Yttrium-substituted LiNi0.3Mn0.3Co0.3O2 cathode material with enhanced cycling stability for rechargeable lithium-ion batteries View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-03

AUTHORS

K. Kalaiselvi, G. Paruthimal Kalaignan

ABSTRACT

The layered structure of LiNi1/3Mn1/3Co1/3 – xYxO2 with different concentration of yttrium substituted (x = 0.00, 0.01, 0.03, and 0.05) cathode material was synthesized using the sol-gel method, followed by high-temperature calcination process. The influence of Y substitution on the microstructure and electrochemical performances of the prepared materials were investigated using X-ray diffraction (XRD), transmission electron microscopy (TEM), cyclic voltammetry and galvanostatic charge/discharge test respectively. The XRD result showed that the LiNi1/3Mn1/3Co1/3 − xYxO2 has a well-ordered hexagonal α-NaFeO2 structure with high crystallinity. The surface morphology of pristine material and Y-doped electrode material revealed the spherical-shaped particles which are uniformly distributed. The cyclic voltammograms of the proposed cathode material also yield a well-defined redox peaks at their corresponding potentials. As the doping of yttrium increases, the discharge capacity also increases attributed to the superior capacity retention at high voltage (4.2 V) even after 100 cycles. Therefore, this composition is a promising cathode material for lithium-ion batteries. Graphical abstract Graphical abstract More... »

PAGES

991-997

Journal

TITLE

Ionics

ISSUE

3

VOLUME

25

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11581-018-2754-5

DOI

http://dx.doi.org/10.1007/s11581-018-2754-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1107668153


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Alagappa University", 
          "id": "https://www.grid.ac/institutes/grid.411312.4", 
          "name": [
            "Advanced Lithium-ion Battery Research Lab, Department of Industrial Chemistry, Alagappa University, 630 003, Karaikudi, Tamilnadu, India"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kalaiselvi", 
        "givenName": "K.", 
        "id": "sg:person.011117155557.51", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011117155557.51"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Alagappa University", 
          "id": "https://www.grid.ac/institutes/grid.411312.4", 
          "name": [
            "Advanced Lithium-ion Battery Research Lab, Department of Industrial Chemistry, Alagappa University, 630 003, Karaikudi, Tamilnadu, India"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kalaignan", 
        "givenName": "G. Paruthimal", 
        "id": "sg:person.0576510074.57", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0576510074.57"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1021/jacs.5b04690", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001270743"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s1388-2481(99)00127-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004432381"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jpowsour.2013.04.155", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004679202"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.elecom.2006.07.014", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011614659"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ar800229g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015166112"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ar800229g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015166112"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c3ta10980a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017487144"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c5ra18457f", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021779355"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.3390/ma6031028", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022730655"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c1ee01598b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024398491"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s1003-6326(10)60056-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024890810"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0378-7753(01)00683-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029114208"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nl402237u", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039516668"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11581-014-1098-z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039991632", 
          "https://doi.org/10.1007/s11581-014-1098-z"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10008-013-2301-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040963106", 
          "https://doi.org/10.1007/s10008-013-2301-2"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jpowsour.2008.08.014", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042061922"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0013-4686(02)00593-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042220992"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0013-4686(02)00593-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042220992"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jpowsour.2014.05.027", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045599089"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.4236/msce.2014.212003", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047538085"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/acs.accounts.7b00031", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1084121326"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.egypro.2017.03.672", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1085746936"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.20964/2018.10.34", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1106445855"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2019-03", 
    "datePublishedReg": "2019-03-01", 
    "description": "The layered structure of LiNi1/3Mn1/3Co1/3 \u2013 xYxO2 with different concentration of yttrium substituted (x = 0.00, 0.01, 0.03, and 0.05) cathode material was synthesized using the sol-gel method, followed by high-temperature calcination process. The influence of Y substitution on the microstructure and electrochemical performances of the prepared materials were investigated using X-ray diffraction (XRD), transmission electron microscopy (TEM), cyclic voltammetry and galvanostatic charge/discharge test respectively. The XRD result showed that the LiNi1/3Mn1/3Co1/3 \u2212 xYxO2 has a well-ordered hexagonal \u03b1-NaFeO2 structure with high crystallinity. The surface morphology of pristine material and Y-doped electrode material revealed the spherical-shaped particles which are uniformly distributed. The cyclic voltammograms of the proposed cathode material also yield a well-defined redox peaks at their corresponding potentials. As the doping of yttrium increases, the discharge capacity also increases attributed to the superior capacity retention at high voltage (4.2 V) even after 100 cycles. Therefore, this composition is a promising cathode material for lithium-ion batteries. Graphical abstract Graphical abstract", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s11581-018-2754-5", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1041836", 
        "issn": [
          "0947-7047", 
          "1862-0760"
        ], 
        "name": "Ionics", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "25"
      }
    ], 
    "name": "Yttrium-substituted LiNi0.3Mn0.3Co0.3O2 cathode material with enhanced cycling stability for rechargeable lithium-ion batteries", 
    "pagination": "991-997", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "f5c4723aa80d5b0a19d5b98a94db43b9b30ada764a44d8b0f63ba7aad6f55055"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11581-018-2754-5"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1107668153"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11581-018-2754-5", 
      "https://app.dimensions.ai/details/publication/pub.1107668153"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T11:55", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000359_0000000359/records_29207_00000003.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://link.springer.com/10.1007%2Fs11581-018-2754-5"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11581-018-2754-5'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11581-018-2754-5'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11581-018-2754-5'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11581-018-2754-5'


 

This table displays all metadata directly associated to this object as RDF triples.

