Kinetics Study with Rigorous Nonlinear Methods for Thermal Decomposition of Polysaccharide Iron Complex View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-09

AUTHORS

Yingheng Huang, Yao Xia, Sen Liao, Zhipeng Chen, Zhangfa Tong, Yu Li, Qiwei Long

ABSTRACT

The advanced isoconversional and nonlinear model-fitting methods were used to calculate the activation energies of the thermal process of polysaccharide iron complex (PIC). The results of TG/TDG indicate that the processing temperature of the food should not exceed 223 °C when PIC is used as a food additive. The calculated results indicated the decomposition process involved two stages. The region I in stage II is a kinetically complex process, while stage I and region II of stage II are all single-step processes. The most probable mechanisms for stage I and region II of stage II are chemical reaction and contracting sphere. Meanwhile, the most probable mechanism functions for region I of stage II were determined by using nonlinear model-fitting method. The results of nonlinear model-fitting method showed the most probable mechanism of the parallel reactions for region I of stage II were nucleation and branching nuclei. More... »

PAGES

277-284

References to SciGraph publications

  • 2013-03. On the Theoretical Time-Scale Estimation of Physical and Chemical Kinetics Whilst Wheat Dough Processing in FOOD BIOPHYSICS
  • 2013-03. Kinetics of in Vitro Bread Bolus Digestion with Varying Oral and Gastric Digestion Parameters in FOOD BIOPHYSICS
  • 2007-06. Products and kinetics of non-isothermal decomposition of vanadium(IV) oxide compounds in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2007-04. Kinetics of decomposition of different acid calcium phosphates in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2009-12. Kinetic and thermodynamic studies of MgHPO4 · 3H2O by non-isothermal decomposition data in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2012-06. Preparation of LiZnPO4·H2O via a novel modified method and its non-isothermal kinetics and thermodynamics of thermal decomposition in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2012-09. Effects of Acidification, Sodium Chloride, and Moisture Levels on Wheat Dough: II. Modeling of Bread Texture and Staling Kinetics in FOOD BIOPHYSICS
  • 2007-06. Comparative results of kinetic data obtained with different methods for complex decomposition steps in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2013-02. Kinetic study of template removal of MCM-41 derived from rice husk ash in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2011-09. Isoconversional analysis of solid state transformations in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2009-09. Kinetics of Phase Separation of Oat β-Glucan/Whey Protein Isolate Binary Mixtures in FOOD BIOPHYSICS
  • 2011-12. Drying of Pomegranate Arils and Selection of a Suitable Drying Model in FOOD BIOPHYSICS
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s11483-014-9351-6

