Combustion of pistachio shell: physicochemical characterization and evaluation of kinetic parameters View Full Text


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Article Info

DATE

2017-04-06

AUTHORS

Jean Constantino Gomes da Silva, José Luiz Francisco Alves, Wendell Venicio de Araujo Galdino, Regina de Fátima Peralta Muniz Moreira, Humberto Jorge José, Rennio Felix de Sena, Silvia Layara Floriani Andersen

ABSTRACT

The study of different renewable energy sources has been intensifying due to the current climate changes; therefore, the present work had the objective to characterize physicochemically the pistachio shell waste and evaluate kinetic parameters of its combustion. The pistachio shell was characterized through proximate analysis, ultimate analysis, SEM, and FTIR. The thermal and kinetic behaviors were evaluated by a thermogravimetric analyzer under oxidant atmosphere between room temperature and 1000 °C, in which the process was performed in three different heating rates (20, 30, and 40 °C min−1). The combustion of the pistachio shell presented two regions in the derivative thermogravimetric curves, where the first represents the devolatilization of volatile matter compounds and the second one is associated to the biochar oxidation. These zones were considered for the evaluation of the kinetic parameters Ea, A, and f(α) by the modified method of Coats-Redfern, compensation effect, and master plot, respectively. The kinetic parameters for zone 1 were Ea1 = 84.11 kJ mol−1, A1 = 6.39 × 106 min−1, and f(α)1 = 3(1 − α)2/3, while for zone 2, the kinetic parameters were Ea2 = 37.47 kJ mol−1, A2 = 57.14 min−1, and f(α)2 = 2(1 − α)1/2. More... »

PAGES

21420-21429

References to SciGraph publications

  • 2015-03-19. Assessment of Pistachio Shell Biochar Quality and Its Potential for Adsorption of Heavy Metals in WASTE AND BIOMASS VALORIZATION
  • 2014-06-18. Pyrolysis kinetics of elephant grass pretreated biomasses in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 1977-06. Rational approximations of the integral of the Arrhenius function in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2015-08-02. The energetic characterization of pineapple crown leaves in ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
  • 2016-10-27. Thermochemical conversion of waste tyres—a review in ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
  • 2013-09-26. Pathways of lignocellulosic biomass conversion to renewable fuels in BIOMASS CONVERSION AND BIOREFINERY
  • 2010-02-07. Biomass Residues in Brazil: Availability and Potential Uses in WASTE AND BIOMASS VALORIZATION
  • 2013-02-12. Thermal characteristics of the combustion process of biomass and sewage sludge in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2014-12-27. Combustion characteristics of Turkish hazelnut shell biomass, lignite coal, and their respective blends via thermogravimetric analysis in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s11356-017-8945-1

    DOI

    http://dx.doi.org/10.1007/s11356-017-8945-1

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1084519547

    PUBMED

    https://www.ncbi.nlm.nih.gov/pubmed/28386892


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