Decomposition of phenylarsonic acid by AOP processes: degradation rate constants and by-products View Full Text


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Article Info

DATE

2014-10

AUTHORS

K. Jaworek, M. Czaplicka, Ł. Bratek

ABSTRACT

The paper presents results of the studies photodegradation, photooxidation, and oxidation of phenylarsonic acid (PAA) in aquatic solution. The water solutions, which consist of 2.7 g dm(-3) phenylarsonic acid, were subjected to advance oxidation process (AOP) in UV, UV/H2O2, UV/O3, H2O2, and O3 systems under two pH conditions. Kinetic rate constants and half-life of phenylarsonic acid decomposition reaction are presented. The results from the study indicate that at pH 2 and 7, PAA degradation processes takes place in accordance with the pseudo first order kinetic reaction. The highest rate constants (10.45 × 10(-3) and 20.12 × 10(-3)) and degradation efficiencies at pH 2 and 7 were obtained at UV/O3 processes. In solution, after processes, benzene, phenol, acetophenone, o-hydroxybiphenyl, p-hydroxybiphenyl, benzoic acid, benzaldehyde, and biphenyl were identified. More... »

PAGES

11917-11923

References to SciGraph publications

  • 1996-02. The toxicity of organoarsenic-based warfare agents: In vitro and in vivo studies in ARCHIVES OF ENVIRONMENTAL CONTAMINATION AND TOXICOLOGY
  • 1998-06. Chromatographic determination of phenylarsenic compounds in JOURNAL OF ANALYTICAL CHEMISTRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s11356-014-2983-8

    DOI

    http://dx.doi.org/10.1007/s11356-014-2983-8

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1019465821

    PUBMED

    https://www.ncbi.nlm.nih.gov/pubmed/24824504


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