    DOI

    http://dx.doi.org/10.1007/s11483-014-9351-6

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1038877489


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0102", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Applied Mathematics", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/01", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Mathematical Sciences", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "Guangxi University", 
              "id": "https://www.grid.ac/institutes/grid.256609.e", 
              "name": [
                "Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University, 530004, Nanning, Guangxi, China", 
                "School of Materials Science and Engineering, Guangxi University, 530004, Nanning, Guangxi, China"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Huang", 
            "givenName": "Yingheng", 
            "id": "sg:person.011057324235.30", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011057324235.30"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Guangxi University", 
              "id": "https://www.grid.ac/institutes/grid.256609.e", 
              "name": [
                "Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University, 530004, Nanning, Guangxi, China"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Xia", 
            "givenName": "Yao", 
            "id": "sg:person.011654704635.43", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011654704635.43"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Guangxi University", 
              "id": "https://www.grid.ac/institutes/grid.256609.e", 
              "name": [
                "Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University, 530004, Nanning, Guangxi, China"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Liao", 
            "givenName": "Sen", 
            "id": "sg:person.015114422327.53", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015114422327.53"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Guangxi University", 
              "id": "https://www.grid.ac/institutes/grid.256609.e", 
              "name": [
                "Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University, 530004, Nanning, Guangxi, China"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Chen", 
            "givenName": "Zhipeng", 
            "id": "sg:person.012377502072.30", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012377502072.30"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Guangxi University", 
              "id": "https://www.grid.ac/institutes/grid.256609.e", 
              "name": [
                "Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University, 530004, Nanning, Guangxi, China"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Tong", 
            "givenName": "Zhangfa", 
            "id": "sg:person.01016645115.50", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01016645115.50"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Guangxi University", 
              "id": "https://www.grid.ac/institutes/grid.256609.e", 
              "name": [
                "Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University, 530004, Nanning, Guangxi, China"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Li", 
            "givenName": "Yu", 
            "id": "sg:person.01371146012.15", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01371146012.15"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Guangxi University", 
              "id": "https://www.grid.ac/institutes/grid.256609.e", 
              "name": [
                "Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University, 530004, Nanning, Guangxi, China"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Long", 
            "givenName": "Qiwei", 
            "id": "sg:person.013232222017.13", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013232222017.13"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "sg:pub.10.1007/s11483-013-9285-4", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1002740701", 
              "https://doi.org/10.1007/s11483-013-9285-4"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.tca.2011.11.007", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1004852635"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.tca.2010.12.002", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1006259386"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.compositesa.2011.12.005", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1007221097"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s10973-006-8019-y", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1007429429", 
              "https://doi.org/10.1007/s10973-006-8019-y"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0040-6031(92)85118-f", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1008269354"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1080/014423598230108", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1008987242"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s0040-6031(03)00310-1", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1010655873"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s0040-6031(03)00310-1", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1010655873"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.tca.2011.03.034", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1011707925"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.jaap.2011.01.004", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1014403171"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.carbon.2009.09.036", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1015611581"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.tca.2012.05.027", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1015922804"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s10973-011-1446-4", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1020539481", 
              "https://doi.org/10.1007/s10973-011-1446-4"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.actbio.2009.01.017", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1022995877"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0040-6031(93)80081-k", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1023856744"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.tca.2011.11.018", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1026052424"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.tca.2012.05.028", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1032430412"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s10973-005-7149-y", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1036175168", 
