Two-phase reaction mechanism during chemical lithium insertion into α-MoO3 View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-02

AUTHORS

A. M. Hashem, M. H. Askar, M. Winter, J. H. Albering, J. O. Besenhard

ABSTRACT

The phase transition during chemical lithium insertion into α-MoO3 was investigated by chemical analysis, X-ray diffraction (XRD) and electrochemical characterisation. The samples have been prepared by reaction of various amounts of water-free lithium iodide with fine-particulate orthorhombic molybdenum trioxide in n-hexane (non-aqueous media), which yielded materials with different Li/Mo ratio. XRD investigations of these materials proved that the crystal structure of the layered α-MoO3 has been changed after the chemical lithiation. The phase transition ranged from 0.25 < x < 0.5 in LixMoO3 upon chemical lithium insertion into α-MoO3. The XRD lines of lithium inserted phase LixMoO3 grew at the expense of the XRD lines of the pristine α-MoO3 as lithium ions were chemically inserted until the disappearance of lines related to α-MoO3. The electrochemical performance of the lithiated samples is improved in comparison with the starting material (non-lithiated α-MoO3). More... »

PAGES

3-8

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11581-007-0065-3

DOI

http://dx.doi.org/10.1007/s11581-007-0065-3

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1051045190


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