An efficient method for selective oxidation of (oxime)Pt(II) to (oxime)Pt(IV) species using N,N-dichlorotosylamide View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2016-03-01

AUTHORS

Anastasiia M. Afanasenko, Evgeny Yu. Bulatov, Tatiana G. Chulkova, Matti Haukka, Fedor M. Dolgushin

ABSTRACT

The oxidation of (oxime)PtII species using the electrophilic chlorine-based oxidant N,N-dichlorotosylamide (4-CH3C6H4SO2NCl2) was studied. The reactions of trans-[PtCl2(oxime)2] (where oxime = acetoxime, cyclopentanone oxime, or acetaldoxime) with this oxidant led to trans-[PtCl4(oxime)2] products. The oxidation of trans-[Pt(o-OC6H4CH = NOH)2] at room temperature gave trans-[PtCl2(o-OC6H4CH = NOH)2], whereas the same reaction upon heating was accompanied by electrophilic substitution of the benzene rings. More... »

PAGES

387-392

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11243-016-0034-7

DOI

http://dx.doi.org/10.1007/s11243-016-0034-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1033592560


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Chemistry, Saint Petersburg State University, Universitetskiy Pr., 26, 198504, Stary Petergof, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.15447.33", 
          "name": [
            "Institute of Chemistry, Saint Petersburg State University, Universitetskiy Pr., 26, 198504, Stary Petergof, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Afanasenko", 
        "givenName": "Anastasiia M.", 
        "id": "sg:person.011525767536.26", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011525767536.26"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, University of Jyv\u00e4skyl\u00e4, P.O. Box 35, 40014, Jyv\u00e4skyl\u00e4, Finland", 
          "id": "http://www.grid.ac/institutes/grid.9681.6", 
          "name": [
            "Department of Chemistry, University of Jyv\u00e4skyl\u00e4, P.O. Box 35, 40014, Jyv\u00e4skyl\u00e4, Finland"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bulatov", 
        "givenName": "Evgeny Yu.", 
        "id": "sg:person.01076233766.14", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01076233766.14"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemistry, Saint Petersburg State University, Universitetskiy Pr., 26, 198504, Stary Petergof, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.15447.33", 
          "name": [
            "Institute of Chemistry, Saint Petersburg State University, Universitetskiy Pr., 26, 198504, Stary Petergof, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chulkova", 
        "givenName": "Tatiana G.", 
        "id": "sg:person.01077052504.94", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01077052504.94"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, University of Jyv\u00e4skyl\u00e4, P.O. Box 35, 40014, Jyv\u00e4skyl\u00e4, Finland", 
          "id": "http://www.grid.ac/institutes/grid.9681.6", 
          "name": [
            "Department of Chemistry, University of Jyv\u00e4skyl\u00e4, P.O. Box 35, 40014, Jyv\u00e4skyl\u00e4, Finland"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Haukka", 
        "givenName": "Matti", 
        "id": "sg:person.0725737251.91", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0725737251.91"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A.N. Nesmeyanov Institute of Organoelement Compounds, 28 Vavilov Street, 119991, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "A.N. Nesmeyanov Institute of Organoelement Compounds, 28 Vavilov Street, 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dolgushin", 
        "givenName": "Fedor M.", 
        "id": "sg:person.01267101640.70", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01267101640.70"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1023/a:1016365605288", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056307658", 
          "https://doi.org/10.1023/a:1016365605288"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2016-03-01", 
    "datePublishedReg": "2016-03-01", 
    "description": "The oxidation of (oxime)PtII species using the electrophilic chlorine-based oxidant N,N-dichlorotosylamide (4-CH3C6H4SO2NCl2) was studied. The reactions of trans-[PtCl2(oxime)2] (where oxime\u00a0=\u00a0acetoxime, cyclopentanone oxime, or acetaldoxime) with this oxidant led to trans-[PtCl4(oxime)2] products. The oxidation of trans-[Pt(o-OC6H4CH\u00a0=\u00a0NOH)2] at room temperature gave trans-[PtCl2(o-OC6H4CH\u00a0=\u00a0NOH)2], whereas the same reaction upon heating was accompanied by electrophilic substitution of the benzene rings.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s11243-016-0034-7", 
    "inLanguage": "en", 
    "isAccessibleForFree": true, 
    "isPartOf": [
      {
        "id": "sg:journal.1136539", 
        "issn": [
          "0340-4285", 
          "1572-901X"
        ], 
        "name": "Transition Metal Chemistry", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "41"
      }
    ], 
    "keywords": [
      "species", 
      "trans", 
      "substitution", 
      "oxidation", 
      "same reaction", 
      "oxidants", 
      "efficient method", 
      "reaction", 
      "oxidation of trans", 
      "reaction of trans", 
      "selective oxidation", 
      "trans products", 
      "electrophilic substitution", 
      "ring", 
      "benzene ring", 
      "room temperature", 
      "temperature", 
      "method", 
      "heating", 
      "dichlorotosylamide"
    ], 
    "name": "An efficient method for selective oxidation of (oxime)Pt(II) to (oxime)Pt(IV) species using N,N-dichlorotosylamide", 
    "pagination": "387-392", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1033592560"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11243-016-0034-7"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11243-016-0034-7", 
      "https://app.dimensions.ai/details/publication/pub.1033592560"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-01-01T18:41", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220101/entities/gbq_results/article/article_714.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s11243-016-0034-7"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11243-016-0034-7'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11243-016-0034-7'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11243-016-0034-7'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11243-016-0034-7'