133 TRIPLES      21 PREDICATES      48 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11581-018-2754-5 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N05928ff5449946e0a208c27123b62e96
4 schema:citation sg:pub.10.1007/s10008-013-2301-2
5 sg:pub.10.1007/s11581-014-1098-z
6 https://doi.org/10.1016/j.egypro.2017.03.672
7 https://doi.org/10.1016/j.elecom.2006.07.014
8 https://doi.org/10.1016/j.jpowsour.2008.08.014
9 https://doi.org/10.1016/j.jpowsour.2013.04.155
10 https://doi.org/10.1016/j.jpowsour.2014.05.027
11 https://doi.org/10.1016/s0013-4686(02)00593-5
12 https://doi.org/10.1016/s0378-7753(01)00683-8
13 https://doi.org/10.1016/s1003-6326(10)60056-8
14 https://doi.org/10.1016/s1388-2481(99)00127-7
15 https://doi.org/10.1021/acs.accounts.7b00031
16 https://doi.org/10.1021/ar800229g
17 https://doi.org/10.1021/jacs.5b04690
18 https://doi.org/10.1021/nl402237u
19 https://doi.org/10.1039/c1ee01598b
20 https://doi.org/10.1039/c3ta10980a
21 https://doi.org/10.1039/c5ra18457f
22 https://doi.org/10.20964/2018.10.34
23 https://doi.org/10.3390/ma6031028
24 https://doi.org/10.4236/msce.2014.212003
25 schema:datePublished 2019-03
26 schema:datePublishedReg 2019-03-01
27 schema:description The layered structure of LiNi1/3Mn1/3Co1/3 – xYxO2 with different concentration of yttrium substituted (x = 0.00, 0.01, 0.03, and 0.05) cathode material was synthesized using the sol-gel method, followed by high-temperature calcination process. The influence of Y substitution on the microstructure and electrochemical performances of the prepared materials were investigated using X-ray diffraction (XRD), transmission electron microscopy (TEM), cyclic voltammetry and galvanostatic charge/discharge test respectively. The XRD result showed that the LiNi1/3Mn1/3Co1/3 − xYxO2 has a well-ordered hexagonal α-NaFeO2 structure with high crystallinity. The surface morphology of pristine material and Y-doped electrode material revealed the spherical-shaped particles which are uniformly distributed. The cyclic voltammograms of the proposed cathode material also yield a well-defined redox peaks at their corresponding potentials. As the doping of yttrium increases, the discharge capacity also increases attributed to the superior capacity retention at high voltage (4.2 V) even after 100 cycles. Therefore, this composition is a promising cathode material for lithium-ion batteries. Graphical abstract Graphical abstract
28 schema:genre research_article
29 schema:inLanguage en
30 schema:isAccessibleForFree false
31 schema:isPartOf N18f5354d185840fd8682a4e28b738873
32 Ncfd9f478cdcd42a0b38eb7444fa9cb6c
33 sg:journal.1041836
34 schema:name Yttrium-substituted LiNi0.3Mn0.3Co0.3O2 cathode material with enhanced cycling stability for rechargeable lithium-ion batteries
35 schema:pagination 991-997
36 schema:productId N8154cd51a6b34350ac5422701d468d63
37 Na5c06accf6324a589e9b4d78065f85b3
38 Nb675669edebb430da80241f722f8f0eb
39 schema:sameAs https://app.dimensions.ai/details/publication/pub.1107668153
40 https://doi.org/10.1007/s11581-018-2754-5
41 schema:sdDatePublished 2019-04-11T11:55
42 schema:sdLicense https://scigraph.springernature.com/explorer/license/
43 schema:sdPublisher N8dbad45f419f4e7494e1ced1602d6fd5
44 schema:url https://link.springer.com/10.1007%2Fs11581-018-2754-5
45 sgo:license sg:explorer/license/
46 sgo:sdDataset articles
47 rdf:type schema:ScholarlyArticle
48 N05928ff5449946e0a208c27123b62e96 rdf:first sg:person.011117155557.51
49 rdf:rest Nd0eda935b7c7443f8bfcd321e7eef5fa
50 N18f5354d185840fd8682a4e28b738873 schema:issueNumber 3
51 rdf:type schema:PublicationIssue
52 N8154cd51a6b34350ac5422701d468d63 schema:name readcube_id
53 schema:value f5c4723aa80d5b0a19d5b98a94db43b9b30ada764a44d8b0f63ba7aad6f55055
54 rdf:type schema:PropertyValue
55 N8dbad45f419f4e7494e1ced1602d6fd5 schema:name Springer Nature - SN SciGraph project
56 rdf:type schema:Organization
57 Na5c06accf6324a589e9b4d78065f85b3 schema:name doi
58 schema:value 10.1007/s11581-018-2754-5
59 rdf:type schema:PropertyValue
60 Nb675669edebb430da80241f722f8f0eb schema:name dimensions_id
61 schema:value pub.1107668153
62 rdf:type schema:PropertyValue
63 Ncfd9f478cdcd42a0b38eb7444fa9cb6c schema:volumeNumber 25
64 rdf:type schema:PublicationVolume
65 Nd0eda935b7c7443f8bfcd321e7eef5fa rdf:first sg:person.0576510074.57
