Syntheses and crystal structures of two tetranuclear copper(II) complexes with Schiff bases View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-05

AUTHORS

Na Zhang, Zhong-Lu You

ABSTRACT

Two similar tetranuclear copper(II) complexes with the formulae [Cu4(L1)2(μ1,1-N3)4(μ2-CH3COO)2] and [Cu4(L2)2(μ1,1-N3)2(μ-Br)2Br2(CH3OH)2], where L1 and L2 are the deprotonated forms of 2-[(2-ethylaminoethylimino)methyl]-5-methoxyphenol and 5-methoxy-2-[(2-piperidin-1-ylethylimino)methyl]phenol, respectively, have been synthesized and characterized by spectroscopic methods and single-crystal X-ray diffraction. Both complexes are centrosymmetric tetranuclear copper(II) compounds. The bridging groups in [Cu4(L1)2(μ1,1-N3)4(μ2-CH3COO)2] are μ1,1-azide ligands and μ2-acetate ligands, and those in [Cu4(L2)2(μ1,1-N3)2(μ-Br)2Br2(CH3OH)2] are μ1,1-azide ligands and μ-bromide ligands. Each Cu atom in the complexes is in a square pyramidal geometry. More... »

PAGES

437-440

Journal

TITLE

Transition Metal Chemistry

ISSUE

4

VOLUME

35

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11243-010-9346-1

DOI

http://dx.doi.org/10.1007/s11243-010-9346-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1042898136


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Liaoning Normal University", 
          "id": "https://www.grid.ac/institutes/grid.440818.1", 
          "name": [
            "Department of Chemistry and Chemical Engineering, Liaoning Normal University, 116029, Dalian, People\u2019s Republic of China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zhang", 
        "givenName": "Na", 
        "id": "sg:person.010400446152.23", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010400446152.23"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Liaoning Normal University", 
          "id": "https://www.grid.ac/institutes/grid.440818.1", 
          "name": [
            "Department of Chemistry and Chemical Engineering, Liaoning Normal University, 116029, Dalian, People\u2019s Republic of China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "You", 
        "givenName": "Zhong-Lu", 
        "id": "sg:person.01132241366.17", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01132241366.17"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/0584-8539(67)80219-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004143519"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/zaac.200500308", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009485685"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/zaac.200500308", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009485685"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-1902(72)80230-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013439255"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-1902(72)80230-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013439255"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/zaac.200600214", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014820229"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-1902(73)80244-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021202737"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-1902(73)80244-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021202737"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.inoche.2007.11.022", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021634955"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1071/ch9670877", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025634848"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/ejic.200900168", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033108294"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/ejic.200900168", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033108294"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00958979908024545", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034977322"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.ica.2004.09.055", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041990876"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/zaac.200600198", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045620398"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.ica.2008.03.111", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046370627"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic00048a035", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055539767"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic50063a042", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055569993"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja0367086", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055834050"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja0367086", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055834050"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00945718608071387", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058290880"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2010-05", 
    "datePublishedReg": "2010-05-01", 
    "description": "Two similar tetranuclear copper(II) complexes with the formulae [Cu4(L1)2(\u03bc1,1-N3)4(\u03bc2-CH3COO)2] and [Cu4(L2)2(\u03bc1,1-N3)2(\u03bc-Br)2Br2(CH3OH)2], where L1 and L2 are the deprotonated forms of 2-[(2-ethylaminoethylimino)methyl]-5-methoxyphenol and 5-methoxy-2-[(2-piperidin-1-ylethylimino)methyl]phenol, respectively, have been synthesized and characterized by spectroscopic methods and single-crystal X-ray diffraction. Both complexes are centrosymmetric tetranuclear copper(II) compounds. The bridging groups in [Cu4(L1)2(\u03bc1,1-N3)4(\u03bc2-CH3COO)2] are \u03bc1,1-azide ligands and \u03bc2-acetate ligands, and those in [Cu4(L2)2(\u03bc1,1-N3)2(\u03bc-Br)2Br2(CH3OH)2] are \u03bc1,1-azide ligands and \u03bc-bromide ligands. Each Cu atom in the complexes is in a square pyramidal geometry.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s11243-010-9346-1", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136539", 
        "issn": [
          "0340-4285", 
          "1572-901X"
        ], 
        "name": "Transition Metal Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "35"
      }
    ], 
    "name": "Syntheses and crystal structures of two tetranuclear copper(II) complexes with Schiff bases", 
    "pagination": "437-440", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "cc5710cacd8deb95e8f430588a63d533548cd12e863d3b6407f94f7138309975"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11243-010-9346-1"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1042898136"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11243-010-9346-1", 
      "https://app.dimensions.ai/details/publication/pub.1042898136"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T09:55", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000347_0000000347/records_89801_00000001.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs11243-010-9346-1"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11243-010-9346-1'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11243-010-9346-1'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11243-010-9346-1'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11243-010-9346-1'


