Photocatalytic decomposition of N2O over g-C3N4/WO3 photocatalysts View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-12

AUTHORS

Martin Reli, Ladislav Svoboda, Marcel Šihor, Ivana Troppová, Jiří Pavlovský, Petr Praus, Kamila Kočí

ABSTRACT

Although the nitrous oxide belongs among three of the most contributing greenhouse gases to global warming, it is quite neglected by photocatalytic society. The g-C3N4 and WO3 composites were therefore tested for the photocatalytic decomposition of N2O for the first time. The pure photocatalysts were prepared by simple calcination of precursors, and the composites were prepared by mixing of suspension of pure components in water followed by calcination. The structural (X-ray diffraction, X-ray photoelectron spectroscopy, high-resolution transmission electron microscopy), textural (N2 physisorption), and optical properties (diffuse reflectance spectroscopy, photoluminescence spectroscopy, photoelectrochemical measurements) of all composites were correlated with photocatalytic activity. The experimental results and results from characterization techniques confirmed creation of Z-scheme in the WO3/g-C3N4 composites, which was confirmed by hydroxyl radicals' trapping measurements. The photocatalytic decomposition of N2O was carried out in the presence of UVA light (peak intensity at 365 nm) and the 1:2 WO3/g-C3N4 composite was the most active one, but the photocatalytic activity was just negligibly higher than that of pure WO3. This is caused by relatively weak interaction between WO3 and g-C3N4 which was revealed from XPS. More... »

PAGES

1-12

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11356-017-0723-6

DOI

http://dx.doi.org/10.1007/s11356-017-0723-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1092975957

