Ontology type: schema:ScholarlyArticle
2017-03
AUTHORSSandra Stets, Bianca do Amaral, Larissa Bach, Noemi Nagata, Patricio G. Peralta-Zamora
ABSTRACTThis study focuses on the feasibility of a spectroscopic multivariate method for monitoring the concentration of phenol and its main degradation products during heterogeneous photocatalysis. Phenolic compounds were chosen as model to evaluate the degradation process due to their toxicity and persistence in the environment and also their well-known degradation pathway. The predictive capability of the multivariate method developed by partial least squares regression (PLSR) over the spectral range of 200-350 nm was satisfactory, allowing mean predicted errors below 5.0 % in the simultaneous determination of the target compounds using six latent variables and smoothing spectra. Suitable results were reported for the simultaneous determination of hydroquinone, resorcinol, pyrocatechol, and p-benzoquinone in accordance to the chromatographic method. Characteristics such as simplicity, low cost, and fast data acquisition are remarkable in this procedure, which makes it appropriate for this type of analytical control. More... »
PAGES6040-6046
http://scigraph.springernature.com/pub.10.1007/s11356-016-7232-x
DOIhttp://dx.doi.org/10.1007/s11356-016-7232-x
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1038932108
PUBMEDhttps://www.ncbi.nlm.nih.gov/pubmed/27448812
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0907",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Environmental Engineering",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Engineering",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Models, Chemical",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Phenols",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Photolysis",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Titanium",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Federal University of Paran\u00e1",
"id": "https://www.grid.ac/institutes/grid.20736.30",
"name": [
"Chemistry Department, Universidade Federal do Paran\u00e1, Av. Francisco H. dos Santos, s/n, Jardim das Am\u00e9ricas, CP 19032, 81531-980, Curitiba, Paran\u00e1, Brazil"
],
"type": "Organization"
},
"familyName": "Stets",
"givenName": "Sandra",
"id": "sg:person.011245345525.02",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011245345525.02"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Federal University of Paran\u00e1",
"id": "https://www.grid.ac/institutes/grid.20736.30",
"name": [
"Chemistry Department, Universidade Federal do Paran\u00e1, Av. Francisco H. dos Santos, s/n, Jardim das Am\u00e9ricas, CP 19032, 81531-980, Curitiba, Paran\u00e1, Brazil"
],
"type": "Organization"
},
"familyName": "do Amaral",
"givenName": "Bianca",
"id": "sg:person.015330767331.76",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015330767331.76"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Federal University of Paran\u00e1",
"id": "https://www.grid.ac/institutes/grid.20736.30",
"name": [
"Chemistry Department, Universidade Federal do Paran\u00e1, Av. Francisco H. dos Santos, s/n, Jardim das Am\u00e9ricas, CP 19032, 81531-980, Curitiba, Paran\u00e1, Brazil"
],
"type": "Organization"
},
"familyName": "Bach",
"givenName": "Larissa",
"id": "sg:person.012640306525.15",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012640306525.15"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Federal University of Paran\u00e1",
"id": "https://www.grid.ac/institutes/grid.20736.30",
"name": [
"Chemistry Department, Universidade Federal do Paran\u00e1, Av. Francisco H. dos Santos, s/n, Jardim das Am\u00e9ricas, CP 19032, 81531-980, Curitiba, Paran\u00e1, Brazil"
],
"type": "Organization"
},
"familyName": "Nagata",
"givenName": "Noemi",
"id": "sg:person.010637476660.65",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010637476660.65"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Federal University of Paran\u00e1",
"id": "https://www.grid.ac/institutes/grid.20736.30",
"name": [
"Chemistry Department, Universidade Federal do Paran\u00e1, Av. Francisco H. dos Santos, s/n, Jardim das Am\u00e9ricas, CP 19032, 81531-980, Curitiba, Paran\u00e1, Brazil"
],
"type": "Organization"
},
"familyName": "Peralta-Zamora",
"givenName": "Patricio G.",
"id": "sg:person.0611460030.41",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0611460030.41"
],
"type": "Person"
}
],
"citation": [
{
"id": "https://doi.org/10.1016/s0926-3373(00)00248-4",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1003439017"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.apcatb.2011.11.024",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1005988751"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.saa.2015.07.101",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1008298162"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.apcatb.2004.11.008",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1009288577"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.jelechem.2012.03.006",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1012269270"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.jhazmat.2009.05.113",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1014109456"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.talanta.2009.08.039",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1018565246"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.talanta.2014.02.003",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1022729054"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1155/2013/364275",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1023117885"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s1389-5567(00)00002-2",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