Enhanced adsorption of hexavalent chromium by a biochar derived from ramie biomass (Boehmeria nivea (L.) Gaud.) modified with β-cyclodextrin/poly(L-glutamic acid) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-08-29

AUTHORS

Luhua Jiang, Shaobo Liu, Yunguo Liu, Guangming Zeng, Yiming Guo, Yicheng Yin, Xiaoxi Cai, Lu Zhou, Xiaofei Tan, Xixian Huang

ABSTRACT

This paper explored biochar modification to enhance biochar’s ability to adsorb hexavalent chromium from aqueous solution. The ramie stem biomass was pyrolyzed and then treated by β-cyclodextrin/poly(L-glutamic acid) which contained plentiful functional groups. The pristine and modified biochar were characterized by FTIR, X-ray photoelectron spectroscopy, specific surface area, and zeta potential measurement. Results indicated that the β-cyclodextrin/poly(L-glutamic acid) was successfully bound to the biochar surface. Batch experiments were conducted to investigate the kinetics, isotherm, thermodynamics, and adsorption/desorption of Cr(VI). Adsorption capacities of CGA-biochar were significantly higher than that of the untreated biochar, and its maximum adsorption capacity could reach up to 197.21 mg/g at pH 2.0. Results also illustrated that sorption performance depended on initial solution pH; in addition, acidic condition was beneficial to the Cr(VI) uptake. Furthermore, the Cr(VI) uptake was significantly affected by the ion strength and cation species. This study demonstrated that CGA-biochar could be a potential adsorbent for Cr(VI) pollution control. More... »

PAGES

23528-23537

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11356-017-9833-4

DOI

http://dx.doi.org/10.1007/s11356-017-9833-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1091378613

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/28852975


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