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/29177995


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0299", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Other Physical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/02", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Technical University of Ostrava", 
          "id": "https://www.grid.ac/institutes/grid.440850.d", 
          "name": [
            "Institute of Environmental Technology, V\u0160B-Technical University of Ostrava, 17. listopadu 15/2172, 708 33, Ostrava, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Reli", 
        "givenName": "Martin", 
        "id": "sg:person.013765233737.24", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013765233737.24"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Technical University of Ostrava", 
          "id": "https://www.grid.ac/institutes/grid.440850.d", 
          "name": [
            "Institute of Environmental Technology, V\u0160B-Technical University of Ostrava, 17. listopadu 15/2172, 708 33, Ostrava, Czech Republic", 
            "Department of Chemistry, V\u0160B-Technical University of Ostrava, 17. listopadu 15/2172, 708 33, Ostrava, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Svoboda", 
        "givenName": "Ladislav", 
        "id": "sg:person.011470626061.49", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011470626061.49"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Technical University of Ostrava", 
          "id": "https://www.grid.ac/institutes/grid.440850.d", 
          "name": [
            "Institute of Environmental Technology, V\u0160B-Technical University of Ostrava, 17. listopadu 15/2172, 708 33, Ostrava, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "\u0160ihor", 
        "givenName": "Marcel", 
        "id": "sg:person.01163537251.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01163537251.37"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Technical University of Ostrava", 
          "id": "https://www.grid.ac/institutes/grid.440850.d", 
          "name": [
            "Institute of Environmental Technology, V\u0160B-Technical University of Ostrava, 17. listopadu 15/2172, 708 33, Ostrava, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Troppov\u00e1", 
        "givenName": "Ivana", 
        "id": "sg:person.016537430651.44", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016537430651.44"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Technical University of Ostrava", 
          "id": "https://www.grid.ac/institutes/grid.440850.d", 
          "name": [
            "Department of Chemistry, V\u0160B-Technical University of Ostrava, 17. listopadu 15/2172, 708 33, Ostrava, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Pavlovsk\u00fd", 
        "givenName": "Ji\u0159\u00ed", 
        "id": "sg:person.011044450173.54", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011044450173.54"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Technical University of Ostrava", 
          "id": "https://www.grid.ac/institutes/grid.440850.d", 
          "name": [
            "Institute of Environmental Technology, V\u0160B-Technical University of Ostrava, 17. listopadu 15/2172, 708 33, Ostrava, Czech Republic", 
            "Department of Chemistry, V\u0160B-Technical University of Ostrava, 17. listopadu 15/2172, 708 33, Ostrava, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Praus", 
        "givenName": "Petr", 
        "id": "sg:person.015551263113.47", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015551263113.47"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Technical University of Ostrava", 
          "id": "https://www.grid.ac/institutes/grid.440850.d", 
          "name": [
            "Institute of Environmental Technology, V\u0160B-Technical University of Ostrava, 17. listopadu 15/2172, 708 33, Ostrava, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ko\u010d\u00ed", 
        "givenName": "Kamila", 
        "id": "sg:person.014307014140.25", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014307014140.25"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1038/srep01943", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000092376", 
          "https://doi.org/10.1038/srep01943"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.ijhydene.2016.11.105", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000333837"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.solmat.2016.11.005", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006201247"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c6cp00353b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007601579"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11237-015-9423-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008787314", 
          "https://doi.org/10.1007/s11237-015-9423-9"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/cssc.201500024", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010765196"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0005-2728(95)00092-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012498882"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/a:1019050815670", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014641456", 
          "https://doi.org/10.1023/a:1019050815670"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.201205333", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014924645"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.ceramint.2014.12.140", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017418410"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c6cp08066a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017527642"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c6nj01749e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021619221"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/978-3-662-48719-8_10", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023838572", 
          "https://doi.org/10.1007/978-3-662-48719-8_10"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c6ce01557c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024896898"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11356-016-6103-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025316886", 
