Ontology type: schema:ScholarlyArticle
2007-02
AUTHORSA. M. Hashem, M. H. Askar, M. Winter, J. H. Albering, J. O. Besenhard
ABSTRACTThe phase transition during chemical lithium insertion into α-MoO3 was investigated by chemical analysis, X-ray diffraction (XRD) and electrochemical characterisation. The samples have been prepared by reaction of various amounts of water-free lithium iodide with fine-particulate orthorhombic molybdenum trioxide in n-hexane (non-aqueous media), which yielded materials with different Li/Mo ratio. XRD investigations of these materials proved that the crystal structure of the layered α-MoO3 has been changed after the chemical lithiation. The phase transition ranged from 0.25 < x < 0.5 in LixMoO3 upon chemical lithium insertion into α-MoO3. The XRD lines of lithium inserted phase LixMoO3 grew at the expense of the XRD lines of the pristine α-MoO3 as lithium ions were chemically inserted until the disappearance of lines related to α-MoO3. The electrochemical performance of the lithiated samples is improved in comparison with the starting material (non-lithiated α-MoO3). More... »
PAGES3-8
http://scigraph.springernature.com/pub.10.1007/s11581-007-0065-3
DOIhttp://dx.doi.org/10.1007/s11581-007-0065-3
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1051045190
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "National Research Centre",
"id": "https://www.grid.ac/institutes/grid.419725.c",
"name": [
"Institute for Chemical Technology of Inorganic Materials, Graz University of Technology, Stremayrgasse16, 8010, Graz, Austria",
"National Research Center, Behoes Street, Cairo, Egypt"
],
"type": "Organization"
},
"familyName": "Hashem",
"givenName": "A. M.",
"id": "sg:person.014750467076.45",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014750467076.45"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "National Research Centre",
"id": "https://www.grid.ac/institutes/grid.419725.c",
"name": [
"National Research Center, Behoes Street, Cairo, Egypt"
],
"type": "Organization"
},
"familyName": "Askar",
"givenName": "M. H.",
"id": "sg:person.015317136777.29",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015317136777.29"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Graz University of Technology",
"id": "https://www.grid.ac/institutes/grid.410413.3",
"name": [
"Institute for Chemical Technology of Inorganic Materials, Graz University of Technology, Stremayrgasse16, 8010, Graz, Austria"
],
"type": "Organization"
},
"familyName": "Winter",
"givenName": "M.",
"id": "sg:person.01044357630.19",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01044357630.19"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Graz University of Technology",
"id": "https://www.grid.ac/institutes/grid.410413.3",
"name": [
"Institute for Chemical Technology of Inorganic Materials, Graz University of Technology, Stremayrgasse16, 8010, Graz, Austria"
],
"type": "Organization"
},
"familyName": "Albering",
"givenName": "J. H.",
"id": "sg:person.014265242750.05",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014265242750.05"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Graz University of Technology",
"id": "https://www.grid.ac/institutes/grid.410413.3",
"name": [
"Institute for Chemical Technology of Inorganic Materials, Graz University of Technology, Stremayrgasse16, 8010, Graz, Austria"
],
"type": "Organization"
},
"familyName": "Besenhard",
"givenName": "J. O.",
"id": "sg:person.01144123216.14",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01144123216.14"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1007/bf02375864",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1004398769",
"https://doi.org/10.1007/bf02375864"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf02375864",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1004398769",
"https://doi.org/10.1007/bf02375864"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0025-5408(87)90030-4",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1005748586"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0025-5408(87)90030-4",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1005748586"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.electacta.2006.02.050",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1006053640"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0025-5408(76)90218-x",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1018116339"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0025-5408(76)90218-x",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1018116339"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0167-2738(82)90042-x",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1026535647"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0167-2738(82)90042-x",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1026535647"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf01016042",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1032138272",
"https://doi.org/10.1007/bf01016042"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0167-2738(83)90041-3",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1048428155"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0167-2738(83)90041-3",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1048428155"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0167-2738(00)00338-6",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1049454801"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0022-4596(88)90194-6",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1049844326"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0167-2738(97)00418-9",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1050261440"
],
"type": "CreativeWork"
}
],
"datePublished": "2007-02",
"datePublishedReg": "2007-02-01",
"description": "The phase transition during chemical lithium insertion into \u03b1-MoO3 was investigated by chemical analysis, X-ray diffraction (XRD) and electrochemical characterisation. The samples have been prepared by reaction of various amounts of water-free lithium iodide with fine-particulate orthorhombic molybdenum trioxide in n-hexane (non-aqueous media), which yielded materials with different Li/Mo ratio. XRD investigations of these materials proved that the crystal structure of the layered \u03b1-MoO3 has been changed after the chemical lithiation. The phase transition ranged from 0.25 < x < 0.5 in LixMoO3 upon chemical lithium insertion into \u03b1-MoO3. The XRD lines of lithium inserted phase LixMoO3 grew at the expense of the XRD lines of the pristine \u03b1-MoO3 as lithium ions were chemically inserted until the disappearance of lines related to \u03b1-MoO3. The electrochemical performance of the lithiated samples is improved in comparison with the starting material (non-lithiated \u03b1-MoO3).",
"genre": "research_article",
"id": "sg:pub.10.1007/s11581-007-0065-3",
"inLanguage": [
"en"
],
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1041836",
"issn": [
"0947-7047",
"1862-0760"
],
"name": "Ionics",
"type": "Periodical"
},
{
"issueNumber": "1",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "13"
}
],
"name": "Two-phase reaction mechanism during chemical lithium insertion into \u03b1-MoO3",
"pagination": "3-8",
"productId": [
{
"name": "readcube_id",
"type": "PropertyValue",
"value": [
"f329375d8f31c7d8642ac53d7ce85e5e714e122938ae92c88730278e8d713475"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/s11581-007-0065-3"
]
},
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1051045190"
]
}
],
"sameAs": [
"https://doi.org/10.1007/s11581-007-0065-3",
"https://app.dimensions.ai/details/publication/pub.1051045190"
],
"sdDataset": "articles",
"sdDatePublished": "2019-04-10T23:27",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8693_00000524.jsonl",
"type": "ScholarlyArticle",
"url": "http://link.springer.com/10.1007%2Fs11581-007-0065-3"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11581-007-0065-3'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11581-007-0065-3'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11581-007-0065-3'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11581-007-0065-3'
This table displays all metadata directly associated to this object as RDF triples.
125 TRIPLES
21 PREDICATES
37 URIs
19 LITERALS
7 BLANK NODES