 

This table displays all metadata directly associated to this object as RDF triples.

116 TRIPLES      22 PREDICATES      46 URIs      37 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11243-016-0034-7 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N5a4b4587861749699f4aa0eea661dd6c
4 schema:citation sg:pub.10.1023/a:1016365605288
5 schema:datePublished 2016-03-01
6 schema:datePublishedReg 2016-03-01
7 schema:description The oxidation of (oxime)PtII species using the electrophilic chlorine-based oxidant N,N-dichlorotosylamide (4-CH3C6H4SO2NCl2) was studied. The reactions of trans-[PtCl2(oxime)2] (where oxime = acetoxime, cyclopentanone oxime, or acetaldoxime) with this oxidant led to trans-[PtCl4(oxime)2] products. The oxidation of trans-[Pt(o-OC6H4CH = NOH)2] at room temperature gave trans-[PtCl2(o-OC6H4CH = NOH)2], whereas the same reaction upon heating was accompanied by electrophilic substitution of the benzene rings.
8 schema:genre article
9 schema:inLanguage en
10 schema:isAccessibleForFree true
11 schema:isPartOf N208d76493ac247239d66565ef894be99
12 N6d0a97669c0d43489ed35680efa9b3cd
13 sg:journal.1136539
14 schema:keywords benzene ring
15 dichlorotosylamide
16 efficient method
17 electrophilic substitution
18 heating
19 method
20 oxidants
21 oxidation
22 oxidation of trans
23 reaction
24 reaction of trans
25 ring
26 room temperature
27 same reaction
28 selective oxidation
29 species
30 substitution
31 temperature
32 trans
33 trans products
34 schema:name An efficient method for selective oxidation of (oxime)Pt(II) to (oxime)Pt(IV) species using N,N-dichlorotosylamide
35 schema:pagination 387-392
36 schema:productId N0dc1108d0df14a6ea34172daf25beedc
37 N9c91ca2ce11e42f2a2c69286142ed9e3
38 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033592560
39 https://doi.org/10.1007/s11243-016-0034-7
40 schema:sdDatePublished 2022-01-01T18:41
41 schema:sdLicense https://scigraph.springernature.com/explorer/license/
42 schema:sdPublisher N37286e00382a47b5aabf01c74f252ae6
43 schema:url https://doi.org/10.1007/s11243-016-0034-7
44 sgo:license sg:explorer/license/
45 sgo:sdDataset articles
46 rdf:type schema:ScholarlyArticle
47 N0dc1108d0df14a6ea34172daf25beedc schema:name doi
48 schema:value 10.1007/s11243-016-0034-7
49 rdf:type schema:PropertyValue
50 N208d76493ac247239d66565ef894be99 schema:issueNumber 4
51 rdf:type schema:PublicationIssue
52 N37286e00382a47b5aabf01c74f252ae6 schema:name Springer Nature - SN SciGraph project
53 rdf:type schema:Organization
54 N5211e6f98b3541aeab295907f2b749bc rdf:first sg:person.0725737251.91
55 rdf:rest N6db5c22e0af043beb0c357f0726d9dc0
56 N594c33070e714a5fa20eaeb309d49585 rdf:first sg:person.01077052504.94
57 rdf:rest N5211e6f98b3541aeab295907f2b749bc
58 N5a4b4587861749699f4aa0eea661dd6c rdf:first sg:person.011525767536.26
59 rdf:rest Nd71d55df559d4ff3be4dc90c747e1b6c
60 N6d0a97669c0d43489ed35680efa9b3cd schema:volumeNumber 41
61 rdf:type schema:PublicationVolume
62 N6db5c22e0af043beb0c357f0726d9dc0 rdf:first sg:person.01267101640.70