          "https://doi.org/10.1007/s11356-016-6103-9"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jallcom.2011.07.082", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028109574"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.apsusc.2016.07.055", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031374756"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0365110x66000628", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031713510"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11144-014-0787-y", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033433472", 
          "https://doi.org/10.1007/s11144-014-0787-y"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00339-015-9128-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035754828", 
          "https://doi.org/10.1007/s00339-015-9128-x"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.apsusc.2016.11.242", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038713051"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c6ra12861k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038727867"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10854-015-2823-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042985827", 
          "https://doi.org/10.1007/s10854-015-2823-8"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.diamond.2013.06.012", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045268546"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.apsusc.2016.08.120", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048542105"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.3390/nano6090173", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049013535"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.matchemphys.2014.11.001", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049373332"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10562-015-1612-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049840765", 
          "https://doi.org/10.1007/s10562-015-1612-6"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/acs.jpca.6b07236", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055105290"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/acssuschemeng.6b01266", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055140314"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp901097b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056113754"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp901097b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056113754"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.apsusc.2017.02.025", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1083747189"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.matchemphys.2017.03.008", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1084094699"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/1361-6528/aa651a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1084172765"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s1872-2067(17)62759-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1084676002"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/smtd.201700080", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1084909347"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c7ra02297b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1085125925"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.apsusc.2017.06.299", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1090292395"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.ceramint.2017.07.067", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1090599797"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2018-12", 
    "datePublishedReg": "2018-12-01", 
    "description": "Although the nitrous oxide belongs among three of the most contributing greenhouse gases to global warming, it is quite neglected by photocatalytic society. The g-C3N4 and WO3 composites were therefore tested for the photocatalytic decomposition of N2O for the first time. The pure photocatalysts were prepared by simple calcination of precursors, and the composites were prepared by mixing of suspension of pure components in water followed by calcination. The structural (X-ray diffraction, X-ray photoelectron spectroscopy, high-resolution transmission electron microscopy), textural (N2 physisorption), and optical properties (diffuse reflectance spectroscopy, photoluminescence spectroscopy, photoelectrochemical measurements) of all composites were correlated with photocatalytic activity. The experimental results and results from characterization techniques confirmed creation of Z-scheme in the WO3/g-C3N4 composites, which was confirmed by hydroxyl radicals' trapping measurements. The photocatalytic decomposition of N2O was carried out in the presence of UVA light (peak intensity at 365\u00a0nm) and the 1:2 WO3/g-C3N4 composite was the most active one, but the photocatalytic activity was just negligibly higher than that of pure WO3. This is caused by relatively weak interaction between WO3 and g-C3N4 which was revealed from XPS.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s11356-017-0723-6", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isFundedItemOf": [
      {
        "id": "sg:grant.6904693", 
        "type": "MonetaryGrant"
      }
    ], 
    "isPartOf": [
      {
        "id": "sg:journal.1113424", 
        "issn": [
          "0944-1344", 
          "1614-7499"
        ], 
        "name": "Environmental Science and Pollution Research", 
        "type": "Periodical"
      }
    ], 
    "name": "Photocatalytic decomposition of N2O over g-C3N4/WO3 photocatalysts", 
    "pagination": "1-12", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "35e286b93a9c39886790052c3a8b752455c4622695dc70f125c0c788cf9fac75"
        ]
      }, 
      {
        "name": "pubmed_id", 
        "type": "PropertyValue", 
        "value": [
          "29177995"
        ]
      }, 
      {
        "name": "nlm_unique_id", 
        "type": "PropertyValue", 
        "value": [
          "9441769"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11356-017-0723-6"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1092975957"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11356-017-0723-6", 
      "https://app.dimensions.ai/details/publication/pub.1092975957"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T16:04", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8664_00000601.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007/s11356-017-0723-6"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11356-017-0723-6'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11356-017-0723-6'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11356-017-0723-6'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11356-017-0723-6'