 

This table displays all metadata directly associated to this object as RDF triples.

116 TRIPLES      21 PREDICATES      43 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11243-010-9346-1 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N523a6539a62844d8a34f66549dbd984e
4 schema:citation https://doi.org/10.1002/ejic.200900168
5 https://doi.org/10.1002/zaac.200500308
6 https://doi.org/10.1002/zaac.200600198
7 https://doi.org/10.1002/zaac.200600214
8 https://doi.org/10.1016/0022-1902(72)80230-6
9 https://doi.org/10.1016/0022-1902(73)80244-1
10 https://doi.org/10.1016/0584-8539(67)80219-8
11 https://doi.org/10.1016/j.ica.2004.09.055
12 https://doi.org/10.1016/j.ica.2008.03.111
13 https://doi.org/10.1016/j.inoche.2007.11.022
14 https://doi.org/10.1021/ic00048a035
15 https://doi.org/10.1021/ic50063a042
16 https://doi.org/10.1021/ja0367086
17 https://doi.org/10.1071/ch9670877
18 https://doi.org/10.1080/00945718608071387
19 https://doi.org/10.1080/00958979908024545
20 schema:datePublished 2010-05
21 schema:datePublishedReg 2010-05-01
22 schema:description Two similar tetranuclear copper(II) complexes with the formulae [Cu4(L1)2(μ1,1-N3)4(μ2-CH3COO)2] and [Cu4(L2)2(μ1,1-N3)2(μ-Br)2Br2(CH3OH)2], where L1 and L2 are the deprotonated forms of 2-[(2-ethylaminoethylimino)methyl]-5-methoxyphenol and 5-methoxy-2-[(2-piperidin-1-ylethylimino)methyl]phenol, respectively, have been synthesized and characterized by spectroscopic methods and single-crystal X-ray diffraction. Both complexes are centrosymmetric tetranuclear copper(II) compounds. The bridging groups in [Cu4(L1)2(μ1,1-N3)4(μ2-CH3COO)2] are μ1,1-azide ligands and μ2-acetate ligands, and those in [Cu4(L2)2(μ1,1-N3)2(μ-Br)2Br2(CH3OH)2] are μ1,1-azide ligands and μ-bromide ligands. Each Cu atom in the complexes is in a square pyramidal geometry.
23 schema:genre research_article
24 schema:inLanguage en
25 schema:isAccessibleForFree false
26 schema:isPartOf N3387de7252cb4786b515c40f2f5283b2
27 N56cd5729b3594f0789f3186c0924c513
28 sg:journal.1136539
29 schema:name Syntheses and crystal structures of two tetranuclear copper(II) complexes with Schiff bases
30 schema:pagination 437-440
31 schema:productId N543983d9ae6d47b48a170a8baadd4514
32 N6b8765008b404e858be0ccfbe92ec38c
33 Nf8773a8f388c42a1a2f84e615faa9829
34 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042898136
35 https://doi.org/10.1007/s11243-010-9346-1
36 schema:sdDatePublished 2019-04-11T09:55
37 schema:sdLicense https://scigraph.springernature.com/explorer/license/
38 schema:sdPublisher Ne586d1271d0640afa8d6d4c8d32b458f
39 schema:url http://link.springer.com/10.1007%2Fs11243-010-9346-1
40 sgo:license sg:explorer/license/
41 sgo:sdDataset articles
42 rdf:type schema:ScholarlyArticle
43 N3387de7252cb4786b515c40f2f5283b2 schema:volumeNumber 35
44 rdf:type schema:PublicationVolume
45 N523a6539a62844d8a34f66549dbd984e rdf:first sg:person.010400446152.23
46 rdf:rest N8535d7aae29d411890c32de9a47ebb01
47 N543983d9ae6d47b48a170a8baadd4514 schema:name doi
48 schema:value 10.1007/s11243-010-9346-1
49 rdf:type schema:PropertyValue
50 N56cd5729b3594f0789f3186c0924c513 schema:issueNumber 4
51 rdf:type schema:PublicationIssue
52 N6b8765008b404e858be0ccfbe92ec38c schema:name readcube_id
53 schema:value cc5710cacd8deb95e8f430588a63d533548cd12e863d3b6407f94f7138309975
54 rdf:type schema:PropertyValue
55 N8535d7aae29d411890c32de9a47ebb01 rdf:first sg:person.01132241366.17
56 rdf:rest rdf:nil
57 Ne586d1271d0640afa8d6d4c8d32b458f schema:name Springer Nature - SN SciGraph project