63 rdf:rest rdf:nil
64 N9c91ca2ce11e42f2a2c69286142ed9e3 schema:name dimensions_id
65 schema:value pub.1033592560
66 rdf:type schema:PropertyValue
67 Nd71d55df559d4ff3be4dc90c747e1b6c rdf:first sg:person.01076233766.14
68 rdf:rest N594c33070e714a5fa20eaeb309d49585
69 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
70 schema:name Chemical Sciences
71 rdf:type schema:DefinedTerm
72 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
73 schema:name Physical Chemistry (incl. Structural)
74 rdf:type schema:DefinedTerm
75 sg:journal.1136539 schema:issn 0340-4285
76 1572-901X
77 schema:name Transition Metal Chemistry
78 schema:publisher Springer Nature
79 rdf:type schema:Periodical
80 sg:person.01076233766.14 schema:affiliation grid-institutes:grid.9681.6
81 schema:familyName Bulatov
82 schema:givenName Evgeny Yu.
83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01076233766.14
84 rdf:type schema:Person
85 sg:person.01077052504.94 schema:affiliation grid-institutes:grid.15447.33
86 schema:familyName Chulkova
87 schema:givenName Tatiana G.
88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01077052504.94
89 rdf:type schema:Person
90 sg:person.011525767536.26 schema:affiliation grid-institutes:grid.15447.33
91 schema:familyName Afanasenko
92 schema:givenName Anastasiia M.
93 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011525767536.26
94 rdf:type schema:Person
95 sg:person.01267101640.70 schema:affiliation grid-institutes:grid.431939.5
96 schema:familyName Dolgushin
97 schema:givenName Fedor M.
98 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01267101640.70
99 rdf:type schema:Person
100 sg:person.0725737251.91 schema:affiliation grid-institutes:grid.9681.6
101 schema:familyName Haukka
102 schema:givenName Matti
103 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0725737251.91
104 rdf:type schema:Person
105 sg:pub.10.1023/a:1016365605288 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056307658
106 https://doi.org/10.1023/a:1016365605288
107 rdf:type schema:CreativeWork
108 grid-institutes:grid.15447.33 schema:alternateName Institute of Chemistry, Saint Petersburg State University, Universitetskiy Pr., 26, 198504, Stary Petergof, Russian Federation
109 schema:name Institute of Chemistry, Saint Petersburg State University, Universitetskiy Pr., 26, 198504, Stary Petergof, Russian Federation
110 rdf:type schema:Organization
111 grid-institutes:grid.431939.5 schema:alternateName A.N. Nesmeyanov Institute of Organoelement Compounds, 28 Vavilov Street, 119991, Moscow, Russian Federation
112 schema:name A.N. Nesmeyanov Institute of Organoelement Compounds, 28 Vavilov Street, 119991, Moscow, Russian Federation
113 rdf:type schema:Organization
114 grid-institutes:grid.9681.6 schema:alternateName Department of Chemistry, University of Jyväskylä, P.O. Box 35, 40014, Jyväskylä, Finland
115 schema:name Department of Chemistry, University of Jyväskylä, P.O. Box 35, 40014, Jyväskylä, Finland
116 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...