 

This table displays all metadata directly associated to this object as RDF triples.

234 TRIPLES      21 PREDICATES      66 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11356-017-0723-6 schema:about anzsrc-for:02
2 anzsrc-for:0299
3 schema:author N146ce96279a64730b215bc96980d607f
4 schema:citation sg:pub.10.1007/978-3-662-48719-8_10
5 sg:pub.10.1007/s00339-015-9128-x
6 sg:pub.10.1007/s10562-015-1612-6
7 sg:pub.10.1007/s10854-015-2823-8
8 sg:pub.10.1007/s11144-014-0787-y
9 sg:pub.10.1007/s11237-015-9423-9
10 sg:pub.10.1007/s11356-016-6103-9
11 sg:pub.10.1023/a:1019050815670
12 sg:pub.10.1038/srep01943
13 https://doi.org/10.1002/anie.201205333
14 https://doi.org/10.1002/cssc.201500024
15 https://doi.org/10.1002/smtd.201700080
16 https://doi.org/10.1016/0005-2728(95)00092-5
17 https://doi.org/10.1016/j.apsusc.2016.07.055
18 https://doi.org/10.1016/j.apsusc.2016.08.120
19 https://doi.org/10.1016/j.apsusc.2016.11.242
20 https://doi.org/10.1016/j.apsusc.2017.02.025
21 https://doi.org/10.1016/j.apsusc.2017.06.299
22 https://doi.org/10.1016/j.ceramint.2014.12.140
23 https://doi.org/10.1016/j.ceramint.2017.07.067
24 https://doi.org/10.1016/j.diamond.2013.06.012
25 https://doi.org/10.1016/j.ijhydene.2016.11.105
26 https://doi.org/10.1016/j.jallcom.2011.07.082
27 https://doi.org/10.1016/j.matchemphys.2014.11.001
28 https://doi.org/10.1016/j.matchemphys.2017.03.008
29 https://doi.org/10.1016/j.solmat.2016.11.005
30 https://doi.org/10.1016/s1872-2067(17)62759-1
31 https://doi.org/10.1021/acs.jpca.6b07236
32 https://doi.org/10.1021/acssuschemeng.6b01266
33 https://doi.org/10.1021/jp901097b
34 https://doi.org/10.1039/c6ce01557c
35 https://doi.org/10.1039/c6cp00353b
36 https://doi.org/10.1039/c6cp08066a
37 https://doi.org/10.1039/c6nj01749e
38 https://doi.org/10.1039/c6ra12861k
39 https://doi.org/10.1039/c7ra02297b
40 https://doi.org/10.1088/1361-6528/aa651a
41 https://doi.org/10.1107/s0365110x66000628
42 https://doi.org/10.3390/nano6090173
43 schema:datePublished 2018-12
44 schema:datePublishedReg 2018-12-01
45 schema:description Although the nitrous oxide belongs among three of the most contributing greenhouse gases to global warming, it is quite neglected by photocatalytic society. The g-C<sub>3</sub>N<sub>4</sub> and WO<sub>3</sub> composites were therefore tested for the photocatalytic decomposition of N<sub>2</sub>O for the first time. The pure photocatalysts were prepared by simple calcination of precursors, and the composites were prepared by mixing of suspension of pure components in water followed by calcination. The structural (X-ray diffraction, X-ray photoelectron spectroscopy, high-resolution transmission electron microscopy), textural (N<sub>2</sub> physisorption), and optical properties (diffuse reflectance spectroscopy, photoluminescence spectroscopy, photoelectrochemical measurements) of all composites were correlated with photocatalytic activity. The experimental results and results from characterization techniques confirmed creation of Z-scheme in the WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> composites, which was confirmed by hydroxyl radicals' trapping measurements. The photocatalytic decomposition of N<sub>2</sub>O was carried out in the presence of UVA light (peak intensity at 365 nm) and the 1:2 WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> composite was the most active one, but the photocatalytic activity was just negligibly higher than that of pure WO<sub>3</sub>. This is caused by relatively weak interaction between WO<sub>3</sub> and g-C<sub>3</sub>N<sub>4</sub> which was revealed from XPS.
46 schema:genre research_article
47 schema:inLanguage en
48 schema:isAccessibleForFree false
49 schema:isPartOf sg:journal.1113424
50 schema:name Photocatalytic decomposition of N2O over g-C3N4/WO3 photocatalysts
51 schema:pagination 1-12
52 schema:productId N31f282200be24898a24af38d1e87f879
53 N4a9da5a42bef477393a48e3c6dbbab48
54 Na6a94277f1cc424bbaeededae8f496f3
55 Nab88ae5ef8c24ea795afee87ba6b3bd4
56 Nf28a0112ef2941d2b9d925d24b2e8b89
57 schema:sameAs https://app.dimensions.ai/details/publication/pub.1092975957
58 https://doi.org/10.1007/s11356-017-0723-6
59 schema:sdDatePublished 2019-04-10T16:04
60 schema:sdLicense https://scigraph.springernature.com/explorer/license/
61 schema:sdPublisher N2ebc9b88c71442d0810c53272729bc84
62 schema:url http://link.springer.com/10.1007/s11356-017-0723-6
63 sgo:license sg:explorer/license/
64 sgo:sdDataset articles
65 rdf:type schema:ScholarlyArticle
66 N146ce96279a64730b215bc96980d607f rdf:first sg:person.013765233737.24
67 rdf:rest Naf964d44d7dd42678ee6b5e0841e9142
68 N2ebc9b88c71442d0810c53272729bc84 schema:name Springer Nature - SN SciGraph project
69 rdf:type schema:Organization
70 N31f282200be24898a24af38d1e87f879 schema:name nlm_unique_id
71 schema:value 9441769
72 rdf:type schema:PropertyValue
73 N4a9da5a42bef477393a48e3c6dbbab48 schema:name readcube_id
