Photooxidation of herbicide amitrole in the presence of fulvic acid View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-07

AUTHORS

Ivan P. Pozdnyakov, Peter S. Sherin, Victoria A. Salomatova, Marina V. Parkhats, Vjacheslav P. Grivin, Boris M. Dzhagarov, Nikolai M. Bazhin, Victor F. Plyusnin

ABSTRACT

Fulvic acid (Henan ChangSheng Corporation) photoinduced degradation of non-UVA-absorbing herbicide amitrole (3-amino-1,2,4-triazole, AMT) as a way for its removal from polluted water was investigated in details. It was shown that the main primary species generated by fulvic acid under UVA radiation, triplet state and hydrated electron, are not directly involved in the herbicide degradation. AMT decays in reactions with secondary intermediates, reactive oxygen species, formed in reactions of the primary ones with dissolved oxygen. Singlet oxygen is responsible for 80% of herbicide oxidation, and OH and O2-• radicals-for the remaining 20% of AMT. It was found that quantum yield of AMT photodegradation (ϕ 365nm) decreases linearly from 2.2 × 10-3 to 1.2 × 10-3 with the increase of fulvic acid concentration from 1.1 to 30 mg L-1. On the contrary, the increase of AMT concentration from 0.8 to 25 mg L-1 leads to practically linear growth of ϕ 365nm value from 1.8 × 10-4 to 4 × 10-3. Thus, the fulvic acid exhibits a good potential as UVA photooxidizer of organic pollutants sensitive to the singlet oxygen (ϕ 532nm(1O2) = 0.025 at pH 6.5). More... »

PAGES

20320-20327

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11356-017-8580-x

DOI

http://dx.doi.org/10.1007/s11356-017-8580-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1083862602

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/28233210


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    "description": "Fulvic acid (Henan ChangSheng Corporation) photoinduced degradation of non-UVA-absorbing herbicide amitrole (3-amino-1,2,4-triazole, AMT) as a way for its removal from polluted water was investigated in details. It was shown that the main primary species generated by fulvic acid under UVA radiation, triplet state and hydrated electron, are not directly involved in the herbicide degradation. AMT decays in reactions with secondary intermediates, reactive oxygen species, formed in reactions of the primary ones with dissolved oxygen. Singlet oxygen is responsible for 80% of herbicide oxidation, and \u2022OH and O2-\u2022 radicals-for the remaining 20% of AMT. It was found that quantum yield of AMT photodegradation (\u03d5 365nm) decreases linearly from 2.2\u00a0\u00d7\u00a010-3 to 1.2\u00a0\u00d7\u00a010-3 with the increase of fulvic acid concentration from 1.1 to 30\u00a0mg L-1. On the contrary, the increase of AMT concentration from 0.8 to 25\u00a0mg L-1 leads to practically linear growth of \u03d5 365nm value from 1.8\u00a0\u00d7\u00a010-4 to 4\u00a0\u00d7\u00a010-3. Thus, the fulvic acid exhibits a good potential as UVA photooxidizer of organic pollutants sensitive to the singlet oxygen (\u03d5 532nm(1O2)\u00a0=\u00a00.025 at pH\u00a06.5).", 
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