              "https://doi.org/10.1007/s10973-005-7149-y"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s10973-006-8022-3", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1036770843", 
              "https://doi.org/10.1007/s10973-006-8022-3"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s10973-006-8022-3", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1036770843", 
              "https://doi.org/10.1007/s10973-006-8022-3"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s10973-011-1799-8", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1039966265", 
              "https://doi.org/10.1007/s10973-011-1799-8"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s11483-013-9283-6", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1041079885", 
              "https://doi.org/10.1007/s11483-013-9283-6"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s10973-009-0108-2", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1041187195", 
              "https://doi.org/10.1007/s10973-009-0108-2"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s10973-009-0108-2", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1041187195", 
              "https://doi.org/10.1007/s10973-009-0108-2"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s11483-009-9121-z", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1041461060", 
              "https://doi.org/10.1007/s11483-009-9121-z"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s11483-009-9121-z", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1041461060", 
              "https://doi.org/10.1007/s11483-009-9121-z"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s11483-011-9226-z", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1044890278", 
              "https://doi.org/10.1007/s11483-011-9226-z"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s10973-012-2516-y", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1046017354", 
              "https://doi.org/10.1007/s10973-012-2516-y"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.tca.2011.01.022", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1046509378"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s11483-012-9258-z", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1050084822", 
              "https://doi.org/10.1007/s11483-012-9258-z"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s11483-012-9258-z", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1050084822", 
              "https://doi.org/10.1007/s11483-012-9258-z"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.tca.2012.06.023", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1051629623"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.physb.2010.02.046", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1052076664"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.jssc.2004.04.036", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1053166590"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ie300774x", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055605457"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ie302743h", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055606404"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.3144/expresspolymlett.2008.18", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1071053218"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://app.dimensions.ai/details/publication/pub.1082197523", 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2014-09", 
        "datePublishedReg": "2014-09-01", 
        "description": "The advanced isoconversional and nonlinear model-fitting methods were used to calculate the activation energies of the thermal process of polysaccharide iron complex (PIC). The results of TG/TDG indicate that the processing temperature of the food should not exceed 223 \u00b0C when PIC is used as a food additive. The calculated results indicated the decomposition process involved two stages. The region I in stage II is a kinetically complex process, while stage I and region II of stage II are all single-step processes. The most probable mechanisms for stage I and region II of stage II are chemical reaction and contracting sphere. Meanwhile, the most probable mechanism functions for region I of stage II were determined by using nonlinear model-fitting method. The results of nonlinear model-fitting method showed the most probable mechanism of the parallel reactions for region I of stage II were nucleation and branching nuclei.", 
        "genre": "research_article", 
        "id": "sg:pub.10.1007/s11483-014-9351-6", 
        "inLanguage": [
          "en"
        ], 
        "isAccessibleForFree": false, 
        "isFundedItemOf": [
          {
            "id": "sg:grant.6984021", 
            "type": "MonetaryGrant"
          }
        ], 
        "isPartOf": [
          {
            "id": "sg:journal.1037942", 
            "issn": [
              "1557-1858", 
              "1557-1866"
            ], 
            "name": "Food Biophysics", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "3", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "9"
          }
        ], 
        "name": "Kinetics Study with Rigorous Nonlinear Methods for Thermal Decomposition of Polysaccharide Iron Complex", 
        "pagination": "277-284", 
        "productId": [
          {
            "name": "readcube_id", 
            "type": "PropertyValue", 
            "value": [
              "b9315e0e202f11f11023e0dceeda8566c7976958fde2a5767bb28ee0a0fd3399"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/s11483-014-9351-6"
            ]
          }, 
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1038877489"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/s11483-014-9351-6", 
          "https://app.dimensions.ai/details/publication/pub.1038877489"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2019-04-10T15:56", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8664_00000533.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "http://link.springer.com/10.1007%2Fs11483-014-9351-6"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11483-014-9351-6'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11483-014-9351-6'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11483-014-9351-6'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11483-014-9351-6'


