Effect of the Structure of Carboxylate Ligands on the X-Ray Photoelectron Spectral Parameters of Trinuclear Heterometallic Complexes [Fe2MO(O2CR)6(H2O)3](H2O)3 (M = ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-09

AUTHORS

A. G. Kochur, T. M. Ivanova, R. V. Linko, M. A. Kiskin, S. V. Kolotilov, I. L. Eremenko

ABSTRACT

An anomalously large difference was found in the energies of the 2p, 3s, and 3p lines in the X-ray photoelectron spectra for all metal ions in complexes [Fe2MO(O2CCH3)6(H2O)3](H2O)3 and [Fe2MO(O2CCCl3)6(H2O)3](H2O)3(M = Co, Ni). The observed line shifts were explained in the framework of an electrostatic model considering the change in the interaction energy of the electrons of metal atoms and the charge distribution of the peripheral fragments of the complexes. More... »

PAGES

252-258

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11237-016-9476-4

DOI

http://dx.doi.org/10.1007/s11237-016-9476-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1016903569


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141 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
142 schema:name N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninsky Prospekt, 31, 119991, Moscow, Russian Federation
143 rdf:type schema:Organization
144 https://www.grid.ac/institutes/grid.77642.30 schema:alternateName Peoples' Friendship University of Russia
145 schema:name Russian People’s Friendship University (RUDN University), Miklukho-Maklaya Str., 6, 117198, Moscow, Russian Federation
146 rdf:type schema:Organization
 




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