Microstructure and Magnetic Properties in Fe61Co9−xZr8Mo5WxB17 (0 ≤ x ≤ 3) Glasses and Glass-Matrix Composites View Full Text


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Article Info

DATE

2009-01-13

AUTHORS

W.-M. Wang, W.X. Zhang, A. Gebert, S. Roth, C. Mickel, L. Schultz

ABSTRACT

By systematically investigating the Fe61Co9−xZr8Mo5WxB17 (0 ≤ x ≤ 3) melt-spun ribbons and copper-mold cast cylinders with 2-mm diameter, we attempt to discover the effect of tungsten on the microstructure and magnetic properties of the Fe-based glass formers. It was found that all as-spun ribbons are fully amorphous and their characteristic distance δa has an increasing tendency with tungsten content (cW). The precipitates in the as-cast cylinders change from the ferromagnetic phases (Fe23Zr6 + Fe2Zr + Fe2B + Fe8B) plus α-Fe to the nonmagnetic phases (ZrB12 + W2B5) plus α-Fe with increasing cW. The averaged characteristic distance δc of the precipitates formed in the casting and annealing processes increases with cW, consistent with the δa of the ribbons. The temperature and heat of the first crystallization for the as-prepared ribbons and cylinders (Tp1 and ΔH1) also increase with cW. The magnetization and Curie temperature of the as-prepared ribbons and cylinders decrease with cW, while the coercivity of the as-prepared samples is obviously dependent on the volume fraction of the precipitates formed in the casting process (CP). These results indicate that tungsten can tune the fractions of the face-centered-cubic/random-close-packed (fcc/rcp) and body-centered-cubic (bcc) Fe-rich structural units in the undercooled melts of the Fe-based glasses. More... »

PAGES

511-521

References to SciGraph publications

  • 2006-04-01. Localized heating and fracture criterion for bulk metallic glasses in JOURNAL OF MATERIALS RESEARCH
  • 2006-03-26. The shapes of cooperatively rearranging regions in glass-forming liquids in NATURE PHYSICS
  • 1994-01. Crystallization of amorphous Fe78B13Si9 in JOURNAL OF MATERIALS SCIENCE
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    http://scigraph.springernature.com/pub.10.1007/s11661-008-9706-z

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    http://dx.doi.org/10.1007/s11661-008-9706-z

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    https://app.dimensions.ai/details/publication/pub.1018743841


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