Study of photodegradation and photooxidation of p-arsanilic acid in water solutions at pH = 7: kinetics and by-products View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-11

AUTHORS

Marianna Czaplicka, Katarzyna Jaworek, Marta Bąk

ABSTRACT

The paper presents the kinetics and proposed pathways photodegradation and photooxidation of p-arsanilic acid, in a neutral environment by ozone and hydrogen peroxide. The results showed that in a neutral environment, photoozonation process was characterized by the highest decomposition rate constant (k) (k = 31.8 × 10(-3) min(-1)). The rate constants decreased in the order UV/O3 > O3 > UV/H2O2 > H2O2 > UV. It was also found that under pH = 7, decomposition of p-arsanilic acid leads mainly to the formation of aniline, which undergoes secondary reactions. Intermediate products of oxidation and photooxidation by hydrogen peroxide like nitrobenzene, nitrophenol, azobenzenes, and phenylazophenol were identified depending on processes. However, in the photodegradation process, formation of nitrasone as a reaction product of p-arsanilic acid with oxygen in the singlet state was observed. In the case of ozonation and photoozonation, in addition, aniline formation of carboxylic acids was observed. More... »

PAGES

16927-16935

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11356-015-4890-z

DOI

http://dx.doi.org/10.1007/s11356-015-4890-z

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1020514324

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/26109222


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0399", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Other Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Arsanilic Acid", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Hydrogen Peroxide", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Hydrogen-Ion Concentration", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Oxidation-Reduction", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Ozone", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Photolysis", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Water", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Non-Ferrous Metals", 
          "id": "https://www.grid.ac/institutes/grid.425049.e", 
          "name": [
            "Institute of Non-Ferrous Metals, Sowinskiego 5, Gliwice, Poland"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Czaplicka", 
        "givenName": "Marianna", 
        "id": "sg:person.01371503045.05", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01371503045.05"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Non-Ferrous Metals", 
          "id": "https://www.grid.ac/institutes/grid.425049.e", 
          "name": [
            "Institute of Non-Ferrous Metals, Sowinskiego 5, Gliwice, Poland"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Jaworek", 
        "givenName": "Katarzyna", 
        "id": "sg:person.0646402205.11", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0646402205.11"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Non-Ferrous Metals", 
          "id": "https://www.grid.ac/institutes/grid.425049.e", 
          "name": [
            "Institute of Non-Ferrous Metals, Sowinskiego 5, Gliwice, Poland"
          ], 
          "type": "Organization"
        }, 
        "familyName": "B\u0105k", 
        "givenName": "Marta", 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/s0300-483x(00)00458-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005371285"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0003-2670(01)01477-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007554539"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s1010-6030(00)00223-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008375254"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0048-9697(02)00322-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009067332"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0048-9697(02)00322-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009067332"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/09593330.2012.752876", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010401159"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.trac.2005.06.004", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010485729"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0039-9140(95)01395-r", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011036903"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1006/taap.1999.8872", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012719216"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00483364", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012933130", 
          "https://doi.org/10.1007/bf00483364"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00483364", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012933130", 
          "https://doi.org/10.1007/bf00483364"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11270-010-0716-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015362037", 
          "https://doi.org/10.1007/s11270-010-0716-2"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0039-9140(02)00258-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016846501"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11356-014-2983-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019465821", 
          "https://doi.org/10.1007/s11356-014-2983-8"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.chroma.2004.06.016", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019659765"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.3390/molecules20022622", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019925165"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.3390/molecules20022622", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019925165"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0165-9936(95)91620-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024452464"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jhazmat.2009.10.010", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026279999"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.desal.2006.05.040", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027065599"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0304-3894(95)00089-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031842367"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