Synthesis, characterization and charge-transfer photochemistry of trans-aquo azido-N,N′-trimethylenebis(naphthylideneiminato)chromium(III) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2004-10

AUTHORS

Mookandi Kanthimathi, Balachandran Unni Nair

ABSTRACT

A new CrIII complex, viz. trans-[Cr(naphprn)(H2O)2]ClO4·2H2O, (1) {naphprn=N,N′-trimethylenebis(naphthylideneimine)} has been synthesized and characterized. Aquo ligand substitution of (1) by the azide ligand gave rise to trans-[Cr(naphprn)(N3)(H2O)], (2). Irradiation of (2) in DMF gave nitrido(naphprn)chromium(V) (3). Solutions of (3) showed e.p.r. spectra at room temperature (giso=1.9865). The i.r. spectra showed disappearance of a band at 2067cm−1 showing the breakdown of N≡N and appearance of a new band at 1074cm−1which is assigned to the Cr≡14N, stretching frequency indicating the formation of a nitrido chromium(V) complex, (3). The u.v.–vis. spectrum of complex (3) exhibited a d–d band maximum at 553nm (ε=120M−1cm−1). The rate of formation of (2) was found to be 5.0×10−3M−1s−1 in an aqueous acidic medium at [CrIII]=0.5×10−3M; [N3−]=0.01–0.15M; [H+]=0.001M and I=0.2M (LiClO4). The rate of photo-decomposition of (2) to give rise to (3) was found to be 0.15×10−3s−1 in DMF. More... »

PAGES

751-756

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11243-004-8777-y

DOI

http://dx.doi.org/10.1007/s11243-004-8777-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1021314400


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Central Leather Research Institute", 
          "id": "https://www.grid.ac/institutes/grid.418369.1", 
          "name": [
            "Chemical Laboratory, Central Leather Research Institute, Adyar, 600 020, Chennai, India"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kanthimathi", 
        "givenName": "Mookandi", 
        "id": "sg:person.0775712340.31", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0775712340.31"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Central Leather Research Institute", 
          "id": "https://www.grid.ac/institutes/grid.418369.1", 
          "name": [
            "Chemical Laboratory, Central Leather Research Institute, Adyar, 600 020, Chennai, India"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Nair", 
        "givenName": "Balachandran Unni", 
        "id": "sg:person.01020247070.45", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01020247070.45"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf02872561", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001334514", 
          "https://doi.org/10.1007/bf02872561"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0020-1693(97)05528-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003587448"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0010-8545(00)80003-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003846044"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/02603594.1992.11102160", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004051366"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/a:1007090200950", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004259120", 
          "https://doi.org/10.1023/a:1007090200950"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/(sici)1096-9888(199908)34:8<880::aid-jms844>3.0.co;2-e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026999038"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0020-1693(98)00183-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033843382"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/ange.19810930506", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035213949"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/a:1021320804460", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042477962", 
          "https://doi.org/10.1023/a:1021320804460"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ar50135a004", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055151426"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic00148a008", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055545042"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic00148a009", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055545043"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic00220a049", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055547901"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic00227a007", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055548150"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic50177a019", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055577291"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic50179a021", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055577471"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic9508031", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055585744"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic9508031", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055585744"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic980302q", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055588690"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic980302q", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055588690"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02911099", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1085571575", 
          "https://doi.org/10.1007/bf02911099"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2004-10", 
    "datePublishedReg": "2004-10-01", 
    "description": "A new CrIII complex, viz. trans-[Cr(naphprn)(H2O)2]ClO4\u00b72H2O, (1) {naphprn=N,N\u2032-trimethylenebis(naphthylideneimine)} has been synthesized and characterized. Aquo ligand substitution of (1) by the azide ligand gave rise to trans-[Cr(naphprn)(N3)(H2O)], (2). Irradiation of (2) in DMF gave nitrido(naphprn)chromium(V) (3). Solutions of (3) showed e.p.r. spectra at room temperature (giso=1.9865). The i.r. spectra showed disappearance of a band at 2067cm\u22121 showing the breakdown of N\u2261N and appearance of a new band at 1074cm\u22121which is assigned to the Cr\u226114N, stretching frequency indicating the formation of a nitrido chromium(V) complex, (3). The u.v.\u2013vis. spectrum of complex (3) exhibited a d\u2013d band maximum at 553nm (\u03b5=120M\u22121cm\u22121). The rate of formation of (2) was found to be 5.0\u00d710\u22123M\u22121s\u22121 in an aqueous acidic medium at [CrIII]=0.5\u00d710\u22123M; [N3\u2212]=0.01\u20130.15M; [H+]=0.001M and I=0.2M (LiClO4). The rate of photo-decomposition of (2) to give rise to (3) was found to be 0.15\u00d710\u22123s\u22121 in DMF.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s11243-004-8777-y", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136539", 
        "issn": [
          "0340-4285", 
          "1572-901X"
        ], 
        "name": "Transition Metal Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "7", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "29"
      }
    ], 
    "name": "Synthesis, characterization and charge-transfer photochemistry of trans-aquo azido-N,N\u2032-trimethylenebis(naphthylideneiminato)chromium(III)", 
    "pagination": "751-756", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "658d75f0800a4c7b727d75361b6fb63b097bba434cde314ac2813f8f0701a7e6"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11243-004-8777-y"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1021314400"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11243-004-8777-y", 
      "https://app.dimensions.ai/details/publication/pub.1021314400"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T20:49", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8684_00000521.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs11243-004-8777-y"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11243-004-8777-y'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11243-004-8777-y'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11243-004-8777-y'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11243-004-8777-y'