66 rdf:rest rdf:nil
67 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
68 schema:name Chemical Sciences
69 rdf:type schema:DefinedTerm
70 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
71 schema:name Physical Chemistry (incl. Structural)
72 rdf:type schema:DefinedTerm
73 sg:journal.1041836 schema:issn 0947-7047
74 1862-0760
75 schema:name Ionics
76 rdf:type schema:Periodical
77 sg:person.011117155557.51 schema:affiliation https://www.grid.ac/institutes/grid.411312.4
78 schema:familyName Kalaiselvi
79 schema:givenName K.
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011117155557.51
81 rdf:type schema:Person
82 sg:person.0576510074.57 schema:affiliation https://www.grid.ac/institutes/grid.411312.4
83 schema:familyName Kalaignan
84 schema:givenName G. Paruthimal
85 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0576510074.57
86 rdf:type schema:Person
87 sg:pub.10.1007/s10008-013-2301-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040963106
88 https://doi.org/10.1007/s10008-013-2301-2
89 rdf:type schema:CreativeWork
90 sg:pub.10.1007/s11581-014-1098-z schema:sameAs https://app.dimensions.ai/details/publication/pub.1039991632
91 https://doi.org/10.1007/s11581-014-1098-z
92 rdf:type schema:CreativeWork
93 https://doi.org/10.1016/j.egypro.2017.03.672 schema:sameAs https://app.dimensions.ai/details/publication/pub.1085746936
94 rdf:type schema:CreativeWork
95 https://doi.org/10.1016/j.elecom.2006.07.014 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011614659
96 rdf:type schema:CreativeWork
97 https://doi.org/10.1016/j.jpowsour.2008.08.014 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042061922
98 rdf:type schema:CreativeWork
99 https://doi.org/10.1016/j.jpowsour.2013.04.155 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004679202
100 rdf:type schema:CreativeWork
101 https://doi.org/10.1016/j.jpowsour.2014.05.027 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045599089
102 rdf:type schema:CreativeWork
103 https://doi.org/10.1016/s0013-4686(02)00593-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042220992
104 rdf:type schema:CreativeWork
105 https://doi.org/10.1016/s0378-7753(01)00683-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029114208
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1016/s1003-6326(10)60056-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024890810
108 rdf:type schema:CreativeWork
109 https://doi.org/10.1016/s1388-2481(99)00127-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004432381
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1021/acs.accounts.7b00031 schema:sameAs https://app.dimensions.ai/details/publication/pub.1084121326
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1021/ar800229g schema:sameAs https://app.dimensions.ai/details/publication/pub.1015166112
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1021/jacs.5b04690 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001270743
116 rdf:type schema:CreativeWork
117 https://doi.org/10.1021/nl402237u schema:sameAs https://app.dimensions.ai/details/publication/pub.1039516668
118 rdf:type schema:CreativeWork
119 https://doi.org/10.1039/c1ee01598b schema:sameAs https://app.dimensions.ai/details/publication/pub.1024398491
120 rdf:type schema:CreativeWork
121 https://doi.org/10.1039/c3ta10980a schema:sameAs https://app.dimensions.ai/details/publication/pub.1017487144
122 rdf:type schema:CreativeWork
123 https://doi.org/10.1039/c5ra18457f schema:sameAs https://app.dimensions.ai/details/publication/pub.1021779355
124 rdf:type schema:CreativeWork
125 https://doi.org/10.20964/2018.10.34 schema:sameAs https://app.dimensions.ai/details/publication/pub.1106445855
126 rdf:type schema:CreativeWork
127 https://doi.org/10.3390/ma6031028 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022730655
128 rdf:type schema:CreativeWork
129 https://doi.org/10.4236/msce.2014.212003 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047538085
130 rdf:type schema:CreativeWork
131 https://www.grid.ac/institutes/grid.411312.4 schema:alternateName Alagappa University
132 schema:name Advanced Lithium-ion Battery Research Lab, Department of Industrial Chemistry, Alagappa University, 630 003, Karaikudi, Tamilnadu, India
133 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...