Reduced graphene oxide–bismuth oxide composite as electrode material for supercapacitors View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2015-02

AUTHORS

Mateusz Ciszewski, Andrzej Mianowski, Piotr Szatkowski, Ginter Nawrat, Jakub Adamek

ABSTRACT

We have reported a new reduced graphene oxide–bismuth oxide composite that can be used as a supercapacitor electrode. Bi2O3 was synthesized from bismuth nitrate pentahydrate and oxalic acid as a precipitating agent using a hydrothermal process in an aqueous graphene oxide suspension. Instead of mixing graphene oxide with bismuth oxide, we have developed a bismuth oxalate precipitation between the layers. As prepared, composite of hydrated bismuth oxalate and graphene oxide was converted to bismuth oxide and reduced graphene oxide by thermal decomposition in a muffle stove. The material exhibited the specific capacitance of 94 F/g at current density 0.2 A/g. Using the cyclic voltammetry, the specific capacitance was as high as 55 F/g at scan rate 5 mV/s over the potential range 0–1 V. The material exhibited long-term cycle stability retaining 90 % specific capacitance after 3,000 cycles. Except Bi3+ ions present in Bi2O3, some amount of higher energy Bi5+ was confirmed. More... »

PAGES

557-563

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11581-014-1182-4

DOI

http://dx.doi.org/10.1007/s11581-014-1182-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1026534818


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