The composite of Ketjen black and Ti4O7-modified separator for enhancing the electrochemical properties of lithium sulfur battery View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2021-03-18

AUTHORS

Xiao Wu, Shanshan Yao, Mingquan Liu, Shengli Pang, Xiangqian Shen, Tianbao Li, Shibiao Qin

ABSTRACT

The large-scale manufacturing of lithium sulfur (Li-S) battery has been long hampered by the rapid capacity degradation and short cycle life, which is primarily attributed to the soluble polysulfides and subsequent continuing shuttling effect. The separator modification as a simple and effective technique has been extensively applied in Li-S batteries to solve inherent defects. Herein, the composite of Ketjen black (KB) and Ti4O7 was synthetized by carbothermal reduction and made into KB/Ti4O7-modified separator. The multifunctional layer can improve utilization of active substances and restrain shuttling effect by forming synergistic effect of physical obstruct and chemisorption for polysulides. The cell using KB/Ti4O7 separator exhibits enhanced electrochemical properties reflecting in higher specific capacity (1074 mAh g-1 at 1C) and longer cycling life (836 mAh g-1 after 100 cycles). The above results indicate that the composite of carbon and metallic oxide modified separator is pretty suitable for advanced Li-S battery. More... »

PAGES

2397-2408

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11581-021-04004-1

DOI

http://dx.doi.org/10.1007/s11581-021-04004-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1136507639


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