58 rdf:type schema:Organization
59 Nf8773a8f388c42a1a2f84e615faa9829 schema:name dimensions_id
60 schema:value pub.1042898136
61 rdf:type schema:PropertyValue
62 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
63 schema:name Chemical Sciences
64 rdf:type schema:DefinedTerm
65 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
66 schema:name Inorganic Chemistry
67 rdf:type schema:DefinedTerm
68 sg:journal.1136539 schema:issn 0340-4285
69 1572-901X
70 schema:name Transition Metal Chemistry
71 rdf:type schema:Periodical
72 sg:person.010400446152.23 schema:affiliation https://www.grid.ac/institutes/grid.440818.1
73 schema:familyName Zhang
74 schema:givenName Na
75 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010400446152.23
76 rdf:type schema:Person
77 sg:person.01132241366.17 schema:affiliation https://www.grid.ac/institutes/grid.440818.1
78 schema:familyName You
79 schema:givenName Zhong-Lu
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01132241366.17
81 rdf:type schema:Person
82 https://doi.org/10.1002/ejic.200900168 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033108294
83 rdf:type schema:CreativeWork
84 https://doi.org/10.1002/zaac.200500308 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009485685
85 rdf:type schema:CreativeWork
86 https://doi.org/10.1002/zaac.200600198 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045620398
87 rdf:type schema:CreativeWork
88 https://doi.org/10.1002/zaac.200600214 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014820229
89 rdf:type schema:CreativeWork
90 https://doi.org/10.1016/0022-1902(72)80230-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013439255
91 rdf:type schema:CreativeWork
92 https://doi.org/10.1016/0022-1902(73)80244-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021202737
93 rdf:type schema:CreativeWork
94 https://doi.org/10.1016/0584-8539(67)80219-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004143519
95 rdf:type schema:CreativeWork
96 https://doi.org/10.1016/j.ica.2004.09.055 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041990876
97 rdf:type schema:CreativeWork
98 https://doi.org/10.1016/j.ica.2008.03.111 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046370627
99 rdf:type schema:CreativeWork
100 https://doi.org/10.1016/j.inoche.2007.11.022 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021634955
101 rdf:type schema:CreativeWork
102 https://doi.org/10.1021/ic00048a035 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055539767
103 rdf:type schema:CreativeWork
104 https://doi.org/10.1021/ic50063a042 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055569993
105 rdf:type schema:CreativeWork
106 https://doi.org/10.1021/ja0367086 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055834050
107 rdf:type schema:CreativeWork
108 https://doi.org/10.1071/ch9670877 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025634848
109 rdf:type schema:CreativeWork
110 https://doi.org/10.1080/00945718608071387 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058290880
111 rdf:type schema:CreativeWork
112 https://doi.org/10.1080/00958979908024545 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034977322
113 rdf:type schema:CreativeWork
114 https://www.grid.ac/institutes/grid.440818.1 schema:alternateName Liaoning Normal University
115 schema:name Department of Chemistry and Chemical Engineering, Liaoning Normal University, 116029, Dalian, People’s Republic of China
116 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...