74 schema:value 35e286b93a9c39886790052c3a8b752455c4622695dc70f125c0c788cf9fac75
75 rdf:type schema:PropertyValue
76 N740a528ef67a4300806b20d5783e6a01 rdf:first sg:person.015551263113.47
77 rdf:rest Ncde6035217d740d2bdb8e3d76bef48df
78 Na6a94277f1cc424bbaeededae8f496f3 schema:name pubmed_id
79 schema:value 29177995
80 rdf:type schema:PropertyValue
81 Nab88ae5ef8c24ea795afee87ba6b3bd4 schema:name dimensions_id
82 schema:value pub.1092975957
83 rdf:type schema:PropertyValue
84 Naf964d44d7dd42678ee6b5e0841e9142 rdf:first sg:person.011470626061.49
85 rdf:rest Ne991221bbde94ef99390247a2e493750
86 Ncc3ae7d1cb8f4f09b6d63113098cb684 rdf:first sg:person.011044450173.54
87 rdf:rest N740a528ef67a4300806b20d5783e6a01
88 Ncde6035217d740d2bdb8e3d76bef48df rdf:first sg:person.014307014140.25
89 rdf:rest rdf:nil
90 Ndb61bd70a9ce464fbbaf375db148a3ed rdf:first sg:person.016537430651.44
91 rdf:rest Ncc3ae7d1cb8f4f09b6d63113098cb684
92 Ne991221bbde94ef99390247a2e493750 rdf:first sg:person.01163537251.37
93 rdf:rest Ndb61bd70a9ce464fbbaf375db148a3ed
94 Nf28a0112ef2941d2b9d925d24b2e8b89 schema:name doi
95 schema:value 10.1007/s11356-017-0723-6
96 rdf:type schema:PropertyValue
97 anzsrc-for:02 schema:inDefinedTermSet anzsrc-for:
98 schema:name Physical Sciences
99 rdf:type schema:DefinedTerm
100 anzsrc-for:0299 schema:inDefinedTermSet anzsrc-for:
101 schema:name Other Physical Sciences
102 rdf:type schema:DefinedTerm
103 sg:grant.6904693 http://pending.schema.org/fundedItem sg:pub.10.1007/s11356-017-0723-6
104 rdf:type schema:MonetaryGrant
105 sg:journal.1113424 schema:issn 0944-1344
106 1614-7499
107 schema:name Environmental Science and Pollution Research
108 rdf:type schema:Periodical
109 sg:person.011044450173.54 schema:affiliation https://www.grid.ac/institutes/grid.440850.d
110 schema:familyName Pavlovský
111 schema:givenName Jiří
112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011044450173.54
113 rdf:type schema:Person
114 sg:person.011470626061.49 schema:affiliation https://www.grid.ac/institutes/grid.440850.d
115 schema:familyName Svoboda
116 schema:givenName Ladislav
117 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011470626061.49
118 rdf:type schema:Person
119 sg:person.01163537251.37 schema:affiliation https://www.grid.ac/institutes/grid.440850.d
120 schema:familyName Šihor
121 schema:givenName Marcel
122 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01163537251.37
123 rdf:type schema:Person
124 sg:person.013765233737.24 schema:affiliation https://www.grid.ac/institutes/grid.440850.d
125 schema:familyName Reli
126 schema:givenName Martin
127 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013765233737.24
128 rdf:type schema:Person
129 sg:person.014307014140.25 schema:affiliation https://www.grid.ac/institutes/grid.440850.d
130 schema:familyName Kočí
131 schema:givenName Kamila
132 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014307014140.25
133 rdf:type schema:Person
134 sg:person.015551263113.47 schema:affiliation https://www.grid.ac/institutes/grid.440850.d
135 schema:familyName Praus
136 schema:givenName Petr
137 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015551263113.47
138 rdf:type schema:Person
139 sg:person.016537430651.44 schema:affiliation https://www.grid.ac/institutes/grid.440850.d
140 schema:familyName Troppová
141 schema:givenName Ivana
142 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016537430651.44
143 rdf:type schema:Person
144 sg:pub.10.1007/978-3-662-48719-8_10 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023838572
145 https://doi.org/10.1007/978-3-662-48719-8_10
146 rdf:type schema:CreativeWork
147 sg:pub.10.1007/s00339-015-9128-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1035754828
148 https://doi.org/10.1007/s00339-015-9128-x
149 rdf:type schema:CreativeWork
150 sg:pub.10.1007/s10562-015-1612-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049840765
151 https://doi.org/10.1007/s10562-015-1612-6
152 rdf:type schema:CreativeWork
153 sg:pub.10.1007/s10854-015-2823-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042985827
154 https://doi.org/10.1007/s10854-015-2823-8
155 rdf:type schema:CreativeWork
156 sg:pub.10.1007/s11144-014-0787-y schema:sameAs https://app.dimensions.ai/details/publication/pub.1033433472
157 https://doi.org/10.1007/s11144-014-0787-y
158 rdf:type schema:CreativeWork
159 sg:pub.10.1007/s11237-015-9423-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008787314
160 https://doi.org/10.1007/s11237-015-9423-9
161 rdf:type schema:CreativeWork
162 sg:pub.10.1007/s11356-016-6103-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025316886
163 https://doi.org/10.1007/s11356-016-6103-9
164 rdf:type schema:CreativeWork
165 sg:pub.10.1023/a:1019050815670 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014641456
166 https://doi.org/10.1023/a:1019050815670
167 rdf:type schema:CreativeWork
168 sg:pub.10.1038/srep01943 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000092376
169 https://doi.org/10.1038/srep01943
170 rdf:type schema:CreativeWork
171 https://doi.org/10.1002/anie.201205333 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014924645
172 rdf:type schema:CreativeWork
173 https://doi.org/10.1002/cssc.201500024 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010765196
174 rdf:type schema:CreativeWork
175 https://doi.org/10.1002/smtd.201700080 schema:sameAs https://app.dimensions.ai/details/publication/pub.1084909347
176 rdf:type schema:CreativeWork
177 https://doi.org/10.1016/0005-2728(95)00092-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012498882
178 rdf:type schema:CreativeWork
179 https://doi.org/10.1016/j.apsusc.2016.07.055 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031374756
180 rdf:type schema:CreativeWork
181 https://doi.org/10.1016/j.apsusc.2016.08.120 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048542105
182 rdf:type schema:CreativeWork
183 https://doi.org/10.1016/j.apsusc.2016.11.242 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038713051
184 rdf:type schema:CreativeWork
185 https://doi.org/10.1016/j.apsusc.2017.02.025 schema:sameAs https://app.dimensions.ai/details/publication/pub.1083747189
186 rdf:type schema:CreativeWork
187 https://doi.org/10.1016/j.apsusc.2017.06.299 schema:sameAs https://app.dimensions.ai/details/publication/pub.1090292395
188 rdf:type schema:CreativeWork
189 https://doi.org/10.1016/j.ceramint.2014.12.140 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017418410
190 rdf:type schema:CreativeWork
191 https://doi.org/10.1016/j.ceramint.2017.07.067 schema:sameAs https://app.dimensions.ai/details/publication/pub.1090599797
192 rdf:type schema:CreativeWork
193 https://doi.org/10.1016/j.diamond.2013.06.012 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045268546
194 rdf:type schema:CreativeWork
195 https://doi.org/10.1016/j.ijhydene.2016.11.105 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000333837
196 rdf:type schema:CreativeWork
197 https://doi.org/10.1016/j.jallcom.2011.07.082 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028109574
198 rdf:type schema:CreativeWork
199 https://doi.org/10.1016/j.matchemphys.2014.11.001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049373332
200 rdf:type schema:CreativeWork
201 https://doi.org/10.1016/j.matchemphys.2017.03.008 schema:sameAs https://app.dimensions.ai/details/publication/pub.1084094699
202 rdf:type schema:CreativeWork
203 https://doi.org/10.1016/j.solmat.2016.11.005 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006201247
204 rdf:type schema:CreativeWork
205 https://doi.org/10.1016/s1872-2067(17)62759-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1084676002
206 rdf:type schema:CreativeWork
207 https://doi.org/10.1021/acs.jpca.6b07236 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055105290
208 rdf:type schema:CreativeWork
209 https://doi.org/10.1021/acssuschemeng.6b01266 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055140314
210 rdf:type schema:CreativeWork
211 https://doi.org/10.1021/jp901097b schema:sameAs https://app.dimensions.ai/details/publication/pub.1056113754
212 rdf:type schema:CreativeWork
213 https://doi.org/10.1039/c6ce01557c schema:sameAs https://app.dimensions.ai/details/publication/pub.1024896898
214 rdf:type schema:CreativeWork
215 https://doi.org/10.1039/c6cp00353b schema:sameAs https://app.dimensions.ai/details/publication/pub.1007601579
216 rdf:type schema:CreativeWork
217 https://doi.org/10.1039/c6cp08066a schema:sameAs https://app.dimensions.ai/details/publication/pub.1017527642
218 rdf:type schema:CreativeWork
219 https://doi.org/10.1039/c6nj01749e schema:sameAs https://app.dimensions.ai/details/publication/pub.1021619221
220 rdf:type schema:CreativeWork
221 https://doi.org/10.1039/c6ra12861k schema:sameAs https://app.dimensions.ai/details/publication/pub.1038727867
222 rdf:type schema:CreativeWork
223 https://doi.org/10.1039/c7ra02297b schema:sameAs https://app.dimensions.ai/details/publication/pub.1085125925
224 rdf:type schema:CreativeWork
225 https://doi.org/10.1088/1361-6528/aa651a schema:sameAs https://app.dimensions.ai/details/publication/pub.1084172765
226 rdf:type schema:CreativeWork
227 https://doi.org/10.1107/s0365110x66000628 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031713510
228 rdf:type schema:CreativeWork
229 https://doi.org/10.3390/nano6090173 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049013535
230 rdf:type schema:CreativeWork
231 https://www.grid.ac/institutes/grid.440850.d schema:alternateName Technical University of Ostrava
232 schema:name Department of Chemistry, VŠB-Technical University of Ostrava, 17. listopadu 15/2172, 708 33, Ostrava, Czech Republic
233 Institute of Environmental Technology, VŠB-Technical University of Ostrava, 17. listopadu 15/2172, 708 33, Ostrava, Czech Republic
234 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...