Phase Transformations and Microstructural Evolution of Mo-Bearing Stainless Steels View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-01

AUTHORS

T.D. ANDERSON, J.N. DuPONT, M.J. PERRICONE, A.R. MARDER

ABSTRACT

The good corrosion resistance of superaustenitic stainless steel (SASS) alloys has been shown to be a direct consequence of high concentrations of Mo, which can have a significant effect on the microstructural development of welds in these alloys. In this research, the microstructural development of welds in the Fe-Ni-Cr-Mo system was analyzed over a wide variety of Cr/Ni ratios and Mo contents. The system was first simulated by construction of multicomponent phase diagrams using the CALPHAD technique. Data from vertical sections of these diagrams are presented over a wide compositional range to produce diagrams that can be used as a guide to understand the influence of composition on microstructural development. A large number of experimental alloys were then prepared via arc-button melting for comparison with the diagrams. Each alloy was characterized using various microscopy techniques. The expected δ-ferrite and γ-austenite phases were accompanied by martensite at low Cr/Ni ratios and by σ phase at high Mo contents. A total of 20 possible phase transformation sequences are proposed, resulting in various amounts and morphologies of the γ, δ, σ, and martensite phases. The results were used to construct a map of expected phase transformation sequence and resultant microstructure as a function of composition. The results of this work provide a working guideline for future base metal and filler metal development of this class of materials. More... »

PAGES

86-99

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11661-006-9010-8

DOI

http://dx.doi.org/10.1007/s11661-006-9010-8

DIMENSIONS

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