One-pot synthesized mesoporous Ni–Co hydroxide for high performance supercapacitors View Full Text


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Article Info

DATE

2017-05

AUTHORS

Yuqing Qiao, Peng Jia, Xiaoyu Zhang, Ning Cai, Tongde Shen, Xianfeng Hao, Yongfu Tang, Xianhui Wang, Lingxue Kong, Weimin Gao

ABSTRACT

Mesoporous Ni(OH)2/Co(OH)2 electrode materials were synthesized via a simple one-pot procedure by combining homogeneous precipitation and stepwise precipitation method. The configuration of the porous Ni(OH)2/Co(OH)2 electrode materials synthesized provides 3D electron transmission channels through a high conductive Co(OH)2 distributed in the peripheral nanolayer of the composites, which is beneficial to rate capability and cycle stability. The Ni(OH)2/Co(OH)2 electrode materials have a specific surface area of 229 m2 g−1, which is approximately 40% higher than that of Ni(OH)2 (163 m2 g−1). Their specific capacitance is up to 1202 and 1022 F g−1 at the current densities of 10 and 20 A g−1, respectively. Furthermore, the capacitance retention of the electrode materials at the current density of 10 A g−1 is 98% after 5000 cycles. The synthesis method provides a novel simple route to fabricate heterostructure materials for capacitors with high electrochemical performance. Graphical abstractᅟ ᅟ More... »

PAGES

1229-1238

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11581-016-1914-8

DOI

http://dx.doi.org/10.1007/s11581-016-1914-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1003748657


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50 schema:description Mesoporous Ni(OH)2/Co(OH)2 electrode materials were synthesized via a simple one-pot procedure by combining homogeneous precipitation and stepwise precipitation method. The configuration of the porous Ni(OH)2/Co(OH)2 electrode materials synthesized provides 3D electron transmission channels through a high conductive Co(OH)2 distributed in the peripheral nanolayer of the composites, which is beneficial to rate capability and cycle stability. The Ni(OH)2/Co(OH)2 electrode materials have a specific surface area of 229 m2 g−1, which is approximately 40% higher than that of Ni(OH)2 (163 m2 g−1). Their specific capacitance is up to 1202 and 1022 F g−1 at the current densities of 10 and 20 A g−1, respectively. Furthermore, the capacitance retention of the electrode materials at the current density of 10 A g−1 is 98% after 5000 cycles. The synthesis method provides a novel simple route to fabricate heterostructure materials for capacitors with high electrochemical performance. Graphical abstractᅟ ᅟ
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