Influence of Minor Cr-Additions to the Growth of Columnar Dendrites in Al-Zn Alloys: Influence of Icosahedral Short Range Order in ... View Full Text


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Article Info

DATE

2019-10-25

AUTHORS

Güven Kurtuldu, Philippe Jarry, Michel Rappaz

ABSTRACT

The effect of minute Cr additions on dendritic growth directions in Al-20 wt pct Zn alloy has been investigated. As first evidenced by Gonzales and Rappaz (Metall Mater Trans A 37:2797–2806, 2006) Al-Zn alloys exhibit a Dendrite Orientation Transition (DOT), from 〈100〉 below 25 wt pct Zn to 〈110〉 above 60 wt pct, regardless of the solidification speed. The DOT has been interpreted as a modification of the solid–liquid interfacial energy anisotropy (Gonzales and Rappaz, 2006; Haxhimali et al. in Nat Mater 5:660–664, 2006). However, 0.02 to 0.1 wt pct addition of Cr in Al-20 wt pct Zn drastically modifies the dendrite trunk direction from 〈100〉 to 〈110〉 at low solidification speed, typically 200 μm/s. Even more surprising, 〈100〉 dendrite trunks are retrieved in Al-20 wt pct Zn-0.1 wt pct Cr when the speed is increased to 1000 μm/s, but with the concurrent formation of twinned dendrites. Minute additions of Cr have been reported recently to promote icosahedral short range order (ISRO) in liquid Al-Zn, thus reducing the atomic mobility (Kurtuldu et al. in Acta Mater 115:423–433, 2016) and modifying the nucleation kinetics (Kurtuldu et al. in Acta Mater 61:7098–7108, 2013). The present results indicate that ISRO also modifies the attachment kinetics of icosahedral clusters rather than individual atoms, and is most likely responsible of growth direction change in Al-Zn-Cr alloy and of twinned dendrites formation. More... »

PAGES

279-288

References to SciGraph publications

  • 2008-05-22. Grain Selection and Texture Evolution in Directionally Solidified Al-Zn Alloys in METALLURGICAL AND MATERIALS TRANSACTIONS A
  • 2018-09-11. Influence of Minor Additions on Icosahedral Short-Range Order (ISRO) and Its Consequences on Nucleation and Solidification Growth Kinetics in fcc Alloys in TRANSACTIONS OF THE INDIAN INSTITUTE OF METALS
  • 2002-07. Experimental Measurement of Anisotropy in Crystal-Melt Interfacial Energy in INTERFACE SCIENCE
  • 2006-09. Dendrite growth directions in aluminum-zinc alloys in METALLURGICAL AND MATERIALS TRANSACTIONS A
  • 2015-07-21. Quasicrystal-Enhanced Nucleation During the Solidification of fcc Metallic Alloys: A Tentative Thermodynamic Approach in JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION
  • 2006-07-09. Orientation selection in dendritic evolution in NATURE MATERIALS
  • 2015-02-26. Thermodynamic Aspects of Homogeneous Nucleation Enhanced by Icosahedral Short Range Order in Liquid Fcc-Type Alloys in JOM
  • 2019-02-25. Influence of Ir Additions and Icosahedral Short Range Order (ISRO) on Nucleation and Growth Kinetics in Au-20.5Wt Pct Cu-4.5Wt PctAg Alloy in METALLURGICAL AND MATERIALS TRANSACTIONS A
  • 2013-09-05. Dendritic Growth Morphologies in Al-Zn Alloys—Part II: Phase-Field Computations in METALLURGICAL AND MATERIALS TRANSACTIONS A
  • 2013-08-20. Dendritic Growth Morphologies in Al-Zn Alloys—Part I: X-ray Tomographic Microscopy in METALLURGICAL AND MATERIALS TRANSACTIONS A
  • 2007-07-09. Dendrite growth directions and morphology in the directional solidification of anisotropic materials in JOM
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