Reactions of Dimethylether in Single Crystals of the Silicoaluminophosphate STA-7 Studied via Operando Synchrotron Infrared Microspectroscopy View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2018-04

AUTHORS

Russell F. Howe, Suwardiyanto, David J. Price, Maria Castro, Paul A. Wright, Alex Greenaway, Mark D. Frogley, Gianfelice Cinque

ABSTRACT

: Synchrotron infrared micro-spectroscopy has been applied to measure in situ the reaction of dimethylether in single crystals of the silicoaluminophosphate STA-7. The crystals are found to contain a uniform and homogeneous distribution of acidic hydroxyl groups. Dimethylether is hydrogen bonded to the hydroxyl groups at low temperatures, but evidence is found for dissociation to form surface methoxy groups above 473 K, and aromatic hydrocarbon pool species above 573 K. From time resolved infrared measurements coupled with MS analysis of evolved products it is concluded that alkene formation occurs via a direct mechanism from reaction of dimethylether with surface methoxy groups. Graphical Abstract: More... »

PAGES

199-212

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11244-018-0890-9

DOI

http://dx.doi.org/10.1007/s11244-018-0890-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1100424769

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/30956505


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44 schema:description Abstract: Synchrotron infrared micro-spectroscopy has been applied to measure in situ the reaction of dimethylether in single crystals of the silicoaluminophosphate STA-7. The crystals are found to contain a uniform and homogeneous distribution of acidic hydroxyl groups. Dimethylether is hydrogen bonded to the hydroxyl groups at low temperatures, but evidence is found for dissociation to form surface methoxy groups above 473 K, and aromatic hydrocarbon pool species above 573 K. From time resolved infrared measurements coupled with MS analysis of evolved products it is concluded that alkene formation occurs via a direct mechanism from reaction of dimethylether with surface methoxy groups. Graphical Abstract:
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