 

This table displays all metadata directly associated to this object as RDF triples.

129 TRIPLES      21 PREDICATES      46 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11243-004-8777-y schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N3714f5b56592473787fe204b49b4ec4b
4 schema:citation sg:pub.10.1007/bf02872561
5 sg:pub.10.1007/bf02911099
6 sg:pub.10.1023/a:1007090200950
7 sg:pub.10.1023/a:1021320804460
8 https://doi.org/10.1002/(sici)1096-9888(199908)34:8<880::aid-jms844>3.0.co;2-e
9 https://doi.org/10.1002/ange.19810930506
10 https://doi.org/10.1016/s0010-8545(00)80003-x
11 https://doi.org/10.1016/s0020-1693(97)05528-x
12 https://doi.org/10.1016/s0020-1693(98)00183-2
13 https://doi.org/10.1021/ar50135a004
14 https://doi.org/10.1021/ic00148a008
15 https://doi.org/10.1021/ic00148a009
16 https://doi.org/10.1021/ic00220a049
17 https://doi.org/10.1021/ic00227a007
18 https://doi.org/10.1021/ic50177a019
19 https://doi.org/10.1021/ic50179a021
20 https://doi.org/10.1021/ic9508031
21 https://doi.org/10.1021/ic980302q
22 https://doi.org/10.1080/02603594.1992.11102160
23 schema:datePublished 2004-10
24 schema:datePublishedReg 2004-10-01
25 schema:description A new CrIII complex, viz. trans-[Cr(naphprn)(H2O)2]ClO4·2H2O, (1) {naphprn=N,N′-trimethylenebis(naphthylideneimine)} has been synthesized and characterized. Aquo ligand substitution of (1) by the azide ligand gave rise to trans-[Cr(naphprn)(N3)(H2O)], (2). Irradiation of (2) in DMF gave nitrido(naphprn)chromium(V) (3). Solutions of (3) showed e.p.r. spectra at room temperature (giso=1.9865). The i.r. spectra showed disappearance of a band at 2067cm−1 showing the breakdown of N≡N and appearance of a new band at 1074cm−1which is assigned to the Cr≡14N, stretching frequency indicating the formation of a nitrido chromium(V) complex, (3). The u.v.–vis. spectrum of complex (3) exhibited a d–d band maximum at 553nm (ε=120M−1cm−1). The rate of formation of (2) was found to be 5.0×10−3M−1s−1 in an aqueous acidic medium at [CrIII]=0.5×10−3M; [N3−]=0.01–0.15M; [H+]=0.001M and I=0.2M (LiClO4). The rate of photo-decomposition of (2) to give rise to (3) was found to be 0.15×10−3s−1 in DMF.
26 schema:genre research_article
27 schema:inLanguage en
28 schema:isAccessibleForFree false
29 schema:isPartOf N8e2b813d58e444efbaa15a1770401957
30 Nfecdd7d563324f54903d7d002d7c7c39
31 sg:journal.1136539
32 schema:name Synthesis, characterization and charge-transfer photochemistry of trans-aquo azido-N,N′-trimethylenebis(naphthylideneiminato)chromium(III)
33 schema:pagination 751-756
34 schema:productId N029218765a9545548d817fc8eeeb4610
35 N91d9763da4f74318abb9c4924ad0d4b6
36 N9f6456d7cfb84ab984dc94a08529f4ad
37 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021314400
38 https://doi.org/10.1007/s11243-004-8777-y
39 schema:sdDatePublished 2019-04-10T20:49
40 schema:sdLicense https://scigraph.springernature.com/explorer/license/
41 schema:sdPublisher N504e3b30347341fda8abe29770a83498
42 schema:url http://link.springer.com/10.1007%2Fs11243-004-8777-y
43 sgo:license sg:explorer/license/
44 sgo:sdDataset articles
45 rdf:type schema:ScholarlyArticle
46 N029218765a9545548d817fc8eeeb4610 schema:name dimensions_id
47 schema:value pub.1021314400
48 rdf:type schema:PropertyValue
49 N324fb99bdc4c42b5994cd9fc27811fe3 rdf:first sg:person.01020247070.45
50 rdf:rest rdf:nil
51 N3714f5b56592473787fe204b49b4ec4b rdf:first sg:person.0775712340.31
52 rdf:rest N324fb99bdc4c42b5994cd9fc27811fe3
53 N504e3b30347341fda8abe29770a83498 schema:name Springer Nature - SN SciGraph project
54 rdf:type schema:Organization
55 N8e2b813d58e444efbaa15a1770401957 schema:volumeNumber 29
56 rdf:type schema:PublicationVolume
57 N91d9763da4f74318abb9c4924ad0d4b6 schema:name doi
58 schema:value 10.1007/s11243-004-8777-y
59 rdf:type schema:PropertyValue
60 N9f6456d7cfb84ab984dc94a08529f4ad schema:name readcube_id
61 schema:value 658d75f0800a4c7b727d75361b6fb63b097bba434cde314ac2813f8f0701a7e6
62 rdf:type schema:PropertyValue
