Structural diversity and reactivity of d10 metal-(4-pyridylthio)acetate system View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-12

AUTHORS

YueHua Zhang, Jing Wang, LingLing Zheng, Sheng Hu, ZhuoJia Lin, MingLiang Tong

ABSTRACT

The hydrothermal synthesis and crystal structures of four coordination polymers, namely, 2D [Zn(μ3-ta)(pytaH)]n (1), 2D [Zn(μ3-pyta)Cl]n (2), 1D [Cd(μ-pyta)2(H2O)]n (3), and 3D [Cd(μ3-pyta)(μ-Cl)]n (4) (pyta = (4-pyridylthio)acetate, ta = thioglycolate), are reported. They are based on (4-pyridylthio)acetate and its derived ligand. The ta2− ligand present in 1 was generated from an in situ C(sp2)-S bond cleavage of the pyta ligand. In these compounds, versatile intermolecular interactions, such as close S…S interactions and strong (O-H…O/N/S) or weak (C-H…O/S, C-H…Cl) hydrogen bonding interactions, play an important role in the formation of three-dimensional supramolecular networks in the solid state. More... »

PAGES

4277-4284

Journal

TITLE

Science Bulletin

ISSUE

23

VOLUME

54

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11434-009-0673-6

DOI

http://dx.doi.org/10.1007/s11434-009-0673-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1033649718


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