The abnormal behavior of polymers glass transition temperature increase and its mechanism View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-05

AUTHORS

Xiang Wang, GuiCun Qi, XiaoHong Zhang, JianMing Gao, BingHai Li, ZhiHai Song, JinLiang Qiao

ABSTRACT

In terms of the classical theory in textbooks, the two components with phase separation in a binary polymer blend will, depending on their compatibility, have their respective Tg get closer or remain in their original values. According to the classical theory, the Tg of plastic component shall remain unchanged or move toward the lower Tg of rubber component in a rubber/plastic blend. However, ultra-fine full-vulcanized powdered rubber (UFPR) with a diameter of ca. 100 nm can simultaneously increase the toughness and the Tg of plastics, which is abnormal and is difficult to explain by classical theory. In this feature article, the abnormal behavior and its mechanism are discussed in detail. More... »

PAGES

713-717

References to SciGraph publications

Journal

TITLE

Science China Chemistry

ISSUE

5

VOLUME

55

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11426-012-4521-1

DOI

http://dx.doi.org/10.1007/s11426-012-4521-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1013866473


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