63 Nfecdd7d563324f54903d7d002d7c7c39 schema:issueNumber 7
64 rdf:type schema:PublicationIssue
65 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
66 schema:name Chemical Sciences
67 rdf:type schema:DefinedTerm
68 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
69 schema:name Inorganic Chemistry
70 rdf:type schema:DefinedTerm
71 sg:journal.1136539 schema:issn 0340-4285
72 1572-901X
73 schema:name Transition Metal Chemistry
74 rdf:type schema:Periodical
75 sg:person.01020247070.45 schema:affiliation https://www.grid.ac/institutes/grid.418369.1
76 schema:familyName Nair
77 schema:givenName Balachandran Unni
78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01020247070.45
79 rdf:type schema:Person
80 sg:person.0775712340.31 schema:affiliation https://www.grid.ac/institutes/grid.418369.1
81 schema:familyName Kanthimathi
82 schema:givenName Mookandi
83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0775712340.31
84 rdf:type schema:Person
85 sg:pub.10.1007/bf02872561 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001334514
86 https://doi.org/10.1007/bf02872561
87 rdf:type schema:CreativeWork
88 sg:pub.10.1007/bf02911099 schema:sameAs https://app.dimensions.ai/details/publication/pub.1085571575
89 https://doi.org/10.1007/bf02911099
90 rdf:type schema:CreativeWork
91 sg:pub.10.1023/a:1007090200950 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004259120
92 https://doi.org/10.1023/a:1007090200950
93 rdf:type schema:CreativeWork
94 sg:pub.10.1023/a:1021320804460 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042477962
95 https://doi.org/10.1023/a:1021320804460
96 rdf:type schema:CreativeWork
97 https://doi.org/10.1002/(sici)1096-9888(199908)34:8<880::aid-jms844>3.0.co;2-e schema:sameAs https://app.dimensions.ai/details/publication/pub.1026999038
98 rdf:type schema:CreativeWork
99 https://doi.org/10.1002/ange.19810930506 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035213949
100 rdf:type schema:CreativeWork
101 https://doi.org/10.1016/s0010-8545(00)80003-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1003846044
102 rdf:type schema:CreativeWork
103 https://doi.org/10.1016/s0020-1693(97)05528-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1003587448
104 rdf:type schema:CreativeWork
105 https://doi.org/10.1016/s0020-1693(98)00183-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033843382
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1021/ar50135a004 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055151426
108 rdf:type schema:CreativeWork
109 https://doi.org/10.1021/ic00148a008 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055545042
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1021/ic00148a009 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055545043
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1021/ic00220a049 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055547901
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1021/ic00227a007 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055548150
116 rdf:type schema:CreativeWork
117 https://doi.org/10.1021/ic50177a019 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055577291
118 rdf:type schema:CreativeWork
119 https://doi.org/10.1021/ic50179a021 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055577471
120 rdf:type schema:CreativeWork
121 https://doi.org/10.1021/ic9508031 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055585744
122 rdf:type schema:CreativeWork
123 https://doi.org/10.1021/ic980302q schema:sameAs https://app.dimensions.ai/details/publication/pub.1055588690
124 rdf:type schema:CreativeWork
125 https://doi.org/10.1080/02603594.1992.11102160 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004051366
126 rdf:type schema:CreativeWork
127 https://www.grid.ac/institutes/grid.418369.1 schema:alternateName Central Leather Research Institute
128 schema:name Chemical Laboratory, Central Leather Research Institute, Adyar, 600 020, Chennai, India
129 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...