A novel experiment for the study of substrate-induced nucleation in metallic alloys: Application to Zn-Al View Full Text


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Article Info

DATE

2004-11

AUTHORS

A. Quiroga, M. Rappaz, S. Claessens, B. Gay

ABSTRACT

In order to investigate the nucleation and growth mechanisms of Zn-0.2 wt pct Al grains in thin coatings deposited on steel sheets by hot dipping, a new directional solidification experiment has been specifically designed with a steel substrate immersed into the melt. The competition (CTG) between regular columnar (C) grains growing parallel to the thermal gradient and transverse grains (TGs) nucleated on the sheet surface and growing transversely has been observed in longitudinal sections of Zn-0.2 wt pct Al (-Sb) alloys. Without Sb, the CTG began at midheight of the casting, whereas with Sb, no CTG was found. A simple CTG criterion similar to that of Hunt for the columnar-to-equiaxed Transition (CET) was derived. The calculated extension of the TGs was successfully compared with that measured on micrographs reconstructed from electron backscattered diffraction (EBSD) measurements. This indicated that the critical nucleation undercooling for the formation of Zn-0.2 wt pct Al grains on the steel sheet is about 0.7 K and that Sb poisons these available nucleation sites. More... »

PAGES

3543-3550

References to SciGraph publications

  • 1990-06. Spangle formation in galvanized sheet steel coatings in METALLURGICAL AND MATERIALS TRANSACTIONS B
  • 1981-06. Solute redistribution during solidification with rapid solid state diffusion in METALLURGICAL AND MATERIALS TRANSACTIONS A
  • 2000-06. Determination of thermophysical properties and boundary conditions of direct chill-cast aluminum alloys using inverse methods in METALLURGICAL AND MATERIALS TRANSACTIONS A
  • 1999-12. A three-dimensional cellular automation-finite element model for the prediction of solidification grain structures in METALLURGICAL AND MATERIALS TRANSACTIONS A
  • 1998-02. Solidification and spangle formation of hot-dip-galvanized zinc coatings in METALLURGICAL AND MATERIALS TRANSACTIONS A
  • 2002-08. Orientation domains and texture in hot-dipped galvanized coatings in METALLURGICAL AND MATERIALS TRANSACTIONS A
  • 2002-08. Numerical simulation of Zn coating solidification in METALLURGICAL AND MATERIALS TRANSACTIONS A
  • 2000-02. Application of the phase-field method to the solidification of hot-dipped galvanized coatings in METALLURGICAL AND MATERIALS TRANSACTIONS A
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s11661-004-0191-8

    DOI

    http://dx.doi.org/10.1007/s11661-004-0191-8

    DIMENSIONS

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