.aca.2003.11.053", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032560061"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jhazmat.2010.12.005", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033078319"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0048-9697(99)00035-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033089916"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.talanta.2005.11.025", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033906498"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0045-6535(00)00060-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035232426"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0043-1354(03)00080-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037260966"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0043-1354(03)00080-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037260966"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.cattod.2013.09.040", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039627894"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0021-9673(95)00751-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039799074"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0969-806x(98)00348-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040419317"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.cattod.2004.04.020", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041359650"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.cattod.2004.04.020", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041359650"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jhazmat.2009.05.041", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041524713"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.cej.2014.01.016", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041708821"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.aca.2004.10.047", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042394543"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s1001-0742(08)62127-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042447759"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.chemosphere.2010.10.045", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046839655"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0045-6535(92)90060-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047095036"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0045-6535(92)90060-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047095036"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0043-1354(00)00182-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047556743"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.scitotenv.2005.03.031", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050190185"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0021-9673(98)00080-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050781764"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jo01269a035", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056009094"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp072135y", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056071592"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp072135y", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056071592"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/tx00034a025", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056296924"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1131574", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062454645"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2015-11", 
    "datePublishedReg": "2015-11-01", 
    "description": "The paper presents the kinetics and proposed pathways photodegradation and photooxidation of p-arsanilic acid, in a neutral environment by ozone and hydrogen peroxide. The results showed that in a neutral environment, photoozonation process was characterized by the highest decomposition rate constant (k) (k\u2009=\u200931.8\u2009\u00d7\u200910(-3)\u00a0min(-1)). The rate constants decreased in the order UV/O3 > O3 > UV/H2O2 > H2O2 > UV. It was also found that under pH = 7, decomposition of p-arsanilic acid leads mainly to the formation of aniline, which undergoes secondary reactions. Intermediate products of oxidation and photooxidation by hydrogen peroxide like nitrobenzene, nitrophenol, azobenzenes, and phenylazophenol were identified depending on processes. However, in the photodegradation process, formation of nitrasone as a reaction product of p-arsanilic acid with oxygen in the singlet state was observed. In the case of ozonation and photoozonation, in addition, aniline formation of carboxylic acids was observed. ", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s11356-015-4890-z", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1113424", 
        "issn": [
          "0944-1344", 
          "1614-7499"
        ], 
        "name": "Environmental Science and Pollution Research", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "21", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "22"
      }
    ], 
    "name": "Study of photodegradation and photooxidation of p-arsanilic acid in water solutions at pH = 7: kinetics and by-products", 
    "pagination": "16927-16935", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "61bf46c095da993148c07a24a6b52a58f8b881372a591824518bdb03f0e0e047"
        ]
      }, 
      {
        "name": "pubmed_id", 
        "type": "PropertyValue", 
        "value": [
          "26109222"
        ]
      }, 
      {
        "name": "nlm_unique_id", 
        "type": "PropertyValue", 
        "value": [
          "9441769"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11356-015-4890-z"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1020514324"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11356-015-4890-z", 
      "https://app.dimensions.ai/details/publication/pub.1020514324"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T22:34", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8690_00000521.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs11356-015-4890-z"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11356-015-4890-z'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11356-015-4890-z'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11356-015-4890-z'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11356-015-4890-z'


