloys: Part II. Pseudoternary solidification surfaces in METALLURGICAL AND MATERIALS TRANSACTIONS A
  • 1989-10. INCONEL 718: A solidification diagram in METALLURGICAL TRANSACTIONS A
  • 1988-09. A melting and solidification study of alloy 625 in METALLURGICAL TRANSACTIONS A
  • 1990-01. A comparison of the solidification behavior of INCOLOY 909 and INCONEL 718 in METALLURGICAL TRANSACTIONS A
  • 1996-11. Solidification of an alloy 625 weld overlay in METALLURGICAL AND MATERIALS TRANSACTIONS A
  • 1989-12. Solidification of the nickel-base superalloy 718: A phase diagram approach in METALLURGICAL TRANSACTIONS A
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s11661-998-0319-3

    DOI

    http://dx.doi.org/10.1007/s11661-998-0319-3

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1051386323


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