     

    This table displays all metadata directly associated to this object as RDF triples.

    219 TRIPLES      21 PREDICATES      61 URIs      19 LITERALS      7 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/s11483-014-9351-6 schema:about anzsrc-for:01
    2 anzsrc-for:0102
    3 schema:author Nba09189784984c73823e23d1d1792804
    4 schema:citation sg:pub.10.1007/s10973-005-7149-y
    5 sg:pub.10.1007/s10973-006-8019-y
    6 sg:pub.10.1007/s10973-006-8022-3
    7 sg:pub.10.1007/s10973-009-0108-2
    8 sg:pub.10.1007/s10973-011-1446-4
    9 sg:pub.10.1007/s10973-011-1799-8
    10 sg:pub.10.1007/s10973-012-2516-y
    11 sg:pub.10.1007/s11483-009-9121-z
    12 sg:pub.10.1007/s11483-011-9226-z
    13 sg:pub.10.1007/s11483-012-9258-z
    14 sg:pub.10.1007/s11483-013-9283-6
    15 sg:pub.10.1007/s11483-013-9285-4
    16 https://app.dimensions.ai/details/publication/pub.1082197523
    17 https://doi.org/10.1016/0040-6031(92)85118-f
    18 https://doi.org/10.1016/0040-6031(93)80081-k
    19 https://doi.org/10.1016/j.actbio.2009.01.017
    20 https://doi.org/10.1016/j.carbon.2009.09.036
    21 https://doi.org/10.1016/j.compositesa.2011.12.005
    22 https://doi.org/10.1016/j.jaap.2011.01.004
    23 https://doi.org/10.1016/j.jssc.2004.04.036
    24 https://doi.org/10.1016/j.physb.2010.02.046
    25 https://doi.org/10.1016/j.tca.2010.12.002
    26 https://doi.org/10.1016/j.tca.2011.01.022
    27 https://doi.org/10.1016/j.tca.2011.03.034
    28 https://doi.org/10.1016/j.tca.2011.11.007
    29 https://doi.org/10.1016/j.tca.2011.11.018
    30 https://doi.org/10.1016/j.tca.2012.05.027
    31 https://doi.org/10.1016/j.tca.2012.05.028
    32 https://doi.org/10.1016/j.tca.2012.06.023
    33 https://doi.org/10.1016/s0040-6031(03)00310-1
    34 https://doi.org/10.1021/ie300774x
    35 https://doi.org/10.1021/ie302743h
    36 https://doi.org/10.1080/014423598230108
    37 https://doi.org/10.3144/expresspolymlett.2008.18
    38 schema:datePublished 2014-09
    39 schema:datePublishedReg 2014-09-01
    40 schema:description The advanced isoconversional and nonlinear model-fitting methods were used to calculate the activation energies of the thermal process of polysaccharide iron complex (PIC). The results of TG/TDG indicate that the processing temperature of the food should not exceed 223 °C when PIC is used as a food additive. The calculated results indicated the decomposition process involved two stages. The region I in stage II is a kinetically complex process, while stage I and region II of stage II are all single-step processes. The most probable mechanisms for stage I and region II of stage II are chemical reaction and contracting sphere. Meanwhile, the most probable mechanism functions for region I of stage II were determined by using nonlinear model-fitting method. The results of nonlinear model-fitting method showed the most probable mechanism of the parallel reactions for region I of stage II were nucleation and branching nuclei.
    41 schema:genre research_article
    42 schema:inLanguage en
    43 schema:isAccessibleForFree false
    44 schema:isPartOf N9c418fc7c3b14513ac775af3430798e7
    45 Ndfa66382454241fc842db47604be5579
    46 sg:journal.1037942
    47 schema:name Kinetics Study with Rigorous Nonlinear Methods for Thermal Decomposition of Polysaccharide Iron Complex
    48 schema:pagination 277-284
    49 schema:productId N1b1438189291410facecb6448f9b5e01
    50 N6625704fc49a49b4a562c4d28d7503a9
    51 Ne8687d9e96ed4574ad4ae5bf4de2b81a
    52 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038877489
    53 https://doi.org/10.1007/s11483-014-9351-6
    54 schema:sdDatePublished 2019-04-10T15:56
    55 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    56 schema:sdPublisher Na02aea461ee44c3380b90cbf807b7981
    57 schema:url http://link.springer.com/10.1007%2Fs11483-014-9351-6
    58 sgo:license sg:explorer/license/
    59 sgo:sdDataset articles
    60 rdf:type schema:ScholarlyArticle
    61 N00305335efa24ac283f3bdf8ea818b33 rdf:first sg:person.012377502072.30
    62 rdf:rest N7f21525991c84542837131e166090a8e
    63 N1b1438189291410facecb6448f9b5e01 schema:name readcube_id
    64 schema:value b9315e0e202f11f11023e0dceeda8566c7976958fde2a5767bb28ee0a0fd3399
    65 rdf:type schema:PropertyValue
    66 N6625704fc49a49b4a562c4d28d7503a9 schema:name doi
    67 schema:value 10.1007/s11483-014-9351-6
    68 rdf:type schema:PropertyValue
    69 N76f70c85d1694d75a5f02ebfcdc380e7 rdf:first sg:person.01371146012.15
    70 rdf:rest Ne632f83001204afabb3dd294ad340d42
    71 N7f21525991c84542837131e166090a8e rdf:first sg:person.01016645115.50
    72 rdf:rest N76f70c85d1694d75a5f02ebfcdc380e7
