Oxidation Behavior of a Pd43Cu27Ni10P20 Bulk Metallic Glass and Foam in Dry Air View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2010-05-13

AUTHORS

W. Kai, I.F. Ren, B. Barnard, P.K. Liaw, M.D. Demetriou, W.L. Johnson

ABSTRACT

The oxidation behavior of both Pd43Cu27Ni10P20 bulk metallic glass (Pd4-BMG) and its amorphous foam containing 45 pct porosity (Pd4-AF) was investigated over the temperature range of 343 K (70 °C) to 623 K (350 °C) in dry air. The results showed that virtually no oxidation occurred in the Pd4-BMG at T < 523 K (250 °C), revealing the alloy’s favorable oxidation resistance in this temperature range. In addition, the oxidation kinetics at T ≥ 523 K (250 °C) followed a parabolic-rate law, and the parabolic-rate constants (kp values) generally increased with temperature. It was found that the oxidation kp values of the Pd4-AF are slightly lower than those of the Pd4-BMG, indicating that the porous structure contributes to improving the overall oxidation resistance. The scale formed on the alloys was composed exclusively of CuO at T ≥ 548 K (275 °C), whose thickness gradually increased with increasing temperature. In addition, the amorphous structure remained unchanged at T ≤ 548 K (275 °C), while a triplex-phase structure developed after the oxidation at higher temperatures, consisting of Pd2Ni2P, Cu3P, and Pd3P. More... »

PAGES

1720-1725

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11661-010-0231-5

DOI

http://dx.doi.org/10.1007/s11661-010-0231-5

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https://app.dimensions.ai/details/publication/pub.1041615931


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