Preparation of hypercrosslinked amine modification resin and its adsorption properties for nitroaromatics View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-02-18

AUTHORS

Chao Xu, Chuanhong Wang, Weizhi Sun, Wenhao Yu, Chai Yin, Fusheng Liu, Mo Xian, Shitao Yu

ABSTRACT

A nitrosation-reduction method had been applied for the modification of DCE-4 h. It was a kind of non-polar hypercrosslinked resin and synthesized by our group. The functional resin, NR-07, exhibited good adsorption performance for NACs (Nitroaromatics). The adsorption capacity of NR-07 for p-nitrobenzoic acid was almost 1.3 times as much as that of H-103 in 24 h. The adsorption rate of NR-07 calculated by the kinetic function was 1.6 times as much as that of DCE-4h. According to the EA analysis and IR spectrum, the amine and carbonyl group were introduced onto the polymer chains of NR-07. These hydrophilic chemical groups of NR-07 contributed to a higher liquid-film diffusion rate than that of DCE-4h. Besides, the pore volume within 0.46~4.3 nm increased after the modification process, which had a positive effect on the intra-particle diffusion process. More... »

PAGES

1-9

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11356-019-04370-4

DOI

http://dx.doi.org/10.1007/s11356-019-04370-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1112215280

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/30778941


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