    73 N9c418fc7c3b14513ac775af3430798e7 schema:issueNumber 3
    74 rdf:type schema:PublicationIssue
    75 Na02aea461ee44c3380b90cbf807b7981 schema:name Springer Nature - SN SciGraph project
    76 rdf:type schema:Organization
    77 Na49c92720c884bc4912e45d3131a734d rdf:first sg:person.011654704635.43
    78 rdf:rest Ne6b867285055436e9180905c5d3c6de1
    79 Nba09189784984c73823e23d1d1792804 rdf:first sg:person.011057324235.30
    80 rdf:rest Na49c92720c884bc4912e45d3131a734d
    81 Ndfa66382454241fc842db47604be5579 schema:volumeNumber 9
    82 rdf:type schema:PublicationVolume
    83 Ne632f83001204afabb3dd294ad340d42 rdf:first sg:person.013232222017.13
    84 rdf:rest rdf:nil
    85 Ne6b867285055436e9180905c5d3c6de1 rdf:first sg:person.015114422327.53
    86 rdf:rest N00305335efa24ac283f3bdf8ea818b33
    87 Ne8687d9e96ed4574ad4ae5bf4de2b81a schema:name dimensions_id
    88 schema:value pub.1038877489
    89 rdf:type schema:PropertyValue
    90 anzsrc-for:01 schema:inDefinedTermSet anzsrc-for:
    91 schema:name Mathematical Sciences
    92 rdf:type schema:DefinedTerm
    93 anzsrc-for:0102 schema:inDefinedTermSet anzsrc-for:
    94 schema:name Applied Mathematics
    95 rdf:type schema:DefinedTerm
    96 sg:grant.6984021 http://pending.schema.org/fundedItem sg:pub.10.1007/s11483-014-9351-6
    97 rdf:type schema:MonetaryGrant
    98 sg:journal.1037942 schema:issn 1557-1858
    99 1557-1866
    100 schema:name Food Biophysics
    101 rdf:type schema:Periodical
    102 sg:person.01016645115.50 schema:affiliation https://www.grid.ac/institutes/grid.256609.e
    103 schema:familyName Tong
    104 schema:givenName Zhangfa
    105 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01016645115.50
    106 rdf:type schema:Person
    107 sg:person.011057324235.30 schema:affiliation https://www.grid.ac/institutes/grid.256609.e
    108 schema:familyName Huang
    109 schema:givenName Yingheng
    110 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011057324235.30
    111 rdf:type schema:Person
    112 sg:person.011654704635.43 schema:affiliation https://www.grid.ac/institutes/grid.256609.e
    113 schema:familyName Xia
    114 schema:givenName Yao
    115 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011654704635.43
    116 rdf:type schema:Person
    117 sg:person.012377502072.30 schema:affiliation https://www.grid.ac/institutes/grid.256609.e
    118 schema:familyName Chen
    119 schema:givenName Zhipeng
    120 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012377502072.30
    121 rdf:type schema:Person
    122 sg:person.013232222017.13 schema:affiliation https://www.grid.ac/institutes/grid.256609.e
    123 schema:familyName Long
    124 schema:givenName Qiwei
    125 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013232222017.13
    126 rdf:type schema:Person
    127 sg:person.01371146012.15 schema:affiliation https://www.grid.ac/institutes/grid.256609.e
    128 schema:familyName Li
    129 schema:givenName Yu
    130 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01371146012.15
    131 rdf:type schema:Person
    132 sg:person.015114422327.53 schema:affiliation https://www.grid.ac/institutes/grid.256609.e
    133 schema:familyName Liao
    134 schema:givenName Sen
    135 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015114422327.53
    136 rdf:type schema:Person
    137 sg:pub.10.1007/s10973-005-7149-y schema:sameAs https://app.dimensions.ai/details/publication/pub.1036175168
    138 https://doi.org/10.1007/s10973-005-7149-y
    139 rdf:type schema:CreativeWork
    140 sg:pub.10.1007/s10973-006-8019-y schema:sameAs https://app.dimensions.ai/details/publication/pub.1007429429
    141 https://doi.org/10.1007/s10973-006-8019-y
    142 rdf:type schema:CreativeWork
    143 sg:pub.10.1007/s10973-006-8022-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036770843
    144 https://doi.org/10.1007/s10973-006-8022-3
    145 rdf:type schema:CreativeWork
    146 sg:pub.10.1007/s10973-009-0108-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041187195
    147 https://doi.org/10.1007/s10973-009-0108-2
    148 rdf:type schema:CreativeWork
    149 sg:pub.10.1007/s10973-011-1446-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020539481
    150 https://doi.org/10.1007/s10973-011-1446-4
    151 rdf:type schema:CreativeWork
    152 sg:pub.10.1007/s10973-011-1799-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039966265
    153 https://doi.org/10.1007/s10973-011-1799-8
    154 rdf:type schema:CreativeWork
    155 sg:pub.10.1007/s10973-012-2516-y schema:sameAs https://app.dimensions.ai/details/publication/pub.1046017354
    156 https://doi.org/10.1007/s10973-012-2516-y
    157 rdf:type schema:CreativeWork