 

This table displays all metadata directly associated to this object as RDF triples.

236 TRIPLES      21 PREDICATES      77 URIs      28 LITERALS      16 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11356-015-4890-z schema:about N0647e74598f74915b89ec00df9624efe
2 N140a217388dc4ad9bba753e244d8a27b
3 N74666d38ac414020ab517e226f854d0e
4 N84e3c7ad9cf14a26a8a26b176717c066
5 N9298af08deaa4687941716e30d3d8ceb
6 N9836ecd41d4d425ca5a5ec93d8712bd0
7 Ncd6042d0ecd144c58c59e1be6527dfe8
8 anzsrc-for:03
9 anzsrc-for:0399
10 schema:author N678f6e78ad894e9db1e4e4952824f1a8
11 schema:citation sg:pub.10.1007/bf00483364
12 sg:pub.10.1007/s11270-010-0716-2
13 sg:pub.10.1007/s11356-014-2983-8
14 https://doi.org/10.1006/taap.1999.8872
15 https://doi.org/10.1016/0021-9673(95)00751-2
16 https://doi.org/10.1016/0039-9140(95)01395-r
17 https://doi.org/10.1016/0045-6535(92)90060-5
18 https://doi.org/10.1016/0165-9936(95)91620-8
19 https://doi.org/10.1016/0304-3894(95)00089-5
20 https://doi.org/10.1016/j.aca.2003.11.053
21 https://doi.org/10.1016/j.aca.2004.10.047
22 https://doi.org/10.1016/j.cattod.2004.04.020
23 https://doi.org/10.1016/j.cattod.2013.09.040
24 https://doi.org/10.1016/j.cej.2014.01.016
25 https://doi.org/10.1016/j.chemosphere.2010.10.045
26 https://doi.org/10.1016/j.chroma.2004.06.016
27 https://doi.org/10.1016/j.desal.2006.05.040
28 https://doi.org/10.1016/j.jhazmat.2009.05.041
29 https://doi.org/10.1016/j.jhazmat.2009.10.010
30 https://doi.org/10.1016/j.jhazmat.2010.12.005
31 https://doi.org/10.1016/j.scitotenv.2005.03.031
32 https://doi.org/10.1016/j.talanta.2005.11.025
33 https://doi.org/10.1016/j.trac.2005.06.004
34 https://doi.org/10.1016/s0003-2670(01)01477-5
35 https://doi.org/10.1016/s0021-9673(98)00080-6
36 https://doi.org/10.1016/s0039-9140(02)00258-8
37 https://doi.org/10.1016/s0043-1354(00)00182-2
38 https://doi.org/10.1016/s0043-1354(03)00080-0
39 https://doi.org/10.1016/s0045-6535(00)00060-6
40 https://doi.org/10.1016/s0048-9697(02)00322-4
41 https://doi.org/10.1016/s0048-9697(99)00035-2
42 https://doi.org/10.1016/s0300-483x(00)00458-3
43 https://doi.org/10.1016/s0969-806x(98)00348-x
44 https://doi.org/10.1016/s1001-0742(08)62127-0
45 https://doi.org/10.1016/s1010-6030(00)00223-9
46 https://doi.org/10.1021/jo01269a035
47 https://doi.org/10.1021/jp072135y
48 https://doi.org/10.1021/tx00034a025
49 https://doi.org/10.1080/09593330.2012.752876
50 https://doi.org/10.1126/science.1131574
51 https://doi.org/10.3390/molecules20022622
52 schema:datePublished 2015-11
53 schema:datePublishedReg 2015-11-01
54 schema:description The paper presents the kinetics and proposed pathways photodegradation and photooxidation of p-arsanilic acid, in a neutral environment by ozone and hydrogen peroxide. The results showed that in a neutral environment, photoozonation process was characterized by the highest decomposition rate constant (k) (k = 31.8 × 10(-3) min(-1)). The rate constants decreased in the order UV/O3 > O3 > UV/H2O2 > H2O2 > UV. It was also found that under pH = 7, decomposition of p-arsanilic acid leads mainly to the formation of aniline, which undergoes secondary reactions. Intermediate products of oxidation and photooxidation by hydrogen peroxide like nitrobenzene, nitrophenol, azobenzenes, and phenylazophenol were identified depending on processes. However, in the photodegradation process, formation of nitrasone as a reaction product of p-arsanilic acid with oxygen in the singlet state was observed. In the case of ozonation and photoozonation, in addition, aniline formation of carboxylic acids was observed.
55 schema:genre research_article
56 schema:inLanguage en
57 schema:isAccessibleForFree false
58 schema:isPartOf N82dc0c0fa06b4fdda107c0316317e12b
59 Nf0542dc8e5754c529dac05813c927d48
60 sg:journal.1113424
61 schema:name Study of photodegradation and photooxidation of p-arsanilic acid in water solutions at pH = 7: kinetics and by-products
62 schema:pagination 16927-16935
63 schema:productId N34eff9e722334eee82015fec35f1a5ea
64 N69eda17844bd4d6bbc0aa6232bce8e38
65 N8948db50dd294708bc20a708ca5a21ff
66 Nce8562ee8b594577947c5b979f866a4a
67 Nffdf51f8f4d7456c84042821d3885dac
68 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020514324
69 https://doi.org/10.1007/s11356-015-4890-z
70 schema:sdDatePublished 2019-04-10T22:34
71 schema:sdLicense https://scigraph.springernature.com/explorer/license/
72 schema:sdPublisher Nce3861b032584205a162bb149a36321d
73 schema:url http://link.springer.com/10.1007%2Fs11356-015-4890-z
74 sgo:license sg:explorer/license/
75 sgo:sdDataset articles
76 rdf:type schema:ScholarlyArticle
77 N0647e74598f74915b89ec00df9624efe schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
78 schema:name Water
79 rdf:type schema:DefinedTerm
