An efficient method for selective oxidation of (oxime)Pt(II) to (oxime)Pt(IV) species using N,N-dichlorotosylamide View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2016-03-01

AUTHORS

Anastasiia M. Afanasenko, Evgeny Yu. Bulatov, Tatiana G. Chulkova, Matti Haukka, Fedor M. Dolgushin

ABSTRACT

The oxidation of (oxime)PtII species using the electrophilic chlorine-based oxidant N,N-dichlorotosylamide (4-CH3C6H4SO2NCl2) was studied. The reactions of trans-[PtCl2(oxime)2] (where oxime = acetoxime, cyclopentanone oxime, or acetaldoxime) with this oxidant led to trans-[PtCl4(oxime)2] products. The oxidation of trans-[Pt(o-OC6H4CH = NOH)2] at room temperature gave trans-[PtCl2(o-OC6H4CH = NOH)2], whereas the same reaction upon heating was accompanied by electrophilic substitution of the benzene rings. More... »

PAGES

387-392

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11243-016-0034-7

DOI

http://dx.doi.org/10.1007/s11243-016-0034-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1033592560


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