    158 sg:pub.10.1007/s11483-009-9121-z schema:sameAs https://app.dimensions.ai/details/publication/pub.1041461060
    159 https://doi.org/10.1007/s11483-009-9121-z
    160 rdf:type schema:CreativeWork
    161 sg:pub.10.1007/s11483-011-9226-z schema:sameAs https://app.dimensions.ai/details/publication/pub.1044890278
    162 https://doi.org/10.1007/s11483-011-9226-z
    163 rdf:type schema:CreativeWork
    164 sg:pub.10.1007/s11483-012-9258-z schema:sameAs https://app.dimensions.ai/details/publication/pub.1050084822
    165 https://doi.org/10.1007/s11483-012-9258-z
    166 rdf:type schema:CreativeWork
    167 sg:pub.10.1007/s11483-013-9283-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041079885
    168 https://doi.org/10.1007/s11483-013-9283-6
    169 rdf:type schema:CreativeWork
    170 sg:pub.10.1007/s11483-013-9285-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002740701
    171 https://doi.org/10.1007/s11483-013-9285-4
    172 rdf:type schema:CreativeWork
    173 https://app.dimensions.ai/details/publication/pub.1082197523 schema:CreativeWork
    174 https://doi.org/10.1016/0040-6031(92)85118-f schema:sameAs https://app.dimensions.ai/details/publication/pub.1008269354
    175 rdf:type schema:CreativeWork
    176 https://doi.org/10.1016/0040-6031(93)80081-k schema:sameAs https://app.dimensions.ai/details/publication/pub.1023856744
    177 rdf:type schema:CreativeWork
    178 https://doi.org/10.1016/j.actbio.2009.01.017 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022995877
    179 rdf:type schema:CreativeWork
    180 https://doi.org/10.1016/j.carbon.2009.09.036 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015611581
    181 rdf:type schema:CreativeWork
    182 https://doi.org/10.1016/j.compositesa.2011.12.005 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007221097
    183 rdf:type schema:CreativeWork
    184 https://doi.org/10.1016/j.jaap.2011.01.004 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014403171
    185 rdf:type schema:CreativeWork
    186 https://doi.org/10.1016/j.jssc.2004.04.036 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053166590
    187 rdf:type schema:CreativeWork
    188 https://doi.org/10.1016/j.physb.2010.02.046 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052076664
    189 rdf:type schema:CreativeWork
    190 https://doi.org/10.1016/j.tca.2010.12.002 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006259386
    191 rdf:type schema:CreativeWork
    192 https://doi.org/10.1016/j.tca.2011.01.022 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046509378
    193 rdf:type schema:CreativeWork
    194 https://doi.org/10.1016/j.tca.2011.03.034 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011707925
    195 rdf:type schema:CreativeWork
    196 https://doi.org/10.1016/j.tca.2011.11.007 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004852635
    197 rdf:type schema:CreativeWork
    198 https://doi.org/10.1016/j.tca.2011.11.018 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026052424
    199 rdf:type schema:CreativeWork
    200 https://doi.org/10.1016/j.tca.2012.05.027 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015922804
    201 rdf:type schema:CreativeWork
    202 https://doi.org/10.1016/j.tca.2012.05.028 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032430412
    203 rdf:type schema:CreativeWork
    204 https://doi.org/10.1016/j.tca.2012.06.023 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051629623
    205 rdf:type schema:CreativeWork
    206 https://doi.org/10.1016/s0040-6031(03)00310-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010655873
    207 rdf:type schema:CreativeWork
    208 https://doi.org/10.1021/ie300774x schema:sameAs https://app.dimensions.ai/details/publication/pub.1055605457
    209 rdf:type schema:CreativeWork
    210 https://doi.org/10.1021/ie302743h schema:sameAs https://app.dimensions.ai/details/publication/pub.1055606404
    211 rdf:type schema:CreativeWork
    212 https://doi.org/10.1080/014423598230108 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008987242
    213 rdf:type schema:CreativeWork
    214 https://doi.org/10.3144/expresspolymlett.2008.18 schema:sameAs https://app.dimensions.ai/details/publication/pub.1071053218
    215 rdf:type schema:CreativeWork
    216 https://www.grid.ac/institutes/grid.256609.e schema:alternateName Guangxi University
    217 schema:name Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University, 530004, Nanning, Guangxi, China
    218 School of Materials Science and Engineering, Guangxi University, 530004, Nanning, Guangxi, China
    219 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...