80 N140a217388dc4ad9bba753e244d8a27b schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
81 schema:name Ozone
82 rdf:type schema:DefinedTerm
83 N34eff9e722334eee82015fec35f1a5ea schema:name readcube_id
84 schema:value 61bf46c095da993148c07a24a6b52a58f8b881372a591824518bdb03f0e0e047
85 rdf:type schema:PropertyValue
86 N678f6e78ad894e9db1e4e4952824f1a8 rdf:first sg:person.01371503045.05
87 rdf:rest N87b31915017647eabef4e35846dc288a
88 N69eda17844bd4d6bbc0aa6232bce8e38 schema:name pubmed_id
89 schema:value 26109222
90 rdf:type schema:PropertyValue
91 N74666d38ac414020ab517e226f854d0e schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
92 schema:name Arsanilic Acid
93 rdf:type schema:DefinedTerm
94 N7522a3c460c04671898dfb007b7ae4d5 schema:affiliation https://www.grid.ac/institutes/grid.425049.e
95 schema:familyName Bąk
96 schema:givenName Marta
97 rdf:type schema:Person
98 N82dc0c0fa06b4fdda107c0316317e12b schema:issueNumber 21
99 rdf:type schema:PublicationIssue
100 N84e3c7ad9cf14a26a8a26b176717c066 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
101 schema:name Oxidation-Reduction
102 rdf:type schema:DefinedTerm
103 N87b31915017647eabef4e35846dc288a rdf:first sg:person.0646402205.11
104 rdf:rest Nc4fcfc430d2c43678c8cf2f3a674b9e2
105 N8948db50dd294708bc20a708ca5a21ff schema:name nlm_unique_id
106 schema:value 9441769
107 rdf:type schema:PropertyValue
108 N9298af08deaa4687941716e30d3d8ceb schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
109 schema:name Hydrogen-Ion Concentration
110 rdf:type schema:DefinedTerm
111 N9836ecd41d4d425ca5a5ec93d8712bd0 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
112 schema:name Photolysis
113 rdf:type schema:DefinedTerm
114 Nc4fcfc430d2c43678c8cf2f3a674b9e2 rdf:first N7522a3c460c04671898dfb007b7ae4d5
115 rdf:rest rdf:nil
116 Ncd6042d0ecd144c58c59e1be6527dfe8 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
117 schema:name Hydrogen Peroxide
118 rdf:type schema:DefinedTerm
119 Nce3861b032584205a162bb149a36321d schema:name Springer Nature - SN SciGraph project
120 rdf:type schema:Organization
121 Nce8562ee8b594577947c5b979f866a4a schema:name doi
122 schema:value 10.1007/s11356-015-4890-z
123 rdf:type schema:PropertyValue
124 Nf0542dc8e5754c529dac05813c927d48 schema:volumeNumber 22
125 rdf:type schema:PublicationVolume
126 Nffdf51f8f4d7456c84042821d3885dac schema:name dimensions_id
127 schema:value pub.1020514324
128 rdf:type schema:PropertyValue
129 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
130 schema:name Chemical Sciences
131 rdf:type schema:DefinedTerm
132 anzsrc-for:0399 schema:inDefinedTermSet anzsrc-for:
133 schema:name Other Chemical Sciences
134 rdf:type schema:DefinedTerm
135 sg:journal.1113424 schema:issn 0944-1344
136 1614-7499
137 schema:name Environmental Science and Pollution Research
138 rdf:type schema:Periodical
139 sg:person.01371503045.05 schema:affiliation https://www.grid.ac/institutes/grid.425049.e
140 schema:familyName Czaplicka
141 schema:givenName Marianna
142 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01371503045.05
143 rdf:type schema:Person
144 sg:person.0646402205.11 schema:affiliation https://www.grid.ac/institutes/grid.425049.e
145 schema:familyName Jaworek
146 schema:givenName Katarzyna
147 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0646402205.11
148 rdf:type schema:Person
149 sg:pub.10.1007/bf00483364 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012933130
150 https://doi.org/10.1007/bf00483364
151 rdf:type schema:CreativeWork
152 sg:pub.10.1007/s11270-010-0716-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015362037
153 https://doi.org/10.1007/s11270-010-0716-2
154 rdf:type schema:CreativeWork
155 sg:pub.10.1007/s11356-014-2983-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019465821
156 https://doi.org/10.1007/s11356-014-2983-8
157 rdf:type schema:CreativeWork
158 https://doi.org/10.1006/taap.1999.8872 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012719216
159 rdf:type schema:CreativeWork
160 https://doi.org/10.1016/0021-9673(95)00751-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039799074
161 rdf:type schema:CreativeWork
162 https://doi.org/10.1016/0039-9140(95)01395-r schema:sameAs https://app.dimensions.ai/details/publication/pub.1011036903
163 rdf:type schema:CreativeWork
164 https://doi.org/10.1016/0045-6535(92)90060-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047095036
165 rdf:type schema:CreativeWork
166 https://doi.org/10.1016/0165-9936(95)91620-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024452464
167 rdf:type schema:CreativeWork
168 https://doi.org/10.1016/0304-3894(95)00089-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031842367
169 rdf:type schema:CreativeWork
170 https://doi.org/10.1016/j.aca.2003.11.053 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032560061
