Method for studying diatomic rovibrational spectra at a given vibrational state View Full Text


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Article Info

DATE

2019-04

AUTHORS

Yi Zhang, WeiGuo Sun, Jia Fu, QunChao Fan, Jie Ma, LianTuan Xiao, SuoTang Jia

ABSTRACT

An algebraic method for rotational energies at a given vibrational state (AMr(v)) is proposed in this study in order to obtain unknown high-lying rovibrational energies. Applications of this method to the ground electronic state X1Σ+ of CO and the excited state C1Σ+ of 39K7Li molecules show the following: (1) the AMr(v) can give the rational upper limit J¯ of a rotational quantum number of a diatomic electronic state; (2) the full AMr(v) rovibrational energies {EυJ}υ} of given vibrational states not only reproduce all known experimental data excellently but also predict precisely the values of all high-lying rovibrational energies, which may not be available experimentally. More... »

PAGES

943011

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11433-018-9311-3

DOI

http://dx.doi.org/10.1007/s11433-018-9311-3

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https://app.dimensions.ai/details/publication/pub.1112305606


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