1026348006"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.trac.2015.02.015",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1026484910"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.watres.2012.07.048",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1028565923"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.cej.2006.01.017",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1030683173"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.apcatb.2008.04.015",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1033285495"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.talanta.2009.09.044",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1035267277"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.scitotenv.2015.05.085",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1036491759"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.talanta.2008.06.008",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1036680830"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0926-3373(02)00266-7",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1037155088"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0926-3373(02)00266-7",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1037155088"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.aca.2007.04.010",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1037592283"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.apcatb.2014.02.006",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1038988230"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.jenvman.2014.03.006",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1040619672"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.apcatb.2008.02.011",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1041573339"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.jphotochemrev.2010.01.001",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1042835425"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.aca.2005.12.001",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1050108509"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.cattod.2015.03.048",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1051585955"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.molcata.2003.12.006",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1052101454"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ac00162a020",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1054977122"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jp077191d",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056074728"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jp077191d",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056074728"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1590/s0100-40421999000500016",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1068100449"
],
"type": "CreativeWork"
}
],
"datePublished": "2017-03",
"datePublishedReg": "2017-03-01",
"description": "This study focuses on the feasibility of a spectroscopic multivariate method for monitoring the concentration of phenol and its main degradation products during heterogeneous photocatalysis. Phenolic compounds were chosen as model to evaluate the degradation process due to their toxicity and persistence in the environment and also their well-known degradation pathway. The predictive capability of the multivariate method developed by partial least squares regression (PLSR) over the spectral range of 200-350\u00a0nm was satisfactory, allowing mean predicted errors below 5.0\u00a0% in the simultaneous determination of the target compounds using six latent variables and smoothing spectra. Suitable results were reported for the simultaneous determination of hydroquinone, resorcinol, pyrocatechol, and p-benzoquinone in accordance to the chromatographic method. Characteristics such as simplicity, low cost, and fast data acquisition are remarkable in this procedure, which makes it appropriate for this type of analytical control.",
"genre": "research_article",
"id": "sg:pub.10.1007/s11356-016-7232-x",
"inLanguage": [
"en"
],
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1113424",
"issn": [
"0944-1344",
"1614-7499"
],
"name": "Environmental Science and Pollution Research",
"type": "Periodical"
},
{
"issueNumber": "7",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "24"
}
],
"name": "New insight into monitoring degradation products during the TiO2-photocatalysis process by multivariate molecular spectroscopy",
"pagination": "6040-6046",
"productId": [
{
"name": "readcube_id",
"type": "PropertyValue",
"value": [
"b973c4427eefb7997801607e81fa9ad966391739cb72be0aa36960a5f3a9cca4"
]
},
{
"name": "pubmed_id",
"type": "PropertyValue",
"value": [
"27448812"
]
},
{
"name": "nlm_unique_id",
"type": "PropertyValue",
"value": [
"9441769"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/s11356-016-7232-x"
]
},
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1038932108"
]
}
],
"sameAs": [
"https://doi.org/10.1007/s11356-016-7232-x",
"https://app.dimensions.ai/details/publication/pub.1038932108"
],
"sdDataset": "articles",
"sdDatePublished": "2019-04-11T12:42",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000363_0000000363/records_70058_00000001.jsonl",
"type": "ScholarlyArticle",
"url": "https://link.springer.com/10.1007%2Fs11356-016-7232-x"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11356-016-7232-x'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11356-016-7232-x'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11356-016-7232-x'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11356-016-7232-x'
This table displays all metadata directly associated to this object as RDF triples.
200 TRIPLES
21 PREDICATES
62 URIs
25 LITERALS
13 BLANK NODES