171 rdf:type schema:CreativeWork
172 https://doi.org/10.1016/j.aca.2004.10.047 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042394543
173 rdf:type schema:CreativeWork
174 https://doi.org/10.1016/j.cattod.2004.04.020 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041359650
175 rdf:type schema:CreativeWork
176 https://doi.org/10.1016/j.cattod.2013.09.040 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039627894
177 rdf:type schema:CreativeWork
178 https://doi.org/10.1016/j.cej.2014.01.016 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041708821
179 rdf:type schema:CreativeWork
180 https://doi.org/10.1016/j.chemosphere.2010.10.045 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046839655
181 rdf:type schema:CreativeWork
182 https://doi.org/10.1016/j.chroma.2004.06.016 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019659765
183 rdf:type schema:CreativeWork
184 https://doi.org/10.1016/j.desal.2006.05.040 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027065599
185 rdf:type schema:CreativeWork
186 https://doi.org/10.1016/j.jhazmat.2009.05.041 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041524713
187 rdf:type schema:CreativeWork
188 https://doi.org/10.1016/j.jhazmat.2009.10.010 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026279999
189 rdf:type schema:CreativeWork
190 https://doi.org/10.1016/j.jhazmat.2010.12.005 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033078319
191 rdf:type schema:CreativeWork
192 https://doi.org/10.1016/j.scitotenv.2005.03.031 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050190185
193 rdf:type schema:CreativeWork
194 https://doi.org/10.1016/j.talanta.2005.11.025 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033906498
195 rdf:type schema:CreativeWork
196 https://doi.org/10.1016/j.trac.2005.06.004 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010485729
197 rdf:type schema:CreativeWork
198 https://doi.org/10.1016/s0003-2670(01)01477-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007554539
199 rdf:type schema:CreativeWork
200 https://doi.org/10.1016/s0021-9673(98)00080-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050781764
201 rdf:type schema:CreativeWork
202 https://doi.org/10.1016/s0039-9140(02)00258-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016846501
203 rdf:type schema:CreativeWork
204 https://doi.org/10.1016/s0043-1354(00)00182-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047556743
205 rdf:type schema:CreativeWork
206 https://doi.org/10.1016/s0043-1354(03)00080-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037260966
207 rdf:type schema:CreativeWork
208 https://doi.org/10.1016/s0045-6535(00)00060-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035232426
209 rdf:type schema:CreativeWork
210 https://doi.org/10.1016/s0048-9697(02)00322-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009067332
211 rdf:type schema:CreativeWork
212 https://doi.org/10.1016/s0048-9697(99)00035-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033089916
213 rdf:type schema:CreativeWork
214 https://doi.org/10.1016/s0300-483x(00)00458-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005371285
215 rdf:type schema:CreativeWork
216 https://doi.org/10.1016/s0969-806x(98)00348-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1040419317
217 rdf:type schema:CreativeWork
218 https://doi.org/10.1016/s1001-0742(08)62127-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042447759
219 rdf:type schema:CreativeWork
220 https://doi.org/10.1016/s1010-6030(00)00223-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008375254
221 rdf:type schema:CreativeWork
222 https://doi.org/10.1021/jo01269a035 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056009094
223 rdf:type schema:CreativeWork
224 https://doi.org/10.1021/jp072135y schema:sameAs https://app.dimensions.ai/details/publication/pub.1056071592
225 rdf:type schema:CreativeWork
226 https://doi.org/10.1021/tx00034a025 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056296924
227 rdf:type schema:CreativeWork
228 https://doi.org/10.1080/09593330.2012.752876 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010401159
229 rdf:type schema:CreativeWork
230 https://doi.org/10.1126/science.1131574 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062454645
231 rdf:type schema:CreativeWork
232 https://doi.org/10.3390/molecules20022622 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019925165
233 rdf:type schema:CreativeWork
234 https://www.grid.ac/institutes/grid.425049.e schema:alternateName Institute of Non-Ferrous Metals
235 schema:name Institute of Non-Ferrous Metals, Sowinskiego 